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Science China Chemistry, ISSN 1674-7291, 11/2015, Volume 58, Issue 11, pp. 1663 - 1673
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 51, pp. 15520 - 15524
The facile and reversible interconversion between neutral and oxidized forms of palladium complexes containing ferrocene‐bridged phosphine sulfonate ligands... 
copolymerization | palladium catalysis | olefin polymerization | polar monomers | redox chemistry | CHAIN-WALKING | MONOMERS | INSERTION POLYMERIZATION | METAL-CATALYSTS | ACRYLATE | TRANSFER RADICAL POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYLENE | LIGANDS | BIS(IMINO)PYRIDINE IRON | Oligomers | Carbocyclic compounds | Iron compounds | Olefins | Polymerization | Palladium | Metallocenes | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 34, pp. 9948 - 9953
Journal Article
Macromolecules, ISSN 0024-9297, 03/2015, Volume 48, Issue 5, pp. 1304 - 1312
The polymerization of ethylene with late transition metal complexes typically provides highly branched amourphous poly(ethylene)s through a chain-walking... 
CHAIN-WALKING | POLYMER SCIENCE | NICKEL | BEHAVIOR | LATE-TRANSITION-METAL | LIVING POLYMERIZATION | RECENT PROGRESS | C-13 NMR | POLYETHYLENE | ARCHITECTURES | ETHYLENE-OCTENE COPOLYMERS
Journal Article
Macromolecules, ISSN 0024-9297, 12/2016, Volume 49, Issue 23, pp. 8855 - 8862
In the Brookhart type α-diimine palladium catalyst system, it is highly challenging to tune the polymer branching densities through ligand modifications or... 
CHAIN-WALKING | POLYOLEFINS | INSERTION | POLYMER SCIENCE | MOLECULAR-WEIGHT POLYETHYLENE | TEMPERATURE ETHYLENE POLYMERIZATION | LIVING POLYMERIZATION | NICKEL(II) COMPLEXES | BRANCHED POLYETHYLENE | METHYL ACRYLATE | VINYL ETHERS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11604 - 11609
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 428 - 441
Journal Article
Macromolecules, ISSN 0024-9297, 06/2011, Volume 44, Issue 11, pp. 4125 - 4139
We report in this article the “arm-first” synthesis of core–shell-structured multiarm polyethylene (PE) star polymers having multiple linear-but-branched PE... 
ALPHA-OLEFINS | POLYMER SCIENCE | HYPERBRANCHED POLYETHYLENES | RING INCORPORATION | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | CHAIN WALKING COPOLYMERIZATION | SHAPED POLYMERS | PD-DIIMINE CATALYST | CATIONIC-POLYMERIZATION | BRANCHED POLYETHYLENES
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2015, Volume 5, Issue 1, pp. 122 - 128
1-Hexene polymerizations were carried out with amine–imine nickel complexes [(ArNC­(R1)–(R2R3)­CNHAr)­NiBr2, 1a, R1 = R2 = R3 = Me, Ar = 2,6-(iPr)2C6H3; 1b,... 
chain walking | regioselectivity | nickel | 1-hexene | ETHYLENE-PROPYLENE COPOLYMERS | ALPHA-OLEFINS | STEREOCHEMISTRY | DIIMINE NI(II) CATALYST | LIVING POLYMERIZATION | CHEMISTRY, PHYSICAL | POLYETHYLENE | 4-METHYL-1-PENTENE | SYNDIOTACTIC-SPECIFIC POLYMERIZATION | BRANCH FREQUENCY | NMR ANALYSIS
Journal Article
Polymer Chemistry, ISSN 1759-9954, 05/2017, Volume 8, Issue 18, pp. 2785 - 2795
Five types of unsymmetrical bis(arylimino) acenaphthenes, 1-[2,4,6-(CHPh2)(3)C6H2N]-2-(ArN)C2C10H6 (Ar = 2,6-Me2Ph L1, 2,6-Et2Ph L2, 2,6-i-Pr2Ph L3,... 
CHAIN-WALKING | POLYMERS | BRANCHES | POLYMER SCIENCE | BLOCK-COPOLYMERS | POLYMERIZATION SYNTHESIS | STABILITY | COMPLEXES | LIVING POLYMERIZATION | THERMOPLASTIC ELASTOMERS | POLYOLEFIN ELASTOMERS
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2017, Volume 7, Issue 11, pp. 7490 - 7494
The majority of work in the field of olefin polymerization catalysis has been focused on ligand modifications. In this work, we describe an alternative... 
palladium catalyst | redox control | olefin polymerization | switchable polymerization | polar monomer | CHAIN-WALKING | PALLADIUM | COMPLEXES | CHEMISTRY, PHYSICAL | POLYETHYLENE | (CO)POLYMERIZATION | ETHYLENE | LIGANDS | LACTIDE | COPOLYMERIZATION | CATALYSTS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2009, Volume 48, Issue 6, pp. 1089 - 1092
A new ligand–metal combination (see picture, Ni green, Br brown, N blue, O red, C gray) was designed to be cationic and to benefit from removal of electron... 
nickel | polymerization | homogeneous catalysis | substituent effects | Polymerization | Substituent effects | Nickel | Homogeneous catalysis | CHAIN-WALKING | COMPLEXES | LIVING POLYMERIZATION | NI(II) CATALYST | TRANSITION-METAL-CATALYSTS | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | METHYLALUMINOXANE | VINYL MONOMERS | PROPYLENE | COPOLYMERIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 6, pp. 1535 - 1538
Single‐crystal X‐ray characterization of cationic (α‐diimine)Ni‐ethyl and isopropyl β‐agostic complexes, which are key intermediates in olefin polymerization... 
β-agostic interactions | nickel | inverse kinetic isotope effect | polymerization intermediates | CHAIN-WALKING | ALPHA-OLEFINS | beta-agostic interactions | COMPLEXES | OLEFIN POLYMERIZATION | ETHYLENE POLYMERIZATION | NICKEL(II) | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | TEMPERATURE | COPOLYMERIZATION | CATALYSTS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 07/2019, Volume 55, Issue 53, pp. 7607 - 7610
Design and synthesis of a Ni(ii) "sandwich" alpha-diimine complex (1) resulted in a switchable catalyst for the living polymerisation of ethylene over a range... 
CHAIN-WALKING | BLOCK COPOLYMERIZATION | INSERTION | TEMPERATURE | BEHAVIOR | COMPLEXES | OLEFIN POLYMERIZATION | MECHANICAL-PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | POLYETHYLENE | ELASTOMERS
Journal Article