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coordinated dinitrogen (184) 184
chemistry, inorganic & nuclear (154) 154
chemistry, multidisciplinary (83) 83
molybdenum (56) 56
ammonia (53) 53
nitrogen-fixation (51) 51
chemistry (46) 46
catalytic-reduction (45) 45
chemistry, organic (45) 45
molecular nitrogen (43) 43
ligands (41) 41
side-on (40) 40
reduction (39) 39
nitrogen (34) 34
activation (33) 33
molecular-structure (32) 32
nitrogen fixation (32) 32
reactivity (32) 32
on coordinated dinitrogen (31) 31
crystal-structure (29) 29
dinitrogen complexes (29) 29
end-on (28) 28
reduction pathway (27) 27
electronic-structure (26) 26
fixation (22) 22
protonation (22) 22
tungsten (21) 21
chemical properties (20) 20
crystal-structures (20) 20
cleavage (19) 19
hydrogenation (19) 19
research (19) 19
catalysis (18) 18
functionalization (18) 18
ligand (18) 18
complexes (17) 17
ammonia-synthesis (16) 16
bridging n-2 unit (16) 16
n-n bond (16) 16
dinitrogen (15) 15
index medicus (15) 15
iron (15) 15
n-2 (15) 15
nitrogen - chemistry (15) 15
femo-cofactor (14) 14
molecular structure (14) 14
molybdenum triamidoamine complexes (14) 14
zirconium (14) 14
analysis (13) 13
bis complexes (13) 13
effective core potentials (13) 13
models, molecular (13) 13
mono complexes (13) 13
nitrogenase (13) 13
on-bound dinitrogen (13) 13
spectroscopic properties (13) 13
x-ray structure (13) 13
density functional calculations (12) 12
hydrazido complexes (12) 12
ligating dinitrogen (12) 12
metal-complexes (12) 12
nitrogen compounds (12) 12
organometallic compounds - chemistry (12) 12
ray crystal-structure (12) 12
tungsten-dinitrogen (12) 12
bond-cleavage (11) 11
hydrazine (11) 11
molybdenum complexes (11) 11
imido complexes (10) 10
mechanism (10) 10
n bond-cleavage (10) 10
n-2 hydrogenation (10) 10
ruthenium (10) 10
terminal alkynes (10) 10
carbon-monoxide (9) 9
catalysts (9) 9
density-functional theory (9) 9
hydrazidium complexes (9) 9
molecular calculations (9) 9
molybdenum - chemistry (9) 9
phosphines (9) 9
reductive cleavage (9) 9
structure (9) 9
transition-metal complexes (9) 9
transition-metal-complexes (9) 9
zirconium complexes (9) 9
bond formation (8) 8
chemistry, physical (8) 8
conversion (8) 8
coordinated diazoalkanes (8) 8
crystallography (8) 8
dinitrogen cleavage (8) 8
dinitrogen complex (8) 8
diphosphine coligands (8) 8
gaussian-basis sets (8) 8
synthesis (8) 8
usage (8) 8
3-coordinate molybdenum (7) 7
biological nitrogen-fixation (7) 7
c-h activation (7) 7
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Chemical Science, ISSN 2041-6520, 07/2015, Volume 6, Issue 7, pp. 3940 - 3951
A series of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing metallocene-substituted PNP-pincer ligands is synthesized by the reduction of the... 
REDUCTION | LIGANDS | MOLYBDENUM | COORDINATED DINITROGEN | OXIDATION-STATE | C-ATOM | MIXED-VALENCE COMPLEXES | BEARING | MOLECULAR DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY | PRODUCE AMMONIA
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2015, Volume 2015, Issue 4, pp. 567 - 598
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 17, pp. 5666 - 5669
Newly designed and prepared molybdenum–nitride complexes bearing a mer-tridentate triphosphine as a ligand have been found to work as the most effective... 
N-2 | ACTIVATION | MOLECULAR NITROGEN | CONVERSION | COORDINATED DINITROGEN | C-ATOM | MONO(DINITROGEN) COMPLEXES | TRIPOD LIGAND | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PRODUCE AMMONIA | Ammonia | Oxidation-reduction reaction | Research | Chemical properties | Molybdenum compounds | Catalysts
Journal Article
Dalton Transactions, ISSN 1477-9226, 6/2010, Volume 39, Issue 23, pp. 5415 - 5425
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2015, Volume 54, Issue 19, pp. 9234 - 9247
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2009, Volume 131, Issue 27, pp. 9471 - 9472
Reported N2 complexes of cobalt do not have substantial weakening of the N−N bond. Using diketiminate ligands to enforce three-coordinate geometries, we have... 
REDUCTION | MOLECULAR-STRUCTURE | COORDINATED DINITROGEN | CHEMISTRY | NITROGEN | X-RAY-DIFFRACTION | IRON | CRYSTAL | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PROTONATION | Transition Elements - chemistry | Crystallography, X-Ray | Molecular Structure | Nitrogen - chemistry | Cobalt - chemistry | Schiff bases | Ligands | Chemical properties | Structure | Electric properties
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2011, Volume 3, Issue 2, pp. 120 - 125
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12316 - 12320
Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform... 
hydrides | nitriles | organometallics | titanium | dinitrogen activation | SIDE-ON | NN BOND | COMPLEX | MOLECULAR NITROGEN | COORDINATED DINITROGEN | N-2 CLEAVAGE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | PARTIAL HYDROGENATION | END-ON | Nitrogen | Nitriles | Cyanide | Ammonia | Functional anatomy | Titanium | Nitrogen compounds | Activation | Compatibility | Conversion | Bonding | Functional groups | Diimide
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2009, Volume 48, Issue 40, pp. 7415 - 7419
Breaking up: Reduction of a trivalent titanium complex afforded NN cleavage with formation of TiIV nitride complexes (see structure), which can be converted... 
nitrides | reduction | dinitrogen cleavage | hydrogenation | titanium | Titanium | Nitrides | Dinitrogen cleavage | Reduction | Hydrogenation | SIDE-ON | IMIDO COMPLEXES | CATALYTIC-REDUCTION | MOLECULAR NITROGEN | COORDINATED DINITROGEN | CHEMICAL NITROGEN-FIXATION | ORGANONITROGEN COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | END-ON | N-2 HYDROGENATION | ON-BOUND DINITROGEN
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2008, Volume 130, Issue 29, pp. 9394 - 9405
Journal Article
Chemical Communications, ISSN 1359-7345, 2010, Volume 46, Issue 7, pp. 1013 - 1025
That the inert dinitrogen molecule can act as a ligand to a transition metal complex is one of the key discoveries in inorganic chemistry of the past century.... 
SIDE-ON | BRIDGING N-2 UNIT | COORDINATED DINITROGEN | MOLECULAR-HYDROGEN COMPLEXES | RAY CRYSTAL-STRUCTURES | X-RAY | ZEROVALENT OLEFINIC DERIVATIVES | ON-BOUND DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY | NONCLASSICAL DIHYDROGEN COMPLEXES | N BOND-CLEAVAGE
Journal Article