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Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 34, pp. 9948 - 9953
Journal Article
ChemCatChem, ISSN 1867-3880, 01/2016, Volume 8, Issue 2, pp. 434 - 440
The synthesis, characterization, and ethylene polymerization properties of a series of xanthene‐bridged dinuclear α‐diimine NiII complexes are described. The... 
polymerization | cooperativity effects | binuclear catalysts | chain-walking polymerization | Ni catalysts
Journal Article
Macromolecules, ISSN 0024-9297, 01/2018, Volume 51, Issue 1, pp. 49 - 56
Molecular weight and molecular-weight distribution are two critical parameters that determine the properties of a polyolefin material. In this contribution, we... 
POLAR MONOMERS | CHAIN-WALKING | POLYOLEFINS | INSERTION | POLYMER SCIENCE | ALPHA-DIIMINE CATALYSTS | COMPLEXES | OLEFIN POLYMERIZATION | HOMOPOLYMERIZATION | INITIATORS | POLYETHYLENE
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2015, Volume 5, Issue 1, pp. 122 - 128
1-Hexene polymerizations were carried out with amine–imine nickel complexes [(ArNC­(R1)–(R2R3)­CNHAr)­NiBr2, 1a, R1 = R2 = R3 = Me, Ar = 2,6-(iPr)2C6H3; 1b,... 
chain walking | regioselectivity | nickel | 1-hexene | ETHYLENE-PROPYLENE COPOLYMERS | CHAIN-WALKING | ALPHA-OLEFINS | LATE-METAL-CATALYSTS | DIIMINE NI(II) CATALYST | LIVING POLYMERIZATION | CHEMISTRY, PHYSICAL | SYNDIOTACTIC-SPECIFIC POLYMERIZATION | BRANCH FREQUENCY | NMR ANALYSIS | PRECISION POLYETHYLENE
Journal Article
Macromolecules, ISSN 0024-9297, 08/2017, Volume 50, Issue 16, pp. 6074 - 6080
As a promising alternative to thermoset elastomers, thermoplastic elastomers (TPEs) have attracted much attention because of their unique properties, including... 
CHAIN-WALKING | POLYMER SCIENCE | BLOCK-COPOLYMERS | LIGAND BACKBONE | COMPLEXES | OLEFIN POLYMERIZATION | LIVING POLYMERIZATION | ATTRACTIVE INTERACTIONS | OCTENE COPOLYMERS | BRANCHED POLYETHYLENE | ALPHA-DIIMINE CATALYST
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 428 - 441
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2019, Volume 9, Issue 3, pp. 2400 - 2406
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2016, Volume 8, Issue 3, pp. 209 - 219
Exploiting the reactivity of one functional group within a molecule to generate a reaction at a different position is an ongoing challenge in organic... 
CATALYZED HYDROBORATION | CHAIN-WALKING | ALLYLIC ALCOHOLS | INTERNAL ALKENES | HECK ARYLATIONS | UNSATURATED ALCOHOLS | BIFUNCTIONAL CATALYST | C-H ACTIVATION | NONCONJUGATED DIENES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION REACTIONS | Organic chemistry | Inorganic chemistry | Chemical Sciences
Journal Article
Catalysis Communications, ISSN 1566-7367, 04/2019, pp. 23 - 26
2,3-Bis[(2,6-diisopropylphenylimino)butane] nickel/MAO system toward ethylene polymerization displays two active sites with ultraviolet absorption bands at 456... 
Chain walking | Chain transfer | Active site selectivity | Ethylene | Polyethylene microstructure
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 945 - 955
The isomerization of simple terminal alkenes to internal isomers with Z-stereochemistry is rare, because the more stable E-isomers are typically formed. We... 
CHAIN-WALKING | ALLYL ETHERS | CATALYZED ISOMERIZATION | HOMOGENEOUS CATALYSIS | RUTHENIUM | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | OPEN-SHELL ORGANOMETALLICS | HYDRIDE COMPLEXES | 3-COORDINATE | METATHESIS | Usage | Research | Cobalt | Olefins | Isomerization
Journal Article
Polymer Chemistry, ISSN 1759-9954, 04/2017, Volume 8, Issue 15, pp. 2405 - 2409
In this work, ethylene copolymerization and terpolymerization reactions with some nitrogen-containing monomers were investigated using a-diimine palladium and... 
CHAIN-WALKING | INSERTION | POLYMER SCIENCE | ETHYLENE | NORBORNENE | ALPHA-DIIMINE CATALYSTS | OLEFIN POLYMERIZATION | LIGAND | COPOLYMERIZATION | GAS-TRANSPORT | POLYETHYLENE
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2019, Volume 880, pp. 261 - 266
Journal Article
Polymer, ISSN 0032-3861, 10/2017, Volume 127, pp. 88 - 100
A series of higher 2-alkenes, i.e., 2-pentene, 2-hexene and 2-octene were polymerized with phenyl substituted α-diimine nickel complexes in combination with... 
α-Diimine nickel complex | 2-Hexene | 2-Pentene | Chain-walking | 2-Octene | Living polymerization | POLYMER SCIENCE | ISOMERIZATION | COMPLEXES | OLEFIN POLYMERIZATION | CHAIN-WALKING POLYMERIZATION | alpha-Diimine nickel complex | ETHYLENE POLYMERIZATION | NI(II) | POLYETHYLENE | SEC-PHENETHYL GROUPS | COPOLYMERIZATION | TRANS-2-BUTENE
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2015, Volume 5, Issue 10, pp. 5932 - 5937
The synthesis, characterization, and olefin (co)­polymerization studies of a series of palladium complexes bearing phosphine phosphonic amide ligands were... 
copolymerization | palladium | olefin polymerization | phosphine ligands | polar monomer | CHAIN-WALKING | ALPHA-OLEFINS | INSERTION POLYMERIZATION | CHEMISTRY, PHYSICAL | DIMERIZATION | NICKEL(II) | ALKYL COMPLEXES | VINYL ETHERS | LIGANDS | REMOTE SUBSTITUENTS | CATALYSTS
Journal Article
Polymer, ISSN 0032-3861, 02/2019, Volume 164, pp. 26 - 32
The steric effect of the α-diimine nickel catalyst on allylcyclohexane (ACH) and vinylcyclohexane (VCH) polymerizations has been studied with the aim of... 
Chain walking | Alkenylcyclohexane | Steric effect | CHAIN-WALKING | PALLADIUM | POLYMER SCIENCE | VINYL-POLYMERIZATION | COMPLEXES | POLAR MONOMER | ETHYLENE POLYMERIZATION | ISOSPECIFIC POLYMERIZATION | PRECISION SYNTHESIS | NORBORNENE | COPOLYMERIZATION | Catalysts | Bulk polymerization | Aromatic compounds | Isomerization | Polymerization | Insertion | Nickel | Catalysis | Polymers | Monomers
Journal Article
Organometallics, ISSN 0276-7333, 06/2016, Volume 35, Issue 11, pp. 1794 - 1801
A series of α-diimine ligands with different substituents on the acenaphthyl backbone were synthesized and characterized. The corresponding Ni­(II) and Pd­(II)... 
CHAIN-WALKING | OLEFIN POLYMERIZATION CATALYSTS | INSERTION | TEMPERATURE | COMPLEXES | LIVING POLYMERIZATION | CHEMISTRY, ORGANIC | BRANCHED POLYETHYLENE | COPOLYMERIZATION | NICKEL(II) | VINYL ETHERS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 23, pp. 7290 - 7293
A highly enantioselective and site-selective Pd-catalyzed arylation of alkenes linked to carbonyl derivatives to yield α,β-unsaturated systems is reported. The... 
CHAIN-WALKING | PALLADIUM | CATALYZED OXIDATION | ALLYLIC ALCOHOLS | STRATEGY | ARYLATION | OXIDASE CATALYSIS | ASYMMETRIC HECK | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN | CONJUGATE ADDITION
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 03/2019, Volume 55, Issue 19, pp. 2769 - 2772
The operationally simple palladium-catalyzed double-bond migration without heteroatom-containing coordinating functional groups is described. Addition of TaCl5... 
CHAIN-WALKING | ALCOHOLS | ALKENES | METALS | STRATEGY | ISOMERIZATION | COMPLEXES | CARBONYL-COMPOUNDS | CYCLOISOMERIZATION | SYSTEMS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Macromolecules, ISSN 0024-9297, 05/2014, Volume 47, Issue 10, pp. 3325 - 3331
Chiral (1S)- and (1R)-camphyl α-diimine nickel complexes were synthesized respectively with (1S)-(+) camphorquinone and (1R)-(−) camphorquinone as raw reagents... 
CHAIN-WALKING | POLYMER SCIENCE | C-13 | SYNDIOTACTIC-SPECIFIC POLYMERIZATION | LIVING POLYMERIZATION | NI(II) CATALYST | ETHYLENE POLYMERIZATION | NMR ANALYSIS | COPOLYMERIZATION | SCHIFF-BASE COMPLEXES | MICROSTRUCTURE
Journal Article