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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3387 - 3391
The first examples of Lewis base catalyzed enantioselective boryl conjugate additions (BCAs) that generate products containing boron‐substituted quaternary... 
enantioselective synthesis | conjugate additions | N‐heterocyclic carbenes | organic synthesis | boron | N-heterocyclic carbenes | HYDROBORATION | ASYMMETRIC-SYNTHESIS | BOND FORMATION | ALDEHYDES | ALKYNES | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | KETONES | BORATION | ESTERS | EFFICIENT | Boron | Conjugates | Utilities | Synthesis | Accessibility | Lewis base | Copper | Carbenes | Carbon | quaternary carbons
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2009, Volume 15, Issue 8, pp. 1939 - 1943
Josi or Mandy? Asymmetric conjugate addition of diboron to acyclic enones catalyzed by copper affords chiral organoboronates that possess a boronate group at... 
copper | asymmetric catalysis | boron | conjugate addition | enones | Conjugate addition | Boron | Copper | Asymmetric catalysis | Enones | 1,4-DIBORATION | ESTERS | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | DIBORON REAGENTS | ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 29, pp. 3668 - 3671
Dehydrogenative coupling of cyclic enones with heteroarenes has been a longstanding challenge because of the competitive ketone dehydrogenation and conjugated... 
ASYMMETRIC CONJUGATE ADDITION | BASE-FREE | C-H OLEFINATION | BOND FUNCTIONALIZATION | SUBSTITUTED CYCLOHEXANONES | OXIDATIVE HECK REACTION | AROMATIC-SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | AEROBIC DEHYDROGENATION | ARYLBORONIC ACIDS | HIGHLY EFFICIENT
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 29, pp. 3668 - 3671
Dehydrogenative coupling of cyclic enones with heteroarenes has been a longstanding challenge because of the competitive ketone dehydrogenation and conjugated... 
Coupling (molecular) | Substitutes | Thiophenes | Regioselectivity | Dehydrogenation | Palladium | Functional groups
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 21, pp. 6324 - 6328
Reported herein is an asymmetric [3+2] cycloaddition reaction of azomethine ylides with β‐trifluoromethyl β,β‐disubstituted enones, a reaction which is enabled... 
azomethine ylides | copper | cycloaddition | heterocycles | P,O ligand | P,O ligand | ASYMMETRIC 1,3-DIPOLAR CYCLOADDITION | CATALYSIS | IMINO ESTERS | NATURAL-PRODUCTS | CARBON QUATERNARY STEREOCENTERS | CHEMISTRY, MULTIDISCIPLINARY | MEDICINAL CHEMISTRY | PIPERIDINE | AMINO-ACID DERIVATIVES | CONSTRUCTION | CONJUGATE ADDITION | Cycloaddition | Enantiomers | Copper | Quaternary | Functional groups | Substrates
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2017, Volume 359, Issue 19, pp. 3347 - 3353
The highly enantioselective N‐acylaminophosphine‐catalyzed challenging asymmetric intermolecular cross Rauhut–Currier reaction of vinyl ketones with... 
phosphines | perfluoroalkyl groups | asymmetric catalysis | enones | Rauhut–Currier reaction | DIPEPTIDE-DERIVED PHOSPHINES | ENANTIOSELECTIVE SYNTHESIS | PYRROLINES | ANNULATION | AMINOPHOSPHINES | CHEMISTRY, ORGANIC | Rauhut-Currier reaction | CYCLOADDITION | MALEIMIDES | CYCLOPENTENES | STEREOGENIC CENTERS | CHEMISTRY, APPLIED | CONJUGATE ADDITION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2013, Volume 78, Issue 4, pp. 1677 - 1681
A new planar and centrally chiral bicyclic 1,2,4-triazolium salt has been synthesized from [2.2]paracyclophane and phenylglycinol. The N-heterocyclic carbene... 
TRIAZOLIUM SALTS | LIGANDS | 1,3-DIENES | IMINES | ESTERS | CHEMISTRY, ORGANIC | ALDEHYDES | CONJUGATE ADDITIONS | BORYLATION | Thermal properties | Measurement | Analysis | Copper compounds | Catalysis | Chemical properties | Chemical synthesis | Surface energy
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17869 - 17881
Catalytic and asymmetric Michael reactions constitute very powerful tools for the construction of new C–C bonds in synthesis, but most of the reports claiming... 
SUBSTITUTED CYANOACETATES | ACYCLIC STEREOSELECTION | ASYMMETRIC CONJUGATE ADDITION | DIELS-ALDER REACTIONS | ALPHA,BETA-UNSATURATED KETONES | 1,3-DICARBONYL COMPOUNDS | QUATERNARY STEREOCENTERS | FRIEDEL-CRAFTS ALKYLATIONS | PHASE-TRANSFER CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | CHIRAL LEWIS-ACID
Journal Article
Organic Letters, ISSN 1523-7060, 02/2016, Volume 18, Issue 4, pp. 716 - 719
Carbonyl compounds bearing a γ-amino group are valuable pharmacologically active targets. Regioselective γ-C–N bond formation is achieved with simple enone... 
NITROETHYLENE | NUCLEOPHILES | DIANIONS | ASYMMETRIC CONJUGATE ADDITION | CHEMISTRY | CHEMISTRY, ORGANIC | ELECTROPHILIC AMINATION | GENERATION | ALDEHYDES | MICHAEL ADDITION | VINYLOGOUS ESTERS | Combinatorial Chemistry Techniques | Amination | Nitrogen - chemistry | Ketones - chemical synthesis | Stereoisomerism | Ketones - chemistry | Molecular Structure | Catalysis
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2019, Volume 361, Issue 1, pp. 176 - 184
Catalysts generated by combinations of Pd(TFA)2 and enantiomerically pure pyridine‐hydrazone ligands have been applied to the 1,4‐addition of arylboronic acids... 
Hydrazones | Palladium | Asymmetric Catalysis | N Ligands | Arylboronic acids | COMPLEXES | CHEMISTRY, ORGANIC | DECARBOXYLATIVE ALLYLIC ETHERIFICATION | BIS-HYDRAZONES | ARYL | CHEMISTRY, APPLIED | CHIRAL DIENE | CONJUGATE ADDITION | Substitutes | Catalysts | Natural products | Aromatic compounds | Ligands | Catalysis
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2013, Volume 78, Issue 21, pp. 11053 - 11058
A bifunctional squaramide-catalyzed sulfa-Michael/aldol cascade reaction initiated by sulfa-Michael addition of mercaptoacetaldehyde to... 
ASYMMETRIC-SYNTHESIS | FACILE SYNTHESIS | STEREOCENTERS | CHEMISTRY, ORGANIC | FLUORINE | ALDEHYDES | DERIVATIVES | EFFICIENT | NITROALKENES | CONJUGATE ADDITION | DIARYLPYRROLINES | Chemical reactions | Chemical properties | Research | Stereochemistry | Organometallic compounds
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2018, Volume 83, Issue 17, pp. 10535 - 10540
A simple, highly efficient and regiospecific method for the direct conversion of 3-O-benzylated as well as silylated glycals into the corresponding enones has... 
OLIGOSACCHARIDES | TRIISOPROPYLSILYL ENOL ETHERS | ANALOGS | N-GLYCOPEPTIDES | CHEMISTRY | CHEMISTRY, ORGANIC | SUGARS | TRIMETHYLSILYL AZIDE | CONJUGATE ADDITIONS | HYPERVALENT IODINE REAGENTS
Journal Article