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Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 51, pp. 13432 - 13436
Journal Article
Catalysis Communications, ISSN 1566-7367, 04/2019, Volume 123, pp. 23 - 26
2,3-Bis[(2,6-diisopropylphenylimino)butane] nickel/MAO system toward ethylene polymerization displays two active sites with ultraviolet absorption bands at 456... 
Chain walking | Chain transfer | Active site selectivity | Ethylene | Polyethylene microstructure | POLYOLEFINS | CATALYZED OLEFIN POLYMERIZATION | STRATEGY | BEHAVIOR | COMPLEXES | CHEMISTRY, PHYSICAL | CHAIN-WALKING POLYMERIZATION | MONOMER | NICKEL | COPOLYMERIZATION
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2010, Volume 46, Issue 42, pp. 7879 - 7893
The innovation of polyolefin with unique architecture, composition and topology continues to inspire polymer chemists. An exciting recent direction in the... 
N-HETEROCYCLIC CARBENE | NI(II)-CATALYZED POLYMERIZATION | SINGLE-SITE CATALYSTS | METALLOCENE CATALYSTS | PALLADIUM-COMPLEXES | CHAIN-WALKING POLYMERIZATION | STRUCTURAL-CHARACTERIZATION | ALPHA-DIIMINE CATALYST | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | NEUTRAL NICKEL(II) CATALYSTS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 07/2019, Volume 55, Issue 53, pp. 7607 - 7610
Design and synthesis of a Ni(ii) "sandwich" alpha-diimine complex (1) resulted in a switchable catalyst for the living polymerisation of ethylene over a range... 
CHAIN-WALKING | BLOCK COPOLYMERIZATION | INSERTION | TEMPERATURE | BEHAVIOR | COMPLEXES | OLEFIN POLYMERIZATION | MECHANICAL-PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | POLYETHYLENE | ELASTOMERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2018, Volume 140, Issue 19, pp. 6062 - 6066
The Rh-catalyzed, remote terminal hydroarylation of active olefins at the C7-position of indoles and the ortho-position of indolines and anilines with the... 
CHAIN-WALKING | FUNCTIONALIZATION | ALKENYL ALCOHOLS | C-H ARYLATION | HECK ARYLATIONS | QUATERNARY STEREOCENTERS | CARBONYL-COMPOUNDS | BOND | CHEMISTRY, MULTIDISCIPLINARY | REDOX-RELAY STRATEGY | ACID ESTERS | Chemical properties | Rhodium | Chemical compounds | Isomerization | Analysis
Journal Article
Nature Communications, ISSN 2041-1723, 02/2017, Volume 8, Issue 1, p. 14200
Combining functionalization at a distant position from a reactive site with the creation of several consecutive stereogenic centres, including the formation of... 
CHAIN-WALKING | ALCOHOLS | ORGANIC-SYNTHESIS | ALKENE ISOMERIZATION | INTERNAL ALKENES | MULTIDISCIPLINARY SCIENCES | ARYL HALIDES | C-C BONDS | QUATERNARY STEREOCENTERS | REDOX-RELAY STRATEGY | H ACTIVATION | Organic chemistry | Inorganic chemistry | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 23, pp. 7729 - 7732
We report the first observed Pd-catalyzed isomerization (“cage-walking”) of B(9)-bromo-meta-carborane during Pd-catalyzed cross-coupling, which enables the... 
CHAIN-WALKING | ALKENES | ICOSAHEDRAL CARBORANES | CHEMISTRY | STRUCTURAL-CHARACTERIZATION | ELIMINATION | ARYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | B-H ACTIVATION | METAL-COMPLEXES | LIGAND DESIGN | Usage | Analysis | Isomerization | Chemical bonds | Ligands | Palladium | Research | Chemical properties
Journal Article
Macromolecules, ISSN 0024-9297, 06/2018, Volume 51, Issue 11, pp. 4040 - 4048
Late-transition-metal catalysts have great potentials to incorporate polar comonomers during olefin polymerization. The preparation of polar-functionalized... 
ALPHA-OLEFINS | FREE-RADICAL COPOLYMERIZATION | NICKEL-CATALYSTS | POLYMER SCIENCE | INSERTION POLYMERIZATION | ACID COPOLYMERS | VINYL MONOMERS | OLEFIN POLYMERIZATION | PHOSPHINE-SULFONATE PALLADIUM | CHAIN-WALKING POLYMERIZATION | CATALYZED ETHYLENE POLYMERIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11604 - 11609
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 24, pp. 7636 - 7639
An inhibitory role of 1,5-cyclooctadiene (COD) in nickel-catalyzed C–H functionalization processes was identified and studied. The bound COD participates in... 
CHAIN-WALKING | BOND OXIDATIVE ADDITION | ACTIVATION | COMPLEX | FLUOROBENZENES | FLUORINATED AROMATICS | ALKYNES | HYDROHETEROARYLATION | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | BORYLATION | Computational chemistry | Usage | Alkadienes | Nickel | Chemical properties | Catalysis | Research
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 51, pp. 15520 - 15524
The facile and reversible interconversion between neutral and oxidized forms of palladium complexes containing ferrocene‐bridged phosphine sulfonate ligands... 
copolymerization | palladium catalysis | olefin polymerization | polar monomers | redox chemistry | CHAIN-WALKING | MONOMERS | INSERTION POLYMERIZATION | METAL-CATALYSTS | ACRYLATE | TRANSFER RADICAL POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYLENE | LIGANDS | BIS(IMINO)PYRIDINE IRON | Oligomers | Carbocyclic compounds | Iron compounds | Olefins | Polymerization | Palladium | Metallocenes | Catalysis
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 06/2019, Volume 33, Issue 6, pp. e4911 - n/a
Upon activation with diethylaluminium chloride (Et2AlCl), a series of phenyl‐substituted α‐diimine nickel precatalysts conducted 4‐methyl‐1‐pentene (4MP) and... 
chain‐walking polymerization | nickel complex | ethylene | 4‐methyl‐1‐pentene | 4-methyl-1-pentene | chain-walking polymerization | Nuclear magnetic resonance--NMR | Molecular weight distribution | Ethylene | Elastomers | Polymerization | Chain branching | Insertion | Glass transition temperature | Molecular weight | Substitutes | Copolymers | Nickel | Polymers
Journal Article
Macromolecules, ISSN 0024-9297, 09/2018, Volume 51, Issue 17, pp. 6818 - 6824
Ethylene-co-acrylic acid (E–AA) copolymers are typically produced via high-pressure free radical copolymerization and have great industrial importance because... 
POLYMER SCIENCE | ETHYLENE | MOLECULAR-WEIGHT POLYETHYLENE | NICKEL-CATALYST | POLAR VINYL MONOMERS | OLEFIN POLYMERIZATION | CHAIN-WALKING POLYMERIZATION | ACRYLATE | LIGAND | COORDINATION-INSERTION COPOLYMERIZATION | (CO)POLYMERIZATION
Journal Article
Organometallics, ISSN 0276-7333, 02/2019, Volume 38, Issue 3, pp. 614 - 625
New substituted 5-aryl-2-(N-2,6-diisopropyl-phenylformimino)-1H-pyrrole ligand precursors reacted with the complex trans-[Ni(o-C6H4Cl)(PPh3)(2)Cl] to give rise... 
NICKEL-COMPLEXES | VINYLIC POLYMERIZATION | CHELATE LIGANDS | NORBORNENE | METHYL-METHACRYLATE | PD-DIIMINE | CHAIN WALKING POLYMERIZATION | CHEMISTRY, ORGANIC | C-13 NMR | COPOLYMERIZATION | WEIGHT HYPERBRANCHED POLYETHYLENES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 08/2019, Volume 10, Issue 30, pp. 7246 - 7250
A regioselective and enantioselective palladium-catalyzed relay Heck alkenylation of alkenylbenzene derivatives to construct remote stereocenters is disclosed.... 
CHAIN-WALKING | ALCOHOLS | STRATEGY | DOUBLE-BOND MIGRATION | HECK ARYLATIONS | ISOMERIZATION | COMPLEXES | NONCOVALENT INTERACTIONS | REMOTE | CHEMISTRY, MULTIDISCIPLINARY | ALKENOLS
Journal Article