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cyclobutanone o-benzoyloximes (21) 21
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iminyl radicals (12) 12
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Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 4, pp. 1034 - 1037
An efficient synthesis of cyanoalkylated heteroarenes via iron-catalyzed direct C–H cyanoalkylation of heteroarenes has been developed. Structurally diverse... 
ALLYLIC ALCOHOLS | CYCLOBUTANONE O-BENZOYLOXIMES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | QUINOXALINONE DERIVATIVES | ALKYL NITRILES | IMINYL RADICALS | INHIBITORS | RING-CLEAVAGE | OXIME ESTERS | UNACTIVATED ALKENES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 4239 - 4249
Metal-catalyzed cyanoalkylation/cyclization of olefinic 1,3-dicarbonyls with cycloketone oxime esters has been developed under redox-neutral conditions. This... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | DERIVATIVES | CYCLIZATION | 2,3-DIHYDROFURANS | C-H CYANOALKYLATION | IMIDATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4614 - 4617
An iron-catalyzed redox-neutral, decarboxylative olefination of cycloketone oxime esters with α,β-unsaturated carboxylic acids has been developed. This... 
ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | CINNAMIC-ACIDS | CYCLOBUTANONE O-BENZOYLOXIMES | TERTIARY CYCLOALKANOLS | CHEMISTRY, ORGANIC | IMINYL RADICALS | H BONDS | RING-CLEAVAGE | HYPERVALENT IODINE REAGENTS | PHOTOREDOX CATALYSIS
Journal Article
by Zhang, JJ and Duan, XH and Wu, Y and Yang, JC and Guo, LN
CHEMICAL SCIENCE, ISSN 2041-6520, 01/2019, Volume 10, Issue 1, pp. 161 - 166
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B-2(OH)(4) reagent not... 
B BOND | MEDICINAL CHEMISTRY | CROSS-COUPLING REACTIONS | CYCLOBUTANONE O-BENZOYLOXIMES | ACID PROTEASOME INHIBITORS | ARYL HALIDES | BIOLOGICAL EVALUATION | COPPER-CATALYZED BORYLATION | RING-CLEAVAGE | CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 1, pp. 161 - 166
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B (OH) reagent not only... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
VISIBLE-LIGHT | H CYANOALKYLATION | NITROGEN-CENTERED RADICALS | CYCLOBUTANONE O-BENZOYLOXIMES | LIGHT PHOTOREDOX CATALYSIS | GENERATION | RING-CLEAVAGE | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CARBOXYLIC-ACIDS | Cleavage | Photocatalysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
Journal Article
by Anand, D and He, YW and Li, LY and Zhou, L
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 01/2019, Volume 17, Issue 3, pp. 533 - 540
The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C-C bond cleavage were described. The... 
H CYANOALKYLATION | NITRILES | AMINES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | INDOLES | ACCESS
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 27, pp. 5883 - 5889
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic... 
C BOND-CLEAVAGE | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | IMINYL RADICALS | VINYLBENZIODOXOLONES | GENERATION | RING-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | DECARBOXYLATIVE ALKYNYLATION | CARBOXYLIC-ACIDS | Oxidation | Catalysis | Catalysts | Ethers | Cascades | Ring opening
Journal Article
Chemical science, ISSN 2041-6520, 07/2018, Volume 9, Issue 27, pp. 5883 - 5889
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated oxidative ring opening of cyclic... 
Journal Article
by Liu, ZL and Shen, HG and Xiao, HW and Wang, ZT and Zhu, L and Li, CZ
ORGANIC LETTERS, ISSN 1523-7060, 07/2019, Volume 21, Issue 13, pp. 5201 - 5205
The copper-catalyzed ring-opening C-trifluoromethylation of cycloalkanone oximes with Zn(CF3)(2) complexes is described. The reaction proceeds in... 
MIGRATION | ALKENES | DESIGN | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | DRIVEN | ELECTROPHILIC N-TRIFLUOROMETHYLATION | CLEAVAGE
Journal Article
by Yang, L and Zhang, JY and Duan, XH and Gao, P and Jiao, J and Guo, LN
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 07/2019, Volume 84, Issue 13, pp. 8615 - 8629
The efficient copper-catalyzed cyanoalkylation of amines via C-C bond cleavage has been demonstrated. Distinctive features of this procedure involves mild... 
TRANSFORMATION | H CYANOALKYLATION | PHOTOREDOX | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY | SECONDARY | CHEMISTRY, ORGANIC | RADICALS | COUPLINGS | REDUCTIVE AMINATION | ALKYL-HALIDES
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2019, Volume 55, Issue 79, pp. 11900 - 11903
A visible-light-induced radical cascade cyclization of aryl isonitriles and cyclobutanone oxime esters for the synthesis of cyclopenta[b]quinoxalines has been... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | IMINYL RADICALS | RING-CLEAVAGE | BOND-CLEAVAGE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H CYANOALKYLATION
Journal Article
by Tang, YQ and Yang, JC and Wang, L and Fan, MJ and Guo, LN
ORGANIC LETTERS, ISSN 1523-7060, 07/2019, Volume 21, Issue 13, pp. 5178 - 5182
A nickel-catalyzed iminyl radical-triggered C-C bond cleavage/radical addition/cyclization cascade of oxime esters and vinyl azides is described. This protocol... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | IMINYL RADICALS | BOND-CLEAVAGE | METAL-FREE | C-H CYANOALKYLATION
Journal Article
by Ding, DC and Lan, Y and Lin, ZY and Wang, C
ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 8, pp. 2723 - 2730
By merging C-F and C-C bond activation in the cross-electrophile coupling, we developed an efficient cyanide-free synthesis of diverse functional-group-rich... 
H CYANOALKYLATION | TERTIARY ALKYL | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | NICKEL CATALYSIS | CYCLOBUTANONE O-BENZOYLOXIMES | BIOLOGICAL-ACTIVITY | DIFLUOROMETHYL 2-PYRIDYL SULFONE | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | RING-CLEAVAGE | FