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alpha,beta-unsaturated carbonyl-compounds (26) 26
chemistry, organic (23) 23
beta-boration (22) 22
chemistry, multidisciplinary (15) 15
catalyzed beta-boration (14) 14
borylation (11) 11
diboron reagents (11) 11
n-heterocyclic carbenes (10) 10
allylic carbonates (9) 9
copper (9) 9
esters (9) 9
lewis-base adducts (8) 8
asymmetric-synthesis (7) 7
copper-catalyzed reaction (7) 7
alkenes (6) 6
alpha,beta-unsaturated esters (6) 6
boron (6) 6
conjugate additions (6) 6
copper boryl complexes (6) 6
efficient route (6) 6
boron conjugate additions (5) 5
catalysis (5) 5
chemistry, inorganic & nuclear (5) 5
conjugate addition (5) 5
cross-coupling reaction (5) 5
platinum-catalyzed diboration (5) 5
transition-metal-complexes (5) 5
alkynes (4) 4
chemical properties (4) 4
complexes (4) 4
diboration (4) 4
diboron (4) 4
diboron compounds (4) 4
enantioselective diboration (4) 4
enantioselective synthesis (4) 4
hydroboration (4) 4
ligands (4) 4
molecular-structures (4) 4
tertiary (4) 4
asymmetric catalysis (3) 3
asymmetric induction (3) 3
bisdiboron (3) 3
boron compounds - chemistry (3) 3
boron conjugate addition (3) 3
boronic acids (3) 3
carboboration (3) 3
catalyzed hydroboration (3) 3
crystallography, x-ray (3) 3
kupfer (3) 3
metal-free diboration (3) 3
one-pot synthesis (3) 3
oxidative addition (3) 3
stereoisomerism (3) 3
synthesis (3) 3
additions (2) 2
alkoxides (2) 2
alpha (2) 2
analysis (2) 2
asymmetric beta-boration (2) 2
asymmetric-catalysis (2) 2
asymmetrische katalyse (2) 2
asymmetry (2) 2
b bond (2) 2
boration (2) 2
boron compounds - chemical synthesis (2) 2
boronic acids - chemistry (2) 2
c-13 splittings (2) 2
carbenes (2) 2
carbonyl-compounds (2) 2
catalyzed diboration (2) 2
chemistry, applied (2) 2
chemistry, physical (2) 2
conjugated compounds (2) 2
copper - chemistry (2) 2
cross-coupling reactions (2) 2
density-functional theory (2) 2
efficient (2) 2
efficient synthesis (2) 2
enantio-selectivity (2) 2
enantiomers (2) 2
enantioselective beta-boration (2) 2
enantioselectivity (2) 2
enantioselektivität (2) 2
enones (2) 2
field gradient (2) 2
generalized gradient approximation (2) 2
intramolecular cyanoboration (2) 2
magnetic-resonance spectra (2) 2
nucleophilic boron (2) 2
optical activity (2) 2
organoboronic esters (2) 2
organocatalysis (2) 2
palladium-catalyzed borylation (2) 2
planar (2) 2
quadrupolar nuclei (2) 2
reactivity (2) 2
reagents (2) 2
regioselectivity (2) 2
research (2) 2
residual dipolar couplings (2) 2
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Chemical Reviews, ISSN 0009-2665, 08/2016, Volume 116, Issue 16, pp. 9091 - 9161
Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural... 
PALLADIUM-CATALYZED BORYLATION | LEWIS-BASE ADDUCTS | N-HETEROCYCLIC CARBENE | CROSS-COUPLING REACTION | TRANSITION-METAL-COMPLEXES | ONE-POT SYNTHESIS | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | B-B BOND | BORON CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC BETA-BORATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 4/2012, Volume 41, Issue 9, pp. 3558 - 357
Boron compounds have been traditionally regarded as Lewis acids preferring to accept electrons rather than donate them in the course of their reactions but... 
MAGNESIUM ALKOXIDES | ALLYLIC CARBONATES | CU-CATALYZED HYDROBORATION | EFFICIENT ROUTE | ENANTIOSELECTIVE DIBORATION | COPPER(I) BORYL COMPLEXES | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | CONJUGATED COMPOUNDS | DIBORON REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | BETA-BORATION
Journal Article
Nature communications, ISSN 2041-1723, 2014, Volume 5, Issue 1, p. 4245
Transition metal reagents and catalysts are generally effective to cleave all three bonds (one sigma and two pi) in a triple bond despite its high bonding... 
B BOND | LEWIS-BASE ADDUCTS | MONOXIDE | MULTIDISCIPLINARY SCIENCES | TERT-BUTYLAZADIBORIRIDINE | N-HETEROCYCLIC CARBENES | DIBORON COMPOUNDS | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | BETA-BORATION | CATALYZED CLEAVAGE | MOLECULAR-OXYGEN
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2013, Volume 52, Issue 14, pp. 3989 - 3992
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2015, Volume 13, Issue 43, pp. 10691 - 10698
... in asymmetric beta-boration of acyclic enones, giving a variety of chiral beta-boryl ketones in good yields and enantioselectivities... 
ALKENES | TRIAZOLIUM SALTS | LIGANDS | ESTERS | COMPLEXES | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | PLANAR | BORON CONJUGATE ADDITIONS | BORYLATION | CATALYZED DIBORATION
Journal Article
Synthesis, ISSN 0039-7881, 07/2014, Volume 46, Issue 14, pp. 1924 - 1932
Abstract Three-component carboboration of alkenes takes place efficiently by the reaction with a diboron compound and carbon electrophiles with the aid of a... 
special topic | carboboration | copper | equol | alkenes | multicomponent reaction | ALLYLIC CARBONATES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | ALPHA | BORONIC ESTERS | ALKYNES | COPPER(I)-CATALYZED REACTION | BETA-BORATION | INTRAMOLECULAR CYANOBORATION | DIBORON
Journal Article
Chemical Science, ISSN 2041-6520, 5/2014, Volume 5, Issue 6, pp. 2428 - 2437
Diboron compounds are a part of a relatively unexplored, yet immensely useful, class of compounds. Their main use is for β-boration reactions where a boron... 
QUADRUPOLAR NUCLEI | FIELD GRADIENT | RESIDUAL DIPOLAR COUPLINGS | RESOLUTION | MAGNETIC-RESONANCE SPECTRA | DENSITY-FUNCTIONAL THEORY | CATALYZED BETA-BORATION | DIBORON COMPOUNDS | C-13 SPLITTINGS | CHEMISTRY, MULTIDISCIPLINARY | GENERALIZED GRADIENT APPROXIMATION
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2014, Volume 5, Issue 6, pp. 2428 - 2437
Diboron compounds are a part of a relatively unexplored, yet immensely useful, class of compounds. Their main use is for β-boration reactions where a boron... 
Journal Article
Synthesis, ISSN 0039-7881, 11/2017, Volume 49, Issue 21, pp. 4775 - 4782
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 12/2010, Volume 14, Issue 20, pp. 2531 - 2548
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2013, Volume 355, Issue 18, pp. 3527 - 3531
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2015, Volume 51, Issue 47, pp. 9594 - 9607
Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a major challenge still remains: very few boron-centered nucleophiles... 
BRIDGING GUANIDINATE LIGANDS | LEWIS-BASE ADDUCTS | SOLID-STATE NMR | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | COPPER(I) BORYL COMPLEXES | N-HETEROCYCLIC CARBENES | ALKOXY DIBORON REAGENTS | ANIONIC DIMETALLOBORYLENE COMPLEX | CATALYZED BETA-BORATION | METAL-FREE DIBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Nature chemistry, ISSN 1755-4330, 2011, Volume 3, Issue 11, pp. 894 - 899
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2009, Volume 74, Issue 3, pp. 1297 - 1303
Potassium trifluoroboratoketohomoenolates were prepared in good yields from either the corresponding α,β-unsaturated compounds or methyl ketones. These... 
SILOXYCYCLOPROPANES | ALPHA,BETA-UNSATURATED KETONES | ACYLATION | BIS(PINACOLATO)DIBORON | ESTERS | ZINC HOMOENOLATE | CHEMISTRY | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CATALYZED BETA-BORATION | ARYL CHLORIDES
Journal Article
Organic Letters, ISSN 1523-7060, 02/2012, Volume 14, Issue 3, pp. 890 - 893
Borylation of alkyl halides with diboron proceeded in the presence of a copper(I)/Xantphos catalyst and a stoichiometric amount of K(O-t-Bu) base. The boryl... 
SINGLE ELECTRON-TRANSFER | ENANTIOSELECTIVE SYNTHESIS | ALLYLIC CARBONATES | EFFICIENT ROUTE | ESTERS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | DIBORON REAGENTS | ORGANIC HALIDES | COPPER-CATALYZED BORYLATION | BETA-BORATION
Journal Article