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Catalysis Science and Technology, ISSN 2044-4753, 2018, Volume 8, Issue 13, pp. 3395 - 3405
Metal hydrides play important roles in catalysis for sustainable energy, the environment, the petrochemical industry, and many important chemical processes.... 
H-H | DEHYDROGENATION | MECHANISM | LIGANDS | CATALYTIC-HYDROGENATION | COMPLEXES | CHEMISTRY, PHYSICAL | STRUCTURAL-CHARACTERIZATION | BASIS-SETS | H-2 ACTIVATION | CLEAVAGE | Lewis acid | Organic chemistry | Metal hydrides | Electronic structure | Reactivity | Alkenes | Bridging | Chemical reactions | Density functional theory | Product design | Catalysis | Coordination compounds
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2016, Volume 116, Issue 15, pp. 8373 - 8426
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen bond, are crucial intermediates in numerous nickel-catalyzed reactions.... 
C-H BOND | TRANSITION-METAL-COMPLEXES | MECHANISTIC INSIGHTS | PINCER COMPLEXES | SI-H | OXIDATIVE-ADDITION | DONOR ABILITIES | STRUCTURAL-CHARACTERIZATION | CARBON-CARBON BONDS | TETRAKIS(TRIETHYL PHOSPHITE)NICKEL HYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | Molecules | Enzymes | Nickel | Hydrogen bonds | Crystallography
Journal Article
Dalton Transactions, ISSN 1477-9226, 1524, Volume 42, Issue 33, pp. 11987 - 11991
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 07/2018, Volume 39, Issue 19, pp. 1177 - 1191
Journal Article
International Journal of Hydrogen Energy, ISSN 0360-3199, 04/2013, Volume 38, Issue 11, pp. 4533 - 4576
This report summarizes the 5-year R&D activities within the U.S. Department of Energy Metal Hydride Center of Excellence (MHCoE). The purpose of the MHCoE was... 
Hydrogen storage materials | Destabilized hydrides | Amides | Complex metal hydrides | Alane | Borohydrides | SYSTEM | LIBH4 | ELECTROCHEMISTRY | ENERGY & FUELS | CHEMISTRY, PHYSICAL | MAGNESIUM | METHODOLOGY | MG-N-H | 1ST-PRINCIPLES CALCULATIONS | Hydrogen | Analysis | Energy development
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 41, pp. 10377 - 10381
A Golden Gate: Alkynylspirocyclopropanes served as a template for the development of gold-catalyzed hydride transfer from unactivated C(sp super(3))--H bonds... 
gold | homogeneous catalysis | hydride transfer | C(sp | cyclization | H bond cleavage | C(sp3)?H bond cleavage | ACTIVATION | C-H BOND | RING EXPANSIONS | TERMINAL ALKYNES | SULFONAMIDES | REARRANGEMENTS | CHEMISTRY, MULTIDISCIPLINARY | FISCHER CARBENE COMPLEXES | CYCLOISOMERIZATION | METAL | Cleavage | Hydrides | Gates | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 52, pp. 16654 - 16659
Reaction of Ba[N(SiMe 3 ) 2 ] 2 with PhSiH 3 in toluene gave simple access to the unique Ba hydride cluster Ba 7 H 7 [N(SiMe 3 ) 2 ] 7 that can be described as... 
hydrides | self-assembly | barium | reductants | alkaline earth metals | ANION | CHEMICAL-SHIFTS | CRYSTAL-STRUCTURE | AMIDE | COMPLEXES | SPIN-ORBIT | CALCIUM HYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | MAGNESIUM | CHEMISTRY | LIGAND | Structure | Barium | Crystals | Coalescing | Toluene | Clusters | Coalescence | Crystal structure | Intermediates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 4024 - 4027
(1,3‐bis[2,6‐bis[di(4‐tert‐butylphenyl)methyl]‐4‐methylphenyl]imidazol‐2‐ylidene)CuOPh [(IPr**)CuOPh] reacts with poly(methylhydrosiloxane) as the hydride... 
carbenes | copper | hydride | silver | COMPLEXES | REACTIVITY | TERMINAL ALKYNES | CONVENIENT | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIC (ALKYL)(AMINO)CARBENES | INTRAMOLECULAR HYDROIMINIUMATION | X-LIGAND | ALKYL AMINO CARBENES | CATALYTIC-ACTIVITY | Copper | Silver | Monomers
Journal Article