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Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 02/2007, Issue 8, pp. 816 - 819
The discovery of a new generation of highly active and selective ethene trimerisation and tetramerisation catalysts has radically changed the field of olefin... 
Journal Article
Journal of the Chemical Society. Dalton Transactions, ISSN 1477-9226, 01/2007, Issue 8, pp. 816 - 819
The discovery of a new generation of highly active and selective ethene trimerisation and tetramerisation catalysts has radically changed the field of olefin... 
ALPHA-OLEFINS | ORTHO-METHOXYARYL | MECHANISM | SELECTIVE ETHYLENE TRIMERIZATION | COMPLEXES | NITROGEN | CR-PNP | POLYMERIZATION | BRIDGED DIPHOSPHINE LIGAND | METAL OXIDATION-STATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 38, pp. 13459 - 13465
Chromium-based complexes are among the most important catalysts in the field of ethylene polymerization and oligomerization. Heterogeneous Cr Phillips... 
TRICHLORIDES SYNTHESIS | MECHANISM | ACTIVE-SITE | OLEFIN POLYMERIZATION | TRI-/TETRAMERIZATION | CR-PNP | CR/SIO2 CATALYST | OLIGOMERIZATION | TRIMERIZATION CATALYSTS | COPOLYMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie - International Edition, ISSN 0570-0833, 2012, Volume 51, Issue 6, pp. 1366 - 1369
Small change, big difference: The introduction of an additional CH sub(2) group into the bridge of ligands with two P/N units leads to a different selectivity... 
tetramerization | chromium | oligomerization | 1-octene | ethylene | MECHANISTIC INVESTIGATIONS | OLIGOMERIZATION REACTIONS | POLYMERIZATION | CHAIN GROWTH | METAL OXIDATION-STATE | CHEMISTRY, MULTIDISCIPLINARY | DIPHOSPHINE LIGANDS | TRIAZACYCLOHEXANE COMPLEXES | ETHENE TRIMERIZATION | CR-PNP | CHROMIUM CATALYSTS | Purity | Bridges (structures) | Ligands | Selectivity | Catalysts | Ethylene
Journal Article
Catal. Sci. Technol, ISSN 2044-4753, 2017, Volume 7, Issue 21, pp. 5011 - 5018
Journal Article
Organometallics, ISSN 0276-7333, 09/2016, Volume 35, Issue 17, pp. 3045 - 3050
A series of chromium(III) complexes, LCrCl3 (Cr1-Cr4: L = 2-(N-R-2-benzimidazol-2=yl)-6-(3,5-R-1-pyrazol-1-yl)pyridine; Cr1: R-1 = H, R-2 = H; Cr-2: = Me, R-2... 
MECHANISTIC INVESTIGATIONS | TETRAMERIZATION | 1-OCTENE | TRIMERIZATION CATALYST | COMPLEXES | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | LIGAND STRUCTURE | CR-PNP | LINEAR ALPHA-OLEFINS | SELECTIVITIES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 09/2008, Volume 27, Issue 17, pp. 4277 - 4279
Cr(III) complexes with [NON] and [NSN] heteroscorpionate ligands derived from bis(pyrazol-1-yl)methane have been prepared, which are active for ethylene... 
NICKEL-COMPLEXES | COORDINATION CHEMISTRY | P,N-PHOSPHINOPYRIDINE LIGANDS | CHEMISTRY, ORGANIC | CR-PNP | POLYMERIZATION | OXAZOLINE | DIPHOSPHINOAMINE LIGANDS | METAL OXIDATION-STATE | OLIGOMERIZATION | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 42, pp. 17020 - 17029
An amidinato-phosphino ligand ArN = C(R)NH(o-Ph2PC6H4) (Ar = 2,4,6-Me3C6H2, R = Ph (1); Ar = 2,6-iPr(2)C(6)H(3), R = Ph (2); Ar = 2,6-iPr(2)C(6)H(3), R = tBu... 
TETRAMERIZATION | 1-OCTENE | ISOPRENE | IMINE | EPR | PENDANT | CR-PNP | SUBSTITUTED DIPHOSPHINOAMINE LIGANDS | OLIGOMERIZATION | TRIMERIZATION CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis (chemistry) | Catalysts | Ethylene | Polymerization | Ligands | Activation | Catalysis
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 2017, Volume 7, Issue 21, pp. 5011 - 5018
High performance catalysts switched by a series of silicon-bridged/N, P-based ancillary ligands have been explored. The precatalyst supported by L1 possessed a... 
MECHANISTIC INVESTIGATIONS | TETRAMERIZATION | 1-OCTENE | DIPHOSPHINE LIGANDS | PNP | CR/PNP CATALYSTS | COMPLEXES | CHEMISTRY, PHYSICAL | OLIGOMERIZATION | SELECTIVITY | TRIMERIZATION | Chromium | Ligands | Silicon | Selectivity | Catalysis | Catalysts
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2018, Volume 8, Issue 11, pp. 10836 - 10845
Journal Article
Journal of the Chemical Society. Dalton Transactions, ISSN 1477-9226, 2007, Issue 32, pp. 3493 - 3498
Several N-functionalized bis(phosphino) amine ligands with ether, thioether and pyridyl tethers [(R '')(2)PN(R') P(R '')(2) = PNP] (1a-1g) have been... 
DIPHOSPHINE LIGANDS | MECHANISM | TEMPERATURE | COMPLEXES | CR-PNP | 1-HEXENE | POLYMERIZATION | METAL OXIDATION-STATE | OLIGOMERIZATION | TRIMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 01/2012, Volume 31, Issue 1, pp. 486 - 494
Reduction of the tetranuclear {[(t-Bu)NPPh2]-Cr[mu-(t-Bu)NPPh2]Cr}(2)(mu-Cl)(2) (1) with either KC8 or vinyl Grignard afforded the dinuclear, mixed-valence... 
SELECTIVE ETHENE TRIMERIZATION | ALPHA-OLEFINS | ATOMS LI | COMPLEXES | CHEMISTRY, ORGANIC | LIGAND STRUCTURE | CR-PNP | POLYMERIZATION | METAL OXIDATION-STATE | OLIGOMERIZATION | GAUSSIAN-BASIS SETS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2007, Volume 26, Issue 16, pp. 4010 - 4014
A set of chromium(III) complexes CrCl3(L) based on tridentate ligands (1, L = bis[2-(3,5-dimethylpyrazolyl)ethyl)]amine; 2, L =... 
TETRAMERIZATION | ALPHA-OLEFINS | DIPHOSPHINE LIGANDS | TRIAZACYCLOHEXANE COMPLEXES | CHEMISTRY, ORGANIC | CR-PNP | POLYMERIZATION | METAL OXIDATION-STATE | SELECTIVITY | TRIMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Molecular Catalysis. A, Chemical, ISSN 1381-1169, 11/2013, Volume 378, pp. 17 - 21
Cr-catalyzed selective oligomerization of ethylene was carried out with diphosphinoamine ligands bearing pendent amine donors. Catalytic behavior of the Cr... 
Chromium | 1-Octene | Polyethylene | 1-Hexene | Ethylene tetramerization | MECHANISTIC INVESTIGATIONS | CATALYSIS | COMPLEXES | CHEMISTRY, PHYSICAL | TRIMERIZATION | LIGANDS | CR-PNP | OLIGOMERIZATION | Amines | Ethylene
Journal Article