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Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 49, pp. 14805 - 14809
The first example of metal‐free hydrosilylation polymerization between dienes and disilanes is developed by using a borane catalyst, B(C6F5)3 to replace... 
hydrosilylation | polymerization | metal‐free catalysis | borane catalyst | polycarbosilanes | metal-free catalysis | COMPLEX | MECHANISM | LEWIS-ACID | RUTHENIUM | TRANSFER RADICAL POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | CATIONIC-POLYMERIZATION | ALKENES | SILYLATIVE REDUCTION | HYDROSILATION | B(C6F5)-CATALYZED HYDROSILYLATION | Polymerization
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2009, Volume 48, Issue 27, pp. 4957 - 4960
Going fishing! The sulfonium borane [1]+ complexes cyanide in pure water at the maximum allowable concentration of 50 ppb recommended by the European Union.... 
boranes | sulfur | sensors | water | cyanides | Water | Boranes | Cyanides | Sensors | Sulfur | APICAL ALKYL GROUP | LEWIS ACIDITY ENHANCEMENT | ANION | OPTICAL-PROPERTIES | COLORIMETRIC DETECTION | CHEMISTRY, MULTIDISCIPLINARY | ANNULAR BOND FORMATION | CATIONIC BORANE | FLUORIDE-ION | 1ST EXAMPLE | COMPLEXATION
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2013, Volume 42, Issue 32, pp. 11652 - 11660
The dihydridoirida-beta-diketone [IrH2{(PPh2(o-C6H4CO))(2)H}] (2) has been used as a homogeneous catalyst for the hydrolysis of ammonia- or amine-boranes to... 
ROOM-TEMPERATURE | NANOPARTICLES | CARBENE | DEHYDROGENATION | RHODIUM | IRIDIUM | TRANSITION-METAL | COMPLEXES | REACTIVITY | DIMETHYLAMINE-BORANE | CHEMISTRY, INORGANIC & NUCLEAR | Hydrolysis | Ammonia | Hydrogen storage | Amines | Equivalence | Catalysts | Cationic | Hydrides
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2008, Volume 130, Issue 33, pp. 10890 - 10891
Journal Article
Tetrahedron, ISSN 0040-4020, 03/2019, Volume 75, Issue 9, pp. 1123 - 1129
We describe the synthesis and properties of a series of sulfonium boranes featuring a dimesitylboryl unit and a dimethylsulfonium or methylphenyl sulfonium... 
ELECTRON | BORON | FLUORIDE-ION COMPLEXATION | CYANIDE IONS | NONLINEAR-OPTICAL PROPERTIES | CHEMISTRY, ORGANIC | LEWIS ACIDITY | DERIVATIVES | ANION-BINDING PROPERTIES | CATIONIC BORANES | WATER | Structure | Analysis | Crystals
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2010, Volume 16, Issue 43, pp. 12920 - 12927
Journal Article
Macromolecules, ISSN 0024-9297, 03/2010, Volume 43, Issue 5, pp. 2261 - 2267
Newly discovered N-heterocyclic carbene-boryl radicals (NHC-BH2 •) derived from readily available N-heterocyclic carbene−boranes are found to be efficient... 
CENTERED RADICALS | VISIBLE-LIGHT | ELECTRON-SPIN-RESONANCE | LASER FLASH-PHOTOLYSIS | POLYMER SCIENCE | BOND-DISSOCIATION ENERGIES | HOMOLYTIC REACTIONS | BORYL RADICALS | LIGATED BORANES | ACYLGERMANE-BASED PHOTOINITIATOR | CATIONIC-POLYMERIZATION
Journal Article
Organometallics, ISSN 0276-7333, 02/2014, Volume 33, Issue 4, pp. 964 - 973
To investigate phosphine to borane through-space charge transfer and its utility in anion sensing and the formation of metal complexes, a phosphine–borane... 
CHARGE-TRANSFER EMISSION | POLYMERS | MOLECULAR-STRUCTURE | BMES | ION COMPLEXATION | CHEMISTRY, ORGANIC | CRYSTAL | 3-COORDINATE ORGANOBORON COMPOUNDS | CATIONIC BORANES | WATER | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Polymer Chemistry, ISSN 1759-9954, 07/2014, Volume 5, Issue 16, pp. 4726 - 4733
Narrowly distributed poly( epsilon -caprolactone) (PCL) was synthesized by the ring-opening polymerization (ROP) of epsilon -caprolactone (CL) using... 
Controllers | Bulk polymerization | Catalysts | Programmable logic devices | Initiators | Polymerization | Benzyl alcohol | MPEG encoders
Journal Article
Organometallics, ISSN 0276-7333, 01/2012, Volume 31, Issue 1, pp. 31 - 34
The heteroleptic complexes (C ∧ N)2IrIII (C ∧ N: ppy, 2; btp, 3), bearing a 4-(dimesitylboryl)­benzoate (Bbz) auxiliary ligand, and their fluoride adducts were... 
LIGHT-EMITTING-DIODES | ORGANOBORON COMPOUNDS | CYCLOMETALATED IRIDIUM COMPLEXES | CHEMISTRY, ORGANIC | METAL CHELATION | TRIARYLBORON | IR(III) COMPLEX | ELECTRON-ACCEPTING ABILITY | TRANSFER EMISSION | CATIONIC BORANES | ANION-BINDING | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2018, Volume 57, Issue 18, pp. 11696 - 11703
We report a novel example of supramolecular cages containing a Lewis acidic trigonal boron center. Self-assembly of the tris­(pyridyl)­borane donor 1 with... 
COORDINATION CHEMISTRY | BORON-NITROGEN BONDS | DELAYED FLUORESCENCE | FLUORIDE BINDING | METAL CHELATION | 3-COORDINATE ORGANOBORON COMPOUNDS | LEWIS ACIDITY | ELECTRON-ACCEPTING ABILITY | TRANSFER EMISSION | CATIONIC BORANES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 08/2012, Volume 41, Issue 30, pp. 9067 - 9072
Titanium-phosphorus frustrated Lewis pairs (FLPs) based on titanocene-phosphinoaryloxide complexes have been synthesised. The cationic titanium(IV) complex... 
ROOM-TEMPERATURE | PI-DONATION | COMPLEXES | REACTIVITY | CHEMISTRY | POLYMERIZATION | TITANIUM | CLEAVAGE | DIMERS | METAL-FREE | CHEMISTRY, INORGANIC & NUCLEAR | Reduction (chemical) | Hydrogen storage | Catalysts | Cationic | Dehydrogenation | Activation | Catalysis
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 25, pp. 3729 - 3731
In H2O-CHCl3, the phosphonium borane [ortho-(Mes(2)B)C6H4(PMePh2)](+) selectively complexes azide anions to afford ortho-(Mes(2)(N-3)B)C6H4(PMePh2) in which... 
ANIONS | LEWIS ACIDITY ENHANCEMENT | CATIONIC BORANE | FLUORIDE-ION | COMPLEXATION | SALTS | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION | WATER | Organic chemistry | Chemical Sciences
Journal Article
Macromolecules, ISSN 0024-9297, 03/2007, Volume 40, Issue 5, pp. 1413 - 1420
Borane-end-functionalized polymers have been prepared through (i) atom transfer radical polymerization (ATRP) of styrene using a silylated initiator,... 
TERPYRIDINE METAL-COMPLEXES | CHAIN-TRANSFER AGENTS | POLYMER SCIENCE | ACID | SUPRAMOLECULAR POLYMERS | LIVING CATIONIC-POLYMERIZATION | COPOLYMERS | HALOBORATION | BOROXINE | MEDIATED OLEFIN POLYMERIZATION | ELECTROLYTES
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2012, Volume 48, Issue 65, pp. 8096 - 8098
The reactions of Me2NH center dot BH3 with cationic Rh(III) and Ir(III) complexes have been shown to generate the 18-electron aminoborane adduct... 
RHODIUM | IRIDIUM | AGOSTIC INTERACTIONS | METAL CENTERS | MOLECULAR-STRUCTURES | AMINE-BORANES | AMMONIA-BORANE | C-H ACTIVATION | METHYLAMINE-BORANE | CHEMISTRY, MULTIDISCIPLINARY | BORYL | Catalysts | Cationic | Dehydrogenation | Neutron diffraction | X-rays | Boranes | Catalysis | Adducts
Journal Article
Polymer Chemistry, ISSN 1759-9954, 08/2014, Volume 5, Issue 16, pp. 4726 - 4733
Narrowly distributed poly(epsilon-caprolactone) (PCL) was synthesized by the ring-opening polymerization (ROP) of epsilon-caprolactone (CL) using... 
POLYMERS | POLYMER SCIENCE | ZWITTERIONIC POLYMERIZATION | HIGH-MOLECULAR-WEIGHT | B(C6F5) | LACTIDE | CATIONIC-POLYMERIZATION
Journal Article
Polymer Chemistry, ISSN 1759-9954, 2/2011, Volume 2, Issue 3, pp. 625 - 631
Eight N-heterocyclic carbene-boranes (NHC-boranes) are proposed as new efficient co-initiators for acrylatephotopolymerization reactions. They are particularly... 
CENTERED RADICALS | OXYGEN | PHOTOINITIATORS | ELECTRON-SPIN-RESONANCE | POLYMER SCIENCE | ALKYL | BORYL RADICALS | LIGATED BORANES | COMPLEXES | REACTIVITY | CATIONIC-POLYMERIZATION | Rate constants | Alkenes | Lasers | Photopolymerization | Boranes | Flash photolysis | Carbenes | Radicals
Journal Article