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chemistry, inorganic & nuclear (489) 489
cp-asterisk (391) 391
chemistry, organic (259) 259
chemistry, multidisciplinary (166) 166
chemistry (150) 150
reactivity (127) 127
ligands (112) 112
crystal-structure (102) 102
complexes (99) 99
ruthenium (96) 96
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b-h activation (65) 65
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eta-c5me5 (51) 51
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index medicus (43) 43
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hydrogenation (33) 33
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activation (32) 32
metallaboranes (32) 32
carborane (30) 30
carbonyl-compounds (29) 29
ray crystal-structure (28) 28
structure (28) 28
metallaborane clusters (27) 27
molecular structure (27) 27
sulfur (27) 27
tungsten (27) 27
chemistry, physical (26) 26
iridium complexes (26) 26
synthesis (26) 26
eta-c5me5 moiety (25) 25
soluble carbonyl-compounds (25) 25
organometallic compounds - chemistry (24) 24
boranes (23) 23
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h bond activation (23) 23
iron (23) 23
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methyl acetylene carboxylates (23) 23
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chemical sciences (22) 22
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crystallography, x-ray (19) 19
borylene complexes (18) 18
carbenes (18) 18
chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate ligand (18) 18
cobalt (18) 18
crystallography (18) 18
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gallium (18) 18
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organometallic compounds - chemical synthesis (17) 17
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Accounts of Chemical Research, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1523 - 1533
N-Heterocyclic carbenes (NHCs), especially monodentate ones, have become the ligand of choice for many transition-metal-catalyzed transformations. They... 
ELECTRONIC-PROPERTIES | TRANSITION-METAL-COMPLEXES | RUCL CP-ASTERISK | ALPHA-ARYLATION | NHC | SECONDARY ALKYL-HALIDES | ETA-C5ME5 MOIETY | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | ARYL CHLORIDES | NEGISHI REACTIONS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2010, Volume 49, Issue 39, pp. 6940 - 6952
Journal Article
Chemical Communications, ISSN 1359-7345, 2010, Volume 46, Issue 6, pp. 841 - 861
Electronic and steric ligand effects both play major roles in organometallic chemistry and consequently in metal-mediated catalysis. Quantifying such... 
GOLD(I) COMPLEXES | LEWIS-BASE ADDUCTS | CROSS-COUPLING REACTIONS | TRANSITION-METAL-COMPLEXES | OLEFIN METATHESIS CATALYSTS | RUCL CP-ASTERISK | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURES | X-RAY STRUCTURES | CHEMISTRY, MULTIDISCIPLINARY | NHC PALLADIUM COMPLEXES
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 08/2019, Volume 48, Issue 31, pp. 11743 - 11748
A prospective connection between Hume-Rothery inspired TM/E (TM = transition metal; E = Al, Ga, Zn) complexes and clusters with the related solid-state... 
PALLADIUM | CP-ASTERISK | LIGANDS | CLUSTERS | CHEMISTRY | METAL-RICH MOLECULES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 13, pp. 4203 - 4210
In an effort to isolate the chalcogen-rich niobium analogue of [(Cp*Ta)(3)(-S)(3)((3)-S)(3)BH], the room temperature reaction of [Cp*NbCl4] (Cp* = (5)-C5Me5)... 
BOROHYDRIDES | CP-ASTERISK | MOLYBDENUM | COMPLEXES | REACTIVITY | CHEMISTRY | CUBANE | SULFUR | LIGAND | SULFIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 6, pp. 1947 - 1949
The reaction between haloform, the complexes [Cp*IrCl2(kappa C-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(i) oxide proceeded by... 
OXIDATION | LIGANDS | DEUTERATION | C-H ACTIVATION | CP-ASTERISK-IR(III) COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2018, Volume 57, Issue 20, pp. 12657 - 12664
A series of heteroleptic complexes [Ni­(PEt3)4–n (ECp*) n ] (E = Al, Ga, Cp* = pentamethylcyclopentadienyl, n = 0–4) was prepared and characterized by... 
COORDINATION CHEMISTRY | ENERGY | APPROXIMATION | CLUSTERS | CP-ASTERISK-GA | COMPLEXES | LIGAND | TETRAKIS(TRIETHYLPHOSPHINE)NICKEL | NI | VALENCE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2018, Volume 57, Issue 24, pp. 15198 - 15204
In the presence of 1 equiv of t BuNC, the homolytic cleavage of the FeIII–H bond in the diiron terminal hydride complex [Cp*Fe­(t-H)­(μ-η2:η4-bdt)­FeCp*]­[BF4]... 
NITROGENASE | CP-ASTERISK | CARBON | MECHANISM | REDUCTION | SPECTROSCOPY | FEMO-COFACTOR | INTERMEDIATE | N-2 BINDING | ETA-C5ME5 | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2018, Volume 54, Issue 79, pp. 11112 - 11115
Thiolate-bridged dirhodium and diiridium complexes can facilely realize heterolytic cleavage of H-2 across the metal-sulfur bond to generate the corresponding... 
DIIRON CENTERS | NICKEL-IRON | ACTIVATION | CP-ASTERISK | RHODIUM | REACTIVITY | TRANSFER HYDROGENATION | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | MULTI-IRON COMPLEXES
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2014, Volume 50, Issue 70, pp. 10108 - 10111
A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 45, pp. 16017 - 16029
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 3/2012, Volume 41, Issue 8, pp. 3264 - 3279
This review describes how the incorporation of dicarba- closo -dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead... 
ANTICANCER ACTIVITY | TRANSITION-METAL-COMPLEXES | O-CARBORANYL | CP-ASTERISK-IR | BORON CLUSTERS | ORGANOMETALLIC COMPLEXES | CRYSTAL-STRUCTURES | STRUCTURAL-CHARACTERIZATION | LIGAND-BINDING DOMAIN | CHEMISTRY, MULTIDISCIPLINARY | B-H ACTIVATION
Journal Article