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coordinated dinitrogen (186) 186
chemistry, inorganic & nuclear (155) 155
chemistry, multidisciplinary (84) 84
molybdenum (57) 57
ammonia (54) 54
nitrogen-fixation (51) 51
chemistry (46) 46
catalytic-reduction (45) 45
chemistry, organic (45) 45
ligands (42) 42
molecular nitrogen (42) 42
side-on (42) 42
reduction (39) 39
activation (34) 34
nitrogen (34) 34
nitrogen fixation (32) 32
reactivity (32) 32
molecular-structure (31) 31
on coordinated dinitrogen (31) 31
crystal-structure (30) 30
dinitrogen complexes (29) 29
end-on (28) 28
reduction pathway (28) 28
electronic-structure (26) 26
fixation (22) 22
protonation (22) 22
crystal-structures (21) 21
tungsten (21) 21
chemical properties (20) 20
cleavage (20) 20
functionalization (20) 20
hydrogenation (19) 19
ligand (19) 19
research (19) 19
catalysis (18) 18
bridging n-2 unit (17) 17
ammonia-synthesis (16) 16
complexes (16) 16
index medicus (16) 16
n-n bond (16) 16
zirconium (16) 16
dinitrogen (15) 15
n-2 (15) 15
nitrogen - chemistry (15) 15
femo-cofactor (14) 14
iron (14) 14
molybdenum triamidoamine complexes (14) 14
analysis (13) 13
bis complexes (13) 13
effective core potentials (13) 13
metal-complexes (13) 13
molecular structure (13) 13
mono complexes (13) 13
nitrogen compounds (13) 13
nitrogenase (13) 13
on-bound dinitrogen (13) 13
spectroscopic properties (13) 13
x-ray structure (13) 13
bond-cleavage (12) 12
hydrazido complexes (12) 12
ligating dinitrogen (12) 12
models, molecular (12) 12
ray crystal-structure (12) 12
tungsten-dinitrogen (12) 12
density functional calculations (11) 11
hydrazine (11) 11
molybdenum complexes (11) 11
organometallic compounds - chemistry (11) 11
mechanism (10) 10
n bond-cleavage (10) 10
n-2 hydrogenation (10) 10
terminal alkynes (10) 10
bond formation (9) 9
carbon-monoxide (9) 9
catalysts (9) 9
density-functional theory (9) 9
hydrazidium complexes (9) 9
imido complexes (9) 9
molecular calculations (9) 9
molybdenum - chemistry (9) 9
phosphines (9) 9
ruthenium (9) 9
structure (9) 9
synthesis (9) 9
transition-metal complexes (9) 9
transition-metal-complexes (9) 9
chemistry, physical (8) 8
conversion (8) 8
coordinated diazoalkanes (8) 8
crystallography (8) 8
dinitrogen cleavage (8) 8
dinitrogen complex (8) 8
diphosphine coligands (8) 8
gaussian-basis sets (8) 8
reductive cleavage (8) 8
transition metals (8) 8
usage (8) 8
zirconium complexes (8) 8
biological nitrogen-fixation (7) 7
c-h activation (7) 7
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Chemical Science, ISSN 2041-6520, 07/2015, Volume 6, Issue 7, pp. 3940 - 3951
A series of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing metallocene-substituted PNP-pincer ligands is synthesized by the reduction of the corresponding monomeric molybdenum... 
REDUCTION | LIGANDS | MOLYBDENUM | COORDINATED DINITROGEN | OXIDATION-STATE | C-ATOM | MIXED-VALENCE COMPLEXES | BEARING | MOLECULAR DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY | PRODUCE AMMONIA
Journal Article
Dalton Transactions, ISSN 1477-9226, 6/2010, Volume 39, Issue 23, pp. 5415 - 5425
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2009, Volume 131, Issue 27, pp. 9471 - 9472
Reported N2 complexes of cobalt do not have substantial weakening of the N−N bond. Using diketiminate ligands to enforce three-coordinate geometries, we have... 
