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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 44, pp. 11950 - 11954
The alkylation of unactivated β‐methylene C(sp3)H bonds of α‐amino acid substrates with a broad range of alkyl iodides using Pd(OAc)2 as the catalyst is... 
alkylation | CH activation | palladium | synthetic methods | amino acids | DIRECTING GROUP | HALIDES | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PALLADIUM-CATALYZED ALKYLATION | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | C-H activation | AMINO-ACIDS | STEREOSELECTIVE-SYNTHESIS | Amino acids | Synthesis | Iodides | Strategy | Transformations | Compatibility | Arrays | Bonding | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5858 - 5862
The site‐selective functionalization of unactivated C(sp3)−H bonds remains one of the greatest challenges in organic synthesis. Herein, we report on the... 
alkylation | palladium | peptides | palladacycles | site selectivity | C(SP)-H BONDS | ACTIVATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CATALYZED ARYLATION | DIRECTING GROUPS | FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | STEREOSELECTIVE-SYNTHESIS | Hydrogen bonds | Oligopeptides | Peptides | Amino acids | Activation | Palladium | Bonding | Alkylation
Journal Article
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2018, Volume 59, Issue 23, pp. 2302 - 2305
[Display omitted] •An efficient nickel-catalyzed reductive relay cross-coupling of internal alkenes with alkyl/aryl halides has been developed.•This method has... 
Internal alkenes | Terminal-selectivity | Isomerization | Nickel-catalyzed | Alkylation | HALIDES | ORGANIC-SYNTHESIS | COBALT CATALYSTS | CHEMISTRY, ORGANIC | FORMAL HYDROAMINATION | CROSS-COUPLING REACTIONS | ARYL BORONIC ACIDS | REMOTE FUNCTIONALIZATION | OLEFINS | TERTIARY SILANES | CARBOXYLIC-ACIDS | Olefins
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2017, Volume 359, Issue 17, pp. 2912 - 2917
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 1, pp. 130 - 133
An organocatalytic enantioselective formal C­(sp2)–H alkylation is reported. This alkylative desymmetrization of prochiral 2,2-disubstituted... 
MICHAEL REACTION | CATALYZED DESYMMETRIZATION | ASYMMETRIC-SYNTHESIS | 5-MEMBERED RINGS | NATURAL-PRODUCTS | CARBON QUATERNARY STEREOCENTERS | CONSTRUCTION | NITROALKANES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CONJUGATE ADDITION | Alkanes | Chemical properties | Chemical synthesis | Hydrogen | Carbon compounds | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10581 - 10584
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2017, Volume 23, Issue 48, pp. 11524 - 11528
C−H alkylations with challenging β‐hydrogen‐containing alkyl halides were accomplished with sustainable MnCl2 as the catalyst under phosphine‐ligand‐free... 
selectivity | alkylation | C−H activation | mechanism | manganese | ACTIVATION | METHYLATION | STRATEGY | BOND FUNCTIONALIZATIONS | CARBOXAMIDES | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | C-H activation | NICKEL | PALLADIUM-CATALYZED ARYLATION | TRIAZOLE ASSISTANCE | ARYL | Hydrogen | Halides | Catalysts | Phosphine | Benzamide | Alkylation | Manganese
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2014, Volume 136, Issue 38, pp. 13194 - 13197
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 18, pp. 4666 - 4669
The rhodium­(III)-catalyzed cross-coupling reaction of 8-methylquinolines and maleimides is described. In contrast to the C­(sp2)–H functionalization, a first... 
FUNCTIONALIZATION | PALLADIUM | ACTIVATION | AMINATION | C-H BOND | CATALYZED INTERMOLECULAR AMIDATION | ANTICONVULSANTS | COMPLEXES | CHEMISTRY, ORGANIC | COPPER | ALKENYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 04/2014, Volume 16, Issue 7, pp. 1876 - 1879
A catalytic system comprising [RuCl2(PPh3)3], AgOTf, and BINAP enabled atom- and step-economical additions of C(sp3)–H bonds onto unactivated alkenes 2 under... 
H BOND ACTIVATION | FUNCTIONALIZATION | ALKENES | ATOM ECONOMY | COUPLING REACTION | CHEMISTRY, ORGANIC | CATALYZED DIRECT ARYLATIONS | CARBON-HYDROGEN BONDS | RUTHENIUM CATALYST | HYDROARYLATION | CYCLIC AMINES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 15869 - 15872
Herein we present a novel strategy based on palladium-catalyzed allylic alkylation by taking advantage of the nucleophilic addition of external fluoride onto... 
DECARBOXYLATIVE ALLYLATION | IRIDIUM | ENANTIOSELECTIVE FLUORINATION | CATALYZED ALLYLATION REACTION | REGIO | ALPHA-ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | DIASTEREO | ACTIVATED OLEFINS | TRIFLUOROMETHYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 15, pp. 5877 - 5884
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 4, pp. 660 - 664
A C–H alkylation/nucleophilic addition manifold with synthetically useful aryl oximes and pyrazoles was realized by rhodium(III) catalysis under remarkably... 
Domino reactions | Rhodium | C–H functionalization | Homogeneous catalysis | Alkylation | Nucleophilic addition | C-H functionalization | ACTIVATION | IRIDIUM | BOND ALKYLATION | ARYLATION | CHEMISTRY, ORGANIC | CLEAVAGE | CATALYZED HYDROARYLATIONS | FUNCTIONALIZATION | ALKENES | SELECTIVITY | CONJUGATE ADDITION
Journal Article