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The Chemical Record, ISSN 1527-8999, 12/2016, Volume 16, Issue 6, pp. 2687 - 2696
Allylic alkylation reactions are some of the most important carbon‐carbon bond forming reactions in organic synthesis. In particular, the alkylation of... 
metallocene ligands | palladium | enamines | carbonyl compounds | allylic alkylation | SUBSTITUTION | FERROCENE | PLANAR CHIRALITY | P,N-CHELATION | CATALYZED ALLYLATION | CARBONYL-COMPOUNDS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | DIPHOSPHINE LIGANDS | TRANSITION-METAL | Palladium | Metallocenes | Chemical bonds
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 23, pp. 7367 - 7370
An enantio- and regioselective allylic alkylation of sulfoximines with Morita–Baylis–Hillman carbonates was developed. The asymmetric reaction is directed by a... 
ROUTE | AMINATION | LIGANDS | PALLADIUM-CATALYZED DYKAT | ARYLATION | ACETATES | CHEMISTRY, ORGANIC | BAYLIS-HILLMAN CARBONATES | ALLYLAMINE DERIVATIVES | INHIBITOR | ENANTIOSELECTIVE TOTAL-SYNTHESIS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2004, Volume 69, Issue 18, pp. 5813 - 5837
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 15869 - 15872
Herein we present a novel strategy based on palladium-catalyzed allylic alkylation by taking advantage of the nucleophilic addition of external fluoride onto... 
DECARBOXYLATIVE ALLYLATION | IRIDIUM | ENANTIOSELECTIVE FLUORINATION | CATALYZED ALLYLATION REACTION | REGIO | ALPHA-ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | DIASTEREO | ACTIVATED OLEFINS | TRIFLUOROMETHYLATION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2009, Volume 7, Issue 18, pp. 3660 - 3662
The peroxy-asymmetric allylic alkylation of hydroperoxyalkanes with Morita-Baylis-Hillman carbonates was catalysed by modified cinchona alkaloids (up to 93%... 
ENANTIOSELECTIVE SYNTHESIS | KINETIC RESOLUTION | ALDOL REACTION | CHIRAL BRONSTED ACIDS | GAMMA-BUTENOLIDES | CONSTRUCTION | BAYLIS-HILLMAN REACTION | ACETATES | CHEMISTRY, ORGANIC | IONIC LIQUIDS | CATALYZED BAYLIS | Alkenes - chemistry | Catalysis | Esters - chemistry | Stereoisomerism | Alkylation | Peroxides - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2009, Volume 48, Issue 50, pp. 9533 - 9537
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1289 - 1295
An unprecedented indium‐mediated palladium‐catalyzed allylic alkylation of isatins with alkynes is disclosed. This reaction provides a new, practical, and... 
indium | isatins | 3-allyl-3-hydroxy-2-oxindoles | allylic alkylation | palladium-catalyzed | ACID | AQUEOUS-MEDIA | CHEMISTRY, ORGANIC | BOND FORMATION | ALPHA | HYDROAMINATION | ALCOHOLS | C-C | ENANTIOSELECTIVE ALLYLATION | METAL CATALYSIS | CHEMISTRY, APPLIED | MOLECULAR-OXYGEN | Indium | Palladium | Lewis acid | Oxidants | Oxidizing agents | Access routes | Alkylation | Substrates | Alkynes
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2019, Volume 58, Issue 29, pp. 9886 - 9890
An enantioselective rhodium-catalyzed allylic alkylation of b, g-unsaturated a-amino nitriles is described. This protocol provides a novel approach for the... 
SUBSTITUTION | DEPROTONATION | homoenolates | REAGENTS | ASYMMETRIC 1,4-ADDITION | REACTIVITY | asymmetric catalysis | REGIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | a-amino nitriles | STEREOSELECTIVITY | rhodium-catalyzed reactions | CONSTRUCTION | allylic substitution
Journal Article
Organometallics, ISSN 0276-7333, 05/2009, Volume 28, Issue 9, pp. 2724 - 2734
The new INDOLPhosphole ligands 3a,b are obtained in good yield in a two-step synthetic sequence from 3-methylindole, (S)-BINOL, and the corresponding... 
QUINAPHOS | CATALYZED HYDROGENATION | PHOSPHINE-PHOSPHORAMIDITE LIGANDS | APPROXIMATION | BEHAVIOR | ISOMERIZATION | ENANTIOSELECTIVE HYDROGENATIONS | CHEMISTRY, ORGANIC | MONODENTATE LIGANDS | SUPRAMOLECULAR BIDENTATE LIGANDS | HYDROFORMYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2010, Volume 49, Issue 19, pp. 3346 - 3350
Open wide and say AAA: The copper‐free asymmetric allylic alkylation reaction of Grignard reagents, catalyzed by N‐heterocyclic carbenes, is reported for allyl... 
Grignard reagents | allylic substitution | asymmetric catalysis | carbene ligands | LIGANDS | CATALYZED CONJUGATE ADDITION | COMPLEXES | N-HETEROCYCLIC CARBENES | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | Carbene ligands | Asymmetric catalysis | Allylic substitution
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3705 - 3709
The graphene oxide (GO) assisted allylic alkylation of thiophenes with alcohols is presented. Mild reaction conditions and a low GO loading enabled the... 
OXIDATION | SOLVENT-FREE CONDITIONS | CHEMISTRY, ORGANIC | GRAPHITE OXIDE | FRIEDEL-CRAFTS ALKYLATION | CARBON NANOTUBES | S(N)2 REACTION | INDOLES | GOLD-CATALYZED SYNTHESIS | CASCADE REACTION | CARBOCATALYSIS
Journal Article
by Yang, GH and Li, Y and Li, X and Cheng, JP
CHEMICAL SCIENCE, ISSN 2041-6520, 04/2019, Volume 10, Issue 15, pp. 4322 - 4327
A novel biscinchona alkaloid-catalyzed highly enantioselective desymmetrization reaction of bisphenol compounds with achiral Morita-Baylis-Hillman carbonate... 
PHOSPHORUS LIGANDS | MORITA-BAYLIS-HILLMAN | ASYMMETRIC-SYNTHESIS | CATALYZED DESYMMETRIZATION | ACID | GAMMA-BUTENOLIDES | STEREOGENIC PHOSPHINES | ALLENES | REDUCTIVE ALDOL REACTION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 8, pp. 2054 - 2057
In accessing trisubstituted vinyl boronates from terminal alkynes, a propargyl directing (2-pyridyl)sulfonyl group allows terminal alkynes to undergo... 
CATALYZED HYDROBORATION | SITE | BORATION | BORON | ESTERS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | COPPER | ALLYLIC SUBSTITUTION | GRIGNARD-REAGENTS | CONJUGATE ADDITION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2018, Volume 24, Issue 23, pp. 6277 - 6281
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 13, pp. 2239 - 2247
The emerging and versatile application of chiral bisphosphine ligands in diverse asymmetric reactions has resulted in great demand for novel bisphosphine... 
TETRAHYDRO-BETA-CARBOLINES | SPINOL-PHOSPHORIC ACIDS | HYDROGENATION REACTIONS | DIPHOSPHINE LIGANDS | AMINATION | CATALYZED ENANTIOSELECTIVE ALLYLATION | TRIFLUOROMETHYLATED QUATERNARY STEREOCENTERS | CHEMISTRY, ORGANIC | BEARING | FRIEDEL-CRAFTS REACTION | INDOLES | Ligands | Chemical reactions | Asymmetry | Chemical synthesis | Alkylation
Journal Article