REDUCTION | MOLECULAR-STRUCTURE | COORDINATED DINITROGEN | CHEMISTRY | NITROGEN | X-RAY-DIFFRACTION | IRON | CRYSTAL | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PROTONATION | Transition Elements - chemistry | Crystallography, X-Ray | Molecular Structure | Nitrogen - chemistry | Cobalt - chemistry | Schiff bases | Ligands | Chemical properties | Structure | Electric properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12316 - 12320
Activation and functionalization of N2: A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles (see picture... 
hydrides | nitriles | organometallics | titanium | dinitrogen activation | SIDE-ON | NN BOND | COMPLEX | MOLECULAR NITROGEN | COORDINATED DINITROGEN | N-2 CLEAVAGE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | PARTIAL HYDROGENATION | END-ON | Nitrogen | Nitriles | Cyanide | Ammonia | Functional anatomy | Titanium | Nitrogen compounds | Activation | Compatibility | Conversion | Bonding | Functional groups | Diimide
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2011, Volume 3, Issue 2, pp. 120 - 125
The synthesis of transition metal-dinitrogen complexes and the stoichiometric transformation of their coordinated dinitrogen into ammonia and hydrazine have been the subject of considerable research... 
NITROGEN-FIXATION | ACTIVATION | N-2 | MOLECULAR NITROGEN | FEMO-COFACTOR | COORDINATED DINITROGEN | CHEMISTRY | DENSITY-FUNCTIONAL THEORY | TUNGSTEN-DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY | PROTONATION | Molybdenum - chemistry | Hydrazines - chemistry | Nitrogen - chemistry | Oxidation-Reduction | Pyridines - chemistry | Ligands | Molecular Structure | Ammonia - chemistry | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2008, Volume 130, Issue 29, pp. 9394 - 9405
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2013, Volume 49, Issue 95, pp. 11215 - 11217
A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3... 
SINGLE MOLYBDENUM CENTER | MILD REACTION CONDITIONS | CATALYTIC-REDUCTION | AMMONIA | PINCER LIGANDS | IRON | TUNGSTEN-DINITROGEN | H-2 | MOLECULAR DINITROGEN | COORDINATED N-2 | CHEMISTRY, MULTIDISCIPLINARY | Ligands
Journal Article
Dalton Transactions, ISSN 1477-9226, 6/2012, Volume 41, Issue 25, pp. 7447 - 7453
Quite recently we have found two nitrogen fixation systems catalyzed by molybdenum-dinitrogen complexes under mild reaction conditions... 
NITROGEN-FIXATION | N-2 | ACTIVATION | AMMONIA | COORDINATED DINITROGEN | COMPLEXES | GAMMA-CYCLODEXTRIN | TUNGSTEN-DINITROGEN | SILYLATION | PROTONATION | CHEMISTRY, INORGANIC & NUCLEAR | Ammonia | Reduction | Fixation | Equivalence | Catalysts | Ligands | Transformations | Bearing
Journal Article
Nature Chemistry, ISSN 1755-4330, 01/2010, Volume 2, Issue 1, pp. 30 - 35
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 17, pp. 5666 - 5669
Newly designed and prepared molybdenum–nitride complexes bearing a mer-tridentate triphosphine as a ligand have been found to work as the most effective catalysts toward the catalytic reduction of dinitrogen to ammonia under ambient... 
N-2 | ACTIVATION | MOLECULAR NITROGEN | CONVERSION | COORDINATED DINITROGEN | C-ATOM | MONO(DINITROGEN) COMPLEXES | TRIPOD LIGAND | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PRODUCE AMMONIA | Ammonia | Oxidation-reduction reaction | Research | Chemical properties | Molybdenum compounds | Catalysts
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2015, Volume 2015, Issue 4, pp. 567 - 598
Journal Article