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cyanotrimethylsilane (88) 88
chemistry, organic (55) 55
aldehydes (27) 27
trimethylsilyl cyanide (26) 26
ketones (17) 17
chemistry, multidisciplinary (13) 13
cyanohydrins (13) 13
cyanosilylation (13) 13
carbonyl-compounds (12) 12
catalysis (12) 12
chemistry, inorganic & nuclear (11) 11
chemistry, physical (11) 11
alcohols (10) 10
catalyst (10) 10
oxiranes (10) 10
synthetic applications (10) 10
cyanide (9) 9
epoxides (9) 9
catalysts (8) 8
derivatives (8) 8
lewis acid (8) 8
organic-synthesis (8) 8
acid (7) 7
chemistry (7) 7
enantioselective trimethylsilylcyanation (7) 7
hydrocyanation (7) 7
potassium cyanide (7) 7
reagents (7) 7
acetals (6) 6
asymmetric hydrocyanation (6) 6
cyanation (6) 6
asymmetric catalysis (5) 5
complexes (5) 5
lewis-acid (5) 5
nitriles (5) 5
acetal templates (4) 4
analysis (4) 4
asymmetric-synthesis (4) 4
beta-hydroxy nitriles (4) 4
crystallography (4) 4
efficient (4) 4
hydrogen-cyanide (4) 4
k ee chemistry, organic (4) 4
letter (4) 4
regioselectivity (4) 4
synthesis (4) 4
titanium alkoxide complexes (4) 4
1,2-epoxides (3) 3
2,3-epoxy alcohols (3) 3
aldol (3) 3
bases (3) 3
carbonyl compounds (3) 3
chemistry, applied (3) 3
chemistry, medicinal (3) 3
cyanohydrin (3) 3
cyanohydrin synthesis (3) 3
disproportionation (3) 3
efficient catalyst (3) 3
enantioselective addition (3) 3
enantioselective synthesis (3) 3
epoxide (3) 3
ethers (3) 3
facile synthesis (3) 3
k ei chemistry, physical (3) 3
molecular structure (3) 3
o-silylcyanohydrines (3) 3
o-trimethylsilylcyanhydrines (3) 3
oxidation (3) 3
pharmacology & pharmacy (3) 3
reactivity (3) 3
ring-opening reactions (3) 3
stereoselective synthesis (3) 3
1,4-addition (2) 2
acetone cyanohydrin (2) 2
acids (2) 2
aliphatic-aldehydes (2) 2
alkyl-halides (2) 2
alpha,beta-unsaturated ketones (2) 2
anticancer (2) 2
antiviral (2) 2
aromatic cyanohydrins (2) 2
asymmetric addition (2) 2
aziridination (2) 2
base (2) 2
beta-hydroxy nitrile (2) 2
c bond formation (2) 2
calcium oxide (2) 2
carbon bond formation (2) 2
chalcones (2) 2
chiral sulfoxides (2) 2
clay montmorillonite (2) 2
compactin (2) 2
complex (2) 2
conjugate hydrocyanation (2) 2
conversion (2) 2
crystal structure (2) 2
cyanides (2) 2
cyanides - chemistry (2) 2
cyano-trimethylsilane (2) 2
cyclic schiff base (2) 2
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Tetrahedron, ISSN 0040-4020, 2004, Volume 60, Issue 8, pp. 1767 - 1771
Aryl imines, formed in situ from aldehydes and amines undergo smoothly nucleophilic addition with trimethylsilyl cyanide on the surface of montmorillonite KSF... 
Aryl imines | Trimethylsiyl cyanide | α-Aminonitriles | Solid acids | FACILE SYNTHESIS | ACID | trimethylsiyl cyanide | CYANOTRIMETHYLSILANE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | aryl imines | ALDEHYDES | CYANOSILYLATION | alpha-aminonitriles | solid acids
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2007, Volume 48, Issue 11, pp. 2037 - 2039
The addition of TMSCN to α,β-unsaturated ketones such as chalcones, 3-nonen-2-one and benzalacetone under microwave irradiation in the absence of additive and... 
HIGH-PRESSURE | CYANOTRIMETHYLSILANE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CYANOSILYLATION | IMIDES | CYANIDE
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2011, Volume 353, Issue 2‐3, pp. 291 - 294
A simple cyanation reaction of boronic acids with cuprous cyanide is achieved, providing nitriles in moderate to good yields. In the presence of copper(I)... 
cyanation | copper | nitriles | cyanotrimethylsilane | boronic acids | ROOM-TEMPERATURE | TERTIARY-AMINES | CHEMISTRY, ORGANIC | C-H BONDS | OXIDATIVE CYANATION | CROSS-COUPLING REACTIONS | ARYL HALIDES | SODIUM-CYANIDE | HYDROGEN-PEROXIDE | CHEMISTRY, APPLIED | PALLADIUM-CATALYZED CYANATION | N-ARYLATION | cyano-trimethylsilane | Nitriles | Cyanides | Synthesis | Catalysis | Iodides
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 11/2007, Volume 72, Issue 23, pp. 8648 - 8655
Halide or alkoxide free yttrium-salen complexes are excellent catalysts for the ring opening of epoxides mediated by TMSCN and TMSN3. Substrate to catalyst... 
ASYMMETRIC CATALYSIS | ALCOHOLS | CYANOTRIMETHYLSILANE | CHIRAL ORGANOGALLIUM | INDIUM COMPLEXES | MESO-EPOXIDES | OXIRANES | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE ADDITION | TRIMETHYLSILYL CYANIDE | DERIVATIVES
Journal Article
Catalysis Communications, ISSN 1566-7367, 12/2015, Volume 72, pp. 6 - 10
The recoverable nanomagnetic catalyst was manufactured based on thiourea modified magnetic hydroxyapatite. Magnetic hydroxyapatite (mHAp) as the... 
Thiourea modified magnetic hydroxyapatite | Conjugate hydrocyanation | Chalcones | Recoverable nanomagnetic catalyst | CYANOTRIMETHYLSILANE | SYNTHETIC APPLICATIONS | CHEMISTRY, PHYSICAL | HYDROGEN-CYANIDE | AGENTS | CATALYST | 1,4-ADDITION | WATER
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2009, Volume 7, Issue 15, pp. 3024 - 3026
High-yielding Ugi reactions have been carried out with in situ-prepared isocyanides, derived from the reaction of bromide derivatives with silver and potassium... 
ALCOHOLS | MULTICOMPONENT REACTIONS | EPOXIDES | PHASE | CYANOTRIMETHYLSILANE | CHEMISTRY | OXAZOLES | CHEMISTRY, ORGANIC | CONDENSATION | ISONITRILES | ALKYL-HALIDES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2002, Volume 43, Issue 52, pp. 9703 - 9706
Molecular iodine is found to catalyze efficiently the addition of trimethylsilyl cyanide to a range of simple and functionalized ketones under very mild and... 
α-cyanohydrins | iodine | trimethylsiyl cyanide | ketones | Trimethylsiyl cyanide | Ketones | Iodine | CYANOHYDRINS | CYANOTRIMETHYLSILANE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | alpha-cyanohydrins | SUBSTITUTED KETONES | ALDEHYDES | CATALYST | ETHERS | SYNTHETIC APPLICATIONS | CYANOSILYLATION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 11/2011, Volume 76, Issue 22, pp. 9478 - 9487
Journal Article
Organic Letters, ISSN 1523-7060, 04/2000, Volume 2, Issue 7, pp. 1001 - 1004
Journal Article
Polyhedron, ISSN 0277-5387, 01/2013, Volume 49, Issue 1, pp. 234 - 238
In this research, ring opening of epoxides with potassium cyanide in the presence of metal Schiff base complexes as new catalysts under neutral and mild... 
β-Hydroxy nitrile | Potassium cyanide | Schiff base complex | Catalyst | Epoxide | AMINO-ALCOHOLS | CYANOTRIMETHYLSILANE | RING-OPENING REACTIONS | RESOLUTION | CYCLOPROPANATION | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | AZIRIDINATION | TRIMETHYLSILYL CYANIDE | ELEMENTAL HALOGEN | beta-Hydroxy nitrile | STYRENE DERIVATIVES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2001, Volume 42, Issue 16, pp. 3041 - 3043
The catalytic addition of trimethylsilyl cyanide (TMSCN) to a large variety of hetero-substituted ketones promoted by anhydrous InBr has been studied. The low... 
indium | cyanohydrins | catalysis | ketones | Catalysis | Ketones | Indium | Cyanohydrins | CYANOTRIMETHYLSILANE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ASYMMETRIC ADDITION | ALDEHYDES | ALCOHOLS | SYNTHETIC APPLICATIONS | CYANOSILYLATION | DERIVATIVES
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2006, Volume 17, Issue 16, pp. 2328 - 2333
Chiral dinuclear titanium(IV) complexes (generated in situ from hexadentate Schiff bases and titanium tetra-isopropoxide) have been found to be more effective... 
EPOXIDES | DUAL ACTIVATION | CYANOTRIMETHYLSILANE | POTASSIUM CYANIDE | ACETONE CYANOHYDRIN | 1,2-EPOXIDES | REACTIVITY | OXIRANES | CHEMISTRY, PHYSICAL | TRIMETHYLSILYL CYANIDE | CATALYSTS | Schiff bases | Olefins
Journal Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 09/2007, Volume 692, Issue 20, pp. 4361 - 4366
An efficient method for the addition of trimethylsilyl cyanide (TMSCN) to various aldehydes and ketones has been described using Fe(CP)(2)PF6 (2.5 mol%) as a... 
CYANOTRIMETHYLSILANE | LEWIS-ACID | CHEMISTRY, ORGANIC | catalysis | solvent free synthesis | ALDEHYDES | carbonyl compounds | SALEN COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR | N-OXIDE | KETONES | OPTICALLY-ACTIVE CYANOHYDRINS | cyanosilylation | Fe(Cp)PF6 | TRIMETHYLSILYL CYANIDE ADDITION | SYNTHETIC APPLICATIONS | RECYCLABLE CATALYST
Journal Article
Synlett, ISSN 0936-5214, 05/2009, Volume 2009, Issue 8, pp. 1291 - 1294
Abstract Cyanation of biphenyl-4-ylmethyl methanesulfonate with trimethylsilyl cyanide using fluoride-free inorganic salts, such as Cs 2 CO 3 , K 2 CO 3 , and... 
letter | Cyanation | Fluoride-free inorganic salt | Trimethylsilyl cyanide | COMPLEX | CYANOTRIMETHYLSILANE | trimethylsilyl cyanide | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CATALYST | fluoride-free inorganic salt | ALCOHOLS | cyanation | EPOXIDES | KETONES | REDUCTION | NITRILES | CYANOSILYLATION
Journal Article
Synlett, ISSN 0936-5214, 06/2009, Volume 2009, Issue 9, pp. 1401 - 1404
Abstract We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are... 
letter | Multicomponent reaction | Synthesis | Ugi-Smiles | Silver cyanide | Isocyanides | Alkylation | synthesis | CYANOTRIMETHYLSILANE | OXAZOLES | CHEMISTRY, ORGANIC | ISONITRILES | ALKYL-HALIDES | ALCOHOLS | EPOXIDES | isocyanides | PHASE | silver cyanide | UGI | CHEMISTRY | alkylation | COUPLINGS | multicomponent reaction | Organic chemistry | Chemical Sciences
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2005, Volume 347, Issue 11‐13, pp. 1653 - 1658
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2000, Volume 2000, Issue 14, pp. 2655 - 2661
Titanium complexes 1 derived from chiral salen ligands are highly active precatalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and... 
Titanium | Aldehydes | Asymmetric catalysis | Cyanohydrins | cyanohydrins | REAGENTS | CYANOTRIMETHYLSILANE | LEWIS-ACID | titanium | C BOND FORMATION | HYDROCYANATION | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION | asymmetric catalysis | aldehydes | TITANIUM ALKOXIDE COMPLEXES | CYANOSILYLATION | DERIVATIVES | SCHIFF-BASE COMPLEXES
Journal Article
Journal Article
Catalysis Communications, ISSN 1566-7367, 02/2011, Volume 12, Issue 6, pp. 493 - 496
Different amorphous mesoporous TUD-1 catalysts were employed in cyanosilylation of acetophenone with trimethylsilylcyanide in dichloromethane at room... 
TUD-1 | Acetophenone | Heterogeneous catalysis | Mesoporous materials | Al-MCM-41 | Cyanosilylation | CYANOHYDRINS | CYANOTRIMETHYLSILANE | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | ALDEHYDES | SOLID ACID | KETONES | MESOPOROUS AL-MCM-41 | POTASSIUM | EFFICIENT | CYANIDE | Catalysts | Analysis | Investigations
Journal Article
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