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2007, ISBN 9783527308255, xix, 571
The first comprehensive coverage of all facets of the Claisen rearrangement and its variants. As such, this book helps synthetic chemists to exploit the vast... 
Claisen rearrangement | Chemical reactions | Catalysts | Organopalladium compounds
Book
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 3, pp. 885 - 888
A highly efficient asymmetric cascade reaction between alkynyl esters and allylic alcohols has been realized. Key to success was the combination of a... 
gold | nickel | asymmetric catalysis | Claisen rearrangement | hydroalkoxylation | HIGHLY ENANTIOSELECTIVE SYNTHESIS | ALLYLIC ALKYLATION | ROSKAMP REACTION | CHEMISTRY, MULTIDISCIPLINARY | CASCADE REACTION | HOMOALLYLIC KETONES | COOPERATIVE CATALYSIS | BETA-KETOESTERS | ALIPHATIC CLAISEN REARRANGEMENT | DUAL CATALYSIS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 27, pp. 6927 - 6931
A catalytic [1,3] O‐to‐C rearrangement from enyne‐ethers was developed for the rapid synthesis of diverse bridged bicyclic systems. In this reaction, a vinyl... 
[1,3]-rearrangement | gold | ring-expansion reactions | bridged bicycles | [3,3]-rearrangement | 1,3 O | ORGANIC-SYNTHESIS | HYDROALKOXYLATION/CLAISEN REARRANGEMENT | CLAISEN REARRANGEMENT | CHEMISTRY, MULTIDISCIPLINARY | NONDIAZO APPROACH | CYCLOADDITION | YNAMIDES | ETHERS | CYCLIZATION | C-H INSERTION | Ethers | Chemical synthesis | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 38, pp. 11557 - 11561
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 29, pp. 9078 - 9082
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 18, pp. 5956 - 5961
Presented herein is an intriguing effect of fluorine, and it allows difluoroenol silyl ethers to couple with aryliodanes in a redox‐neutral manner to afford... 
hypervalent iodine | difluoromethylation | reduction | rearrangements | fluorine | FUNCTIONALIZATIONS | ALPHA-ARYLATION | ALPHA,ALPHA-DIFLUOROARYLACETIC ACIDS | CHEMISTRY, MULTIDISCIPLINARY | MILD | KETONES | IODONIO-CLAISEN REARRANGEMENT | HYPERVALENT | GENERATION | EFFICIENT | Fluorides | Iodides | Ethers | Fluorine | Aromatic compounds | Substrates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 4015 - 4019
An efficient yttrium‐catalyzed intramolecular hydroalkoxylation/Claisen rearrangement sequence has been achieved, thus enabling facile access to a diverse... 
homogeneous catalysis | yttrium | heterocycles | cyclization | rearrangements | ELECTROPHILIC REARRANGEMENTS | GOLD CATALYSIS | CHIRAL YNAMIDES | C-H FUNCTIONALIZATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | CASCADE REACTION | ETHERS | CLAISEN-TYPE REARRANGEMENT | RING-CLOSING METATHESIS | LACTONES | Rare earth metals | Catalysis | Yttrium | Cascade chemical reactions
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 2-3, pp. 605 - 610
The organocatalytic [2,3]‐Wittig rearrangement of allyloxyketones was investigated. Extensive screening of chiral amine organocatalysts showed that small... 
Allylic compounds | Sigmatropic rearrangement | Ketones | Asymmetric catalysis | Organocatalysis | CATALYSIS | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE CLAISEN REARRANGEMENTS
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2017, Volume 73, Issue 16, pp. 2173 - 2190
From what began as a casual discovery of the ketene-Claisen rearrangement (the Malherbe-Belluš rearrangement) over 3 decades ago has flourished a reaction of... 
Zwitterion-aza-ketene | Thia-ketene (allylic thioethers) | Ketene-Claisen (allylic ethers) | Aza-ketene (allylic amines) | Rearrangements | ALLYL ETHERS | ASYMMETRIC-SYNTHESIS | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | ACETALS | TERTIARY | DICHLOROKETENE | CYCLOADDITIONS | ESTERS | 1,2-ASYMMETRIC INDUCTION | LACTAMS | Chemotherapy | Cancer
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 29, pp. 8529 - 8532
An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4‐dienes under the catalysis of... 
enantioselectivity | gold | alkoxylation | desymmetrization | Claisen rearrangement | INTRAMOLECULAR CARBOALKOXYLATION | ACTIVATION | ASYMMETRIC CLAISEN REARRANGEMENT | GOLD CATALYSIS | COMPLEXES | TRANSITION-STATE | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITION | CHIRALITY | SELECTION | ALLYL VINYL ETHERS | Enantiomers | Catalysis | Formations | Transformations | Gold | enantioselective
Journal Article