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Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 945 - 955
The isomerization of simple terminal alkenes to internal isomers with Z-stereochemistry is rare, because the more stable E-isomers are typically formed. We... 
CHAIN-WALKING | ALLYL ETHERS | CATALYZED ISOMERIZATION | HOMOGENEOUS CATALYSIS | RUTHENIUM | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | OPEN-SHELL ORGANOMETALLICS | HYDRIDE COMPLEXES | 3-COORDINATE | METATHESIS | Usage | Research | Cobalt | Olefins | Isomerization
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2016, Volume 8, Issue 3, pp. 209 - 219
Exploiting the reactivity of one functional group within a molecule to generate a reaction at a different position is an ongoing challenge in organic... 
CATALYZED HYDROBORATION | CHAIN-WALKING | ALLYLIC ALCOHOLS | INTERNAL ALKENES | HECK ARYLATIONS | UNSATURATED ALCOHOLS | BIFUNCTIONAL CATALYST | C-H ACTIVATION | NONCONJUGATED DIENES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION REACTIONS | Organic chemistry | Inorganic chemistry | Chemical Sciences
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2018, Volume 2018, Issue 25, pp. 3317 - 3325
Novel chiral gold(III) complexes, based on bisoxazoline (BOX) and 2‐pyridyl‐(–)menthol ligands, were prepared and characterised (X‐ray), and their catalytic... 
Cycloaddition | Isomerization | Homogeneous catalysis | Diastereoselectivity | GOLD(I)-CATALYZED RING EXPANSION | COMPLEXES | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | REARRANGEMENT | KETONES | ALKENES | INTERMOLECULAR REACTIONS | GOLD-CATALYZED CYCLOISOMERIZATION | PROPARGYLIC CARBOXYLATES | ENYNES | Cyclopropane compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2014, Volume 20, Issue 43, pp. 13918 - 13922
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2012, Volume 48, Issue 53, pp. 6630 - 6632
A bi-enzymatic cascade for the redox-isomerisation of allylic alcohol is presented. Coupling of an alcohol dehydrogenase to an enoate reductase has been... 
REDUCTIONS | OXIDATION | ALLYLIC ALCOHOLS | CATALYZED ISOMERIZATION | REDUCTASE | CHEMISTRY, MULTIDISCIPLINARY | OLD YELLOW ENZYME | Propanols - chemistry | Biocatalysis | Oxidation-Reduction | Models, Biological | Isomerism | Alcohol Dehydrogenase - chemistry | Hydrogen-Ion Concentration
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2015, Volume 56, Issue 45, pp. 6159 - 6169
[Display omitted] In this digest, we report the recent advances in asymmetric isomerization of allylic alcohols. We present the different aspects of this... 
Catalysis | Allylic alcohols | Isomerization | Chirality | Atom economy | CATALYZED ISOMERIZATION | COMPLEXES | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | ALDEHYDES | ENANTIOSELECTIVE ISOMERIZATION | ALLYLAMINES | REDUCTION | RUTHENIUM(II) | KINETIC RESOLUTION | REDOX ISOMERIZATION | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 25, pp. 10357 - 10360
Although controlling both the position of the double bond and E:Z selectivity in alkene isomerization is difficult, 1 is a very efficient catalyst for... 
DOUBLE-BOND ISOMERIZATION | ETHERS | TRANSITION-METAL-COMPLEXES | ALLYLIC ALCOHOLS | IRIDIUM-CATALYZED ISOMERIZATION | BIFUNCTIONAL CATALYST | O-ALLYL | CARBONYL-COMPOUNDS | RUTHENIUM | REDOX ISOMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | Olefins | Analysis | Isomerization | Chemical bonds | Amides | Chemical properties | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18308 - 18310
Organofluorophosphonium salts of the formula [(C6F5)3–x Ph x PF][B(C6F5)4] (x = 0, 1) exhibit Lewis acidity derived from a low-lying σ* orbital at P opposite... 
ACTIVATION | CARBON | MECHANISM | COMPLEXES | SILICON | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | Organofluorine compounds | Chemical properties | Research | Olefins | Isomerization
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 38, pp. 10629 - 10631
A transition metal-free Heck-type cyclization/isomerization reaction has been developed. Mediated by potassium tertbutoxide and phenanthroline a variety of... 
STYRENES | CATALYZED ADDITION | AMINATION | INTRAMOLECULAR ARYLATION | PHENOLS | ARYL HALIDES | CHLORIDES | C-H ACTIVATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
ChemSusChem, ISSN 1864-5631, 02/2020, Volume 13, Issue 4, pp. 693 - 697
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2004, Volume 126, Issue 35, pp. 10858 - 10859
The cycloisomerization of 1,5-enynes catalyzed by cationic triphenylphosphinegold(I) complexes produces bicyclo[3.1.0]hexenes. Substitution at all positions of... 
SILYL ENOL ETHERS | CARBOCYCLIZATION | EXPANSION | GOLD(III) | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CATALYZED CYCLOISOMERIZATION REACTIONS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 50, pp. 16442 - 16447
Journal Article