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1. Full Text Effects of Co-solvents on Reactions Run under Micellar Catalysis Conditions
by Gabriel, Christopher M and Lee, Nicholas R and Bigorne, Florence and Klumphu, Piyatida and Parmentier, Michael and Gallou, Fabrice and Lipshutz, Bruce H
Organic Letters, ISSN 1523-7060, 01/2017, Volume 19, Issue 1, pp. 194 - 197
The impact of varying percentages of an organic solvent added to reactions run in aqueous nanomicelles as the reaction medium has been investigated. Issues... 
CHEMISTRY, ORGANIC | ROOM-TEMPERATURE | CROSS-COUPLINGS | WATER
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2. Full Text Copper-Catalyzed Regioselective C–H Sulfonylation of 8‑Aminoquinolines
by Wei, Jun and Jiang, Jingxing and Xiao, Xinsheng and Lin, Dongen and Deng, Yuanfu and Ke, Zhuofeng and Jiang, Huanfeng and Zeng, Wei
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2016, Volume 81, Issue 3, pp. 946 - 955
Copper­(I)-catalyzed 5-sulfonation of quinolines via bidentate-chelation assistance has been developed. The reaction is compatible with a wide range of... 
DIARYL SULFONES | POTENT | CROSS-COUPLINGS | OLEFINATION | ALKYLATION | ARYLATION | CHLORIDES | CHEMISTRY, ORGANIC | ARYLSULFINIC ACID SALTS
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3. Full Text Palladium-catalyzed carbonylative coupling reactions between Ar-X and carbon nucleophiles
by Wu, Xiao-Feng and Neumann, Helfried and Beller, Matthias
Chemical Society Reviews, ISSN 0306-0012, 10/2011, Volume 40, Issue 10, pp. 4986 - 5009
Palladium-catalyzed carbonylative coupling reactions of aromatic halides and related compounds have undergone a rapid development during recent years.... 
CONVENIENT SYNTHESIS | METAL-PROMOTED CYCLIZATION | IODONIUM SALTS | CROSS-COUPLINGS | ALKYNYL KETONES | TERMINAL ALKYNES | ORGANIC HALIDES | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | UNSYMMETRICAL KETONE SYNTHESIS
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4. Full Text The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)(3) and PCy3 as Ligands
by Fu, GC
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1555 - 1564
Metal-catalyzed coupling reactions of aryl electrophiles with organometallics and with olefins serve as unusually effective tools for forming new carbon-carbon... 
MILD | CROSS-COUPLINGS | ALPHA-ARYLATION | CHLOROARENES | SCOPE | PALLADACYCLES | CHLORIDES | HECK REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | GENERAL-METHOD
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5. Full Text Nickel-Catalyzed Amination of Aryl 2‑Pyridyl Ethers via Cleavage of the Carbon–Oxygen Bond
by Li, Jing and Wang, Zhong-Xia
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3723 - 3726
Reaction of aryl 2-pyridyl ethers with amines was carried out via Ni-catalyzed C–OPy bond cleavage, giving aniline derivatives in reasonable to excellent... 
DIRECTING GROUP | CHEMISTRY, ORGANIC | C-O BONDS | CROSS-COUPLINGS | BORYLATION
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6. Full Text Methane functionalization in water with micellar catalysis
by Gava, R and Ballestin, P and Prieto, A and Caballero, A and Perez, PJ
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 75, pp. 11243 - 11246
The functionalization of methane in water as the reaction medium (where it is nearly insoluble) at room temperature using micellar catalysis is described.... 
CROSS-COUPLINGS | CHEMISTRY, MULTIDISCIPLINARY | BONDS | ALKANES
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7. Full Text Ni-Catalyzed Reductive C-O Bond Arylation of Oxalates Derived from α-Hydroxy Esters with Aryl Halides
by Gao, Mengyu and Sun, Deli and Gong, Hegui
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 6, pp. 1645 - 1648
A Ni-catalyzed reductive cross-coupling of alpha-hydroxycarbonyl compounds modified with oxalyl groups and aryl halides has been developed that furnishes... 
ALCOHOLS | DIARYLMETHANES | CHEMISTRY, ORGANIC | ACTIVATION | CROSS-COUPLINGS | COUPLING REACTIONS
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8. Full Text Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols
by Ngamnithiporn, Aurapat and Jette, Carina I and Bachman, Shoshana and Virgil, Scott C and Stoltz, Brian M
Chemical Science, ISSN 2041-6520, 03/2018, Volume 9, Issue 9, pp. 2547 - 2551
The first nickel-catalyzed enantioselective allylic alkylation of lactone and lactam substrates to deliver products bearing an all-carbon quaternary... 
CROSS-COUPLINGS | HETEROCYCLES | CHEMISTRY, MULTIDISCIPLINARY | TRANSFORMATIONS | CONSTRUCTION | ALLYLATION
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9. Full Text Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds
by Dudnik, Alexander S and Fu, Gregory C
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 25, pp. 10693 - 10697
Through the use of a catalyst formed in situ from NiBr2·diglyme and a pybox ligand (both of which are commercially available), we have achieved our first... 
ALCOHOLS | SUBSTITUTION | SUZUKI CROSS-COUPLINGS | ENANTIOSELECTIVE SYNTHESIS | CONVERSION | ESTERS | REACTIVITY | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION
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10. Full Text Use of the 2-Pyridinesulfonyloxy Leaving Group for the Fast Copper-Catalyzed Coupling Reaction at Secondary Alkyl Carbons with Grignard Reagents
by Shinohara, R and Morita, M and Ogawa, N and Kobayashi, Y
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3247 - 3251
Investigation of the copper-catalyzed coupling reaction of 2-pyridinesulfonates with Grignard reagents revealed that reactions with catalytic Cu(OTf)(2) were... 
HALIDES | CHEMISTRY, ORGANIC | SUZUKI CROSS-COUPLINGS | ALLYLIC SUBSTITUTION
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11. Full Text Enantioselective alpha-Arylation of Aldehydes via the Productive Merger of lodonium Salts and Organocatalysis
by Allen, AE and MacMillan, DWC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2011, Volume 133, Issue 12, pp. 4260 - 4263
The enantioselective alpha-arylation of aldehydes has been accomplished using diaiyliodonium salts and a combination of copper and organic catalysts. These... 
PALLADIUM | KETONES | IODONIUM SALTS | PHENYLATION | CROSS-COUPLINGS | SILYL ENOL ETHERS | DIARYLIODONIUM SALTS | SELECTIVE ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | REGIOCONTROLLED SYNTHESIS | TRIFLUOROMETHYLATION
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12. Full Text Micelle-Enabled Palladium Catalysis for Convenient sp2‑sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions
by Brals, Jeremy and Smith, Justin D and Ibrahim, Faisal and Gallou, Fabrice and Handa, Sachin
ACS Catalysis, ISSN 2155-5435, 10/2017, Volume 7, Issue 10, pp. 7245 - 7250
The efficacy of custom surfactant FI-750-M, designed to mimic polar solvents such as DMF and 1,4-dioxane, has been demonstrated with the palladium-catalyzed... 
Green chemistry | Micellar catalysis | E factor | Cross-couplings | Amphiphiles
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13. Full Text Frontispiece: Metal‐Free Synthesis of Pharmaceutically Important Biaryls by Photosplicing
by Kloss, Florian and Neuwirth, Toni and Haensch, Veit G and Hertweck, Christian
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 44, p. n/a
Photochemistry In their Communication on page 14476 ff., C. Hertweck and co‐workers report on a metal‐free cross‐coupling reaction that involves the tethering... 
sulfonamides | biaryls | photochemistry | cross-couplings | synthetic methods | Tethering | Workers | Sulfonamides | Metals | Photochemistry
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14. Full Text Catalytic Asymmetric Synthesis of Secondary Nitriles via Stereoconvergent Negishi Arylations and Alkenylations of Racemic α-Bromonitriles
by Choi, Junwon and Fu, Gregory C
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 22, pp. 9102 - 9105
The first method for the stereoconvergent cross-coupling of racemic α-halonitriles is described, specifically, nickel-catalyzed Negishi arylations and... 
HALIDES | CROSS-COUPLINGS | ARYLZINC REAGENTS | ALKYL BROMIDES | CHEMISTRY, MULTIDISCIPLINARY
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15. Full Text Expedient Access to Unsymmetrical Diarylindolylmethanes through Palladium-Catalyzed Domino Electrophilic Cyclization-Extended Conjugate Addition Approach
by Reddy, Virsinha and Vijaya Anand, Ramasamy
Organic Letters, ISSN 1523-7060, 07/2015, Volume 17, Issue 14, pp. 3390 - 3393
A palladium-catalyzed domino process to access unsymmetrical diarylindolylmethanes has been developed through the annulation of o-alkynylanilines followed by... 
CROSS-COUPLINGS | ENANTIOSELECTIVE SYNTHESIS | ACIDS | TRIARYLMETHANES | ALKYLATION | SEQUENTIAL ARYLATION | ARENES | CHEMISTRY, ORGANIC | PARA-QUINONE METHIDES | AMBIDENT REACTIVITIES | INDOLES
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16. Full Text Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides
by Han, Chong and Buchwald, Stephen L
Journal of the American Chemical Society, ISSN 0002-7863, 06/2009, Volume 131, Issue 22, pp. 7532 - 7533
An efficient palladium-catalyzed process has been developed for Negishi coupling of secondary alkylzinc halides with a wide range of aryl bromides and... 
ORGANOZINC REAGENTS | CROSS-COUPLINGS | ORGANIC HALIDES | CATALYST | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | GRIGNARD
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17. Full Text Chemoselective Reductions of Nitroaronnatics in Water at Room Temperature
by Kelly, SM and Lipshutz, BH
ORGANIC LETTERS, ISSN 1523-7060, 01/2014, Volume 16, Issue 1, pp. 98 - 101
A robust and green protocol for the reduction of functionalized nitroarenes to the corresponding primary amines has been developed. It relies on inexpensive... 
NANOPARTICLES | NITROARENES | CROSS-COUPLINGS | NITROAROMATICS | CHEMISTRY, ORGANIC | CATALYZED REDUCTION | SELECTIVE REDUCTION
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18. Full Text Synthesis of Biaryls through Nickel‐Catalyzed Suzuki–Miyaura Coupling of Amides by Carbon–Nitrogen Bond Cleavage
by Shi, Shicheng and Meng, Guangrong and Szostak, Michal
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 24, pp. 6959 - 6963
The first Ni‐catalyzed Suzuki–Miyaura coupling of amides for the synthesis of widely occurring biaryl compounds through N−C amide bond activation is reported.... 
cross-coupling | N−C activation | nickel | amide bonds | biaryls | N-C activation | PALLADIUM | C CLEAVAGE | ACTIVATION | CARBOXYLATES | TWISTED AMIDES | CHEMISTRY, MULTIDISCIPLINARY | ETHERS | CROSS-COUPLINGS | RESONANCE | N ROTATIONAL PATHWAY | LACTAMS | Amides | Nickel
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19. Full Text Nickel-Catalyzed Formal Homocoupling of Methoxyarenes for the Synthesis of Symmetrical Biaryls via C–O Bond Cleavage
by Nakamura, Keisuke and Tobisu, Mamoru and Chatani, Naoto
Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6142 - 6145
A new method has been developed for the nickel-catalyzed homocoupling of methoxyarenes via C–O bond cleavage using a diboron reagent. The use of... 
PALLADIUM | CROSS-COUPLINGS | METHYL ETHERS | ARENES | ANISOLES | CHEMISTRY, ORGANIC | ARYL ETHERS | ACTIVATION/CROSS-COUPLING REACTION | BORYLATION
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20. Full Text Sustainable HandaPhos-ppm Palladium Technology for Copper-Free Sonogashira Couplings in Water under Mild Conditions
by Handa, Sachin and Smith, Justin D and Zhang, Yitao and Takale, Balaram S and Gallou, Fabrice and Lipshutz, Bruce H
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 542 - 545
Complexation of ca. 1000 ppm Pd­(OAc)2 with the ligand HandaPhos (1–1.5:1) leads to a precatalyst that efficiently mediates Sonogashira couplings in aqueous... 
ARYL BROMIDES | SUZUKI | AMPHIPHILE | HECK | CATALYZED CROSS-COUPLINGS | CHLORIDES | CHEMISTRY, ORGANIC
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