IEEE Transactions on Power Delivery, ISSN 0885-8977, 02/2017, Volume 32, Issue 1, pp. 254 - 262
c-C 4 F 8 and CF 3 I and their mixtures have garnered much attention as possible substitutes for SF 6 due to their excellent electrical strength and minimal...
Gases | Temperature distribution | Electric potential | saturated vapor pressure | gas insulation | Sulfur hexafluoride | CF3 I-N2 | electric breakdown | SF6 substitute | c-C4F8-N2 | Mathematical model | Electric fields
Gases | Temperature distribution | Electric potential | saturated vapor pressure | gas insulation | Sulfur hexafluoride | CF3 I-N2 | electric breakdown | SF6 substitute | c-C4F8-N2 | Mathematical model | Electric fields
Journal Article
Nature Chemistry, ISSN 1755-4330, 08/2016, Volume 8, Issue 8, pp. 768 - 777
Organofluorine compounds are central to modern chemistry, and broadly applicable transformations that generate them efficiently and enantioselectively are in...
CINCHONA ALKALOIDS | KETONES | TRIFLUOROMETHYL GROUP | HYDROGEN-BOND ACCEPTOR | ALLYLATION | ORGANOCATALYSIS | STETTER REACTION | ORGANIC FLUORINE | CF3 GROUP | CHEMISTRY, MULTIDISCIPLINARY | 2-FLUOROETHANOL | Organic chemistry | Ammonium | Organofluorine compounds | Catalysts | Ketones | Fluorine | Reagents | Antiparasitic agents | Transformations | Enantiomers | Electrostatic properties | Alcohols
CINCHONA ALKALOIDS | KETONES | TRIFLUOROMETHYL GROUP | HYDROGEN-BOND ACCEPTOR | ALLYLATION | ORGANOCATALYSIS | STETTER REACTION | ORGANIC FLUORINE | CF3 GROUP | CHEMISTRY, MULTIDISCIPLINARY | 2-FLUOROETHANOL | Organic chemistry | Ammonium | Organofluorine compounds | Catalysts | Ketones | Fluorine | Reagents | Antiparasitic agents | Transformations | Enantiomers | Electrostatic properties | Alcohols
Journal Article
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Full Text
Synthesis and structural features of N-[(2-(trimethylsilyl)oxy)phenyl]-arylsulfonamides
Journal of Molecular Structure, ISSN 0022-2860, 12/2019, Volume 1198, p. 126782
N-[(2-(Trimethylsilyl)oxy)phenyl]-4-methylbenzenesulfonamide and N-[(2-trimethylsilyloxy)phenyl]-4-chlorobenzenesulfonamide were prepared by two different...
N-[(2-(trimethylsilyl)oxi)phenyl]sulfonamides | DFT calculations | H-bonding | Crystal structure | FTIR spectroscopy | DESIGN | N-(2-HYDROXYPHENYL)ACETAMIDE | CHEMISTRY, PHYSICAL | SULFONAMIDE DERIVATIVES | MEDICINAL CHEMISTRY | CF3 | X-RAY | GAS-PHASE | INHIBITORS | SPECTROSCOPIC CHARACTERIZATIONS
N-[(2-(trimethylsilyl)oxi)phenyl]sulfonamides | DFT calculations | H-bonding | Crystal structure | FTIR spectroscopy | DESIGN | N-(2-HYDROXYPHENYL)ACETAMIDE | CHEMISTRY, PHYSICAL | SULFONAMIDE DERIVATIVES | MEDICINAL CHEMISTRY | CF3 | X-RAY | GAS-PHASE | INHIBITORS | SPECTROSCOPIC CHARACTERIZATIONS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2017, Volume 23, Issue 7, pp. 1557 - 1567
A series of tris‐, bis‐, and mono(pentafluoroethyl)bismuthanes of the type (C2F5)nBiX3–n (X=F, Cl, Br, I) and transition metal complexes are accessible by a...
alkylation | fluorinated ligands | synthetic methods | bismuth | fluorine | MOLECULAR-STRUCTURE | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | TRIS(TRIFLUOROMETHYL)BISMUTH | ELEMENTS | RAY CRYSTAL-STRUCTURES | FLUORIDE-ION AFFINITIES | CHEMISTRY | GENERATION | DERIVATIVES | BI(CF3)3 | Bismuth | Chemical properties | Transition metals | Molecular structure | Perfluoroalkyls | Accessibility | Bismuth compounds | Coordination compounds | X ray diffraction
alkylation | fluorinated ligands | synthetic methods | bismuth | fluorine | MOLECULAR-STRUCTURE | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | TRIS(TRIFLUOROMETHYL)BISMUTH | ELEMENTS | RAY CRYSTAL-STRUCTURES | FLUORIDE-ION AFFINITIES | CHEMISTRY | GENERATION | DERIVATIVES | BI(CF3)3 | Bismuth | Chemical properties | Transition metals | Molecular structure | Perfluoroalkyls | Accessibility | Bismuth compounds | Coordination compounds | X ray diffraction
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2019, Volume 2019, Issue 31, pp. 3612 - 3618
The fluorinated trityl alcohols (C6F5)3COH, (C6H2F3)3COH and (C6(CF3)2H3)3COH were prepared in good to excellent yields by one‐step procedures. These alcohols...
Fluorinated ligands | Acidity | Density functional calculations | Alcohols | O ligands | AGOC(CF3) | ANIONS | COORDINATION CHEMISTRY | ALKOXIDE | COMPLEXES | FEATURES | CHEMISTRY, INORGANIC & NUCLEAR | SCALE | BASIS-SET | DERIVATIVES | Nuclear magnetic resonance spectroscopy | Hydrogen-ion concentration | Mass spectrometry | Analysis | Infrared spectroscopy | Nuclear magnetic resonance--NMR | Phenols | Alcohol | Lithium | Chemical synthesis | Fluorination
Fluorinated ligands | Acidity | Density functional calculations | Alcohols | O ligands | AGOC(CF3) | ANIONS | COORDINATION CHEMISTRY | ALKOXIDE | COMPLEXES | FEATURES | CHEMISTRY, INORGANIC & NUCLEAR | SCALE | BASIS-SET | DERIVATIVES | Nuclear magnetic resonance spectroscopy | Hydrogen-ion concentration | Mass spectrometry | Analysis | Infrared spectroscopy | Nuclear magnetic resonance--NMR | Phenols | Alcohol | Lithium | Chemical synthesis | Fluorination
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 02/2018, Volume 206, pp. 54 - 60
Syntheses of salts of perfluoroalkyltrifluoroborate anions [R BF ] starting from perfluoroalkyltrimethoxyborates, potassium bifluoride, and mineral or organic...
Ionic liquids | Perfluoroalkyltrifluoroborates | Nucleophilic fluorination | Brønsted acid catalysis | Olah reagent | DIFLUOROCARBENE | HYDROPHOBIC IONIC LIQUIDS | (TRIFLUOROMETHYL)GERMANIUM | CHEMISTRY, ORGANIC | SALTS | CHEMISTRY, INORGANIC & NUCLEAR | Bronsted acid catalysis | CHEMISTRY | PERFLUOROETHYLTRIFLUOROBORATE | (CF3)(N)SNX(4-N) | DERIVATIVES | Hydrochloric acid | Fluorides | Catalysis | Acetic acid | Organic acids
Ionic liquids | Perfluoroalkyltrifluoroborates | Nucleophilic fluorination | Brønsted acid catalysis | Olah reagent | DIFLUOROCARBENE | HYDROPHOBIC IONIC LIQUIDS | (TRIFLUOROMETHYL)GERMANIUM | CHEMISTRY, ORGANIC | SALTS | CHEMISTRY, INORGANIC & NUCLEAR | Bronsted acid catalysis | CHEMISTRY | PERFLUOROETHYLTRIFLUOROBORATE | (CF3)(N)SNX(4-N) | DERIVATIVES | Hydrochloric acid | Fluorides | Catalysis | Acetic acid | Organic acids
Journal Article
Russian Chemical Bulletin, ISSN 1066-5285, 12/2001, Volume 50, Issue 12, pp. 2381 - 2383
UV irradiation of the long-lived radical [(CF3)2CF]2C·C2F5 (1) in a hexafluoropropylene trimer (HFPT) glassy matrix at 77 K and in a HFPT solution at 300 K...
long-lived perfluoroalkyl radical | photodecomposition | ESR spectroscopy | Chemistry | CF 3 radical | Chemistry/Food Science, general | Long-lived perfluoroalkyl radical | radical | Photodecomposition | (CF3)-C-center dot radical | CHEMISTRY, MULTIDISCIPLINARY
long-lived perfluoroalkyl radical | photodecomposition | ESR spectroscopy | Chemistry | CF 3 radical | Chemistry/Food Science, general | Long-lived perfluoroalkyl radical | radical | Photodecomposition | (CF3)-C-center dot radical | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 10/1996, Volume 69, Issue 10, pp. 2923 - 2933
The total syntheses of monofluoroporphyrin derivatives from monofluoropyrroles and the reconstitution of synthetic heme into sperm-whale myoglobin are...
DYNAMIC PROPERTIES | H-1-NMR | MECHANISM | ELECTRONIC ABSORPTION | CRYSTAL-STRUCTURES | SPERM WHALE MYOGLOBIN | SPECTRA | CHEMISTRY, MULTIDISCIPLINARY | WITHDRAWING CF3 GROUPS | HEME ORIENTATION | MCD
DYNAMIC PROPERTIES | H-1-NMR | MECHANISM | ELECTRONIC ABSORPTION | CRYSTAL-STRUCTURES | SPERM WHALE MYOGLOBIN | SPECTRA | CHEMISTRY, MULTIDISCIPLINARY | WITHDRAWING CF3 GROUPS | HEME ORIENTATION | MCD
Journal Article
Plasma Chemistry and Plasma Processing, ISSN 0272-4324, 6/1999, Volume 19, Issue 2, pp. 285 - 298
The drift of TEOS etch rate has been observed during MERIE oxide etch for the damascene process. The etch rate typically fluctuates between 5300 Å/min and 6000...
polymer | deposition | Physics | hysteresis | Oxide | emission | Nuclear Physics, Heavy Ions, Hadrons | Le Chatelier's principle | Mechanics | Inorganic Chemistry | Mechanical Engineering | etch | plasma | Characterization and Evaluation Materials | fluorocarbon | Plasma | Etch | Le chatelier's principle | Emission | Polymer | Fluorocarbon | Deposition | Hysteresis | SYSTEM | PHYSICS, APPLIED | EMISSION-SPECTRA | PHYSICS, FLUIDS & PLASMAS | CF4/O2 | SILICON | PLASMAS | ENGINEERING, CHEMICAL | CF3 | oxide | RADICALS | DIAGNOSTICS | SIO2
polymer | deposition | Physics | hysteresis | Oxide | emission | Nuclear Physics, Heavy Ions, Hadrons | Le Chatelier's principle | Mechanics | Inorganic Chemistry | Mechanical Engineering | etch | plasma | Characterization and Evaluation Materials | fluorocarbon | Plasma | Etch | Le chatelier's principle | Emission | Polymer | Fluorocarbon | Deposition | Hysteresis | SYSTEM | PHYSICS, APPLIED | EMISSION-SPECTRA | PHYSICS, FLUIDS & PLASMAS | CF4/O2 | SILICON | PLASMAS | ENGINEERING, CHEMICAL | CF3 | oxide | RADICALS | DIAGNOSTICS | SIO2
Journal Article
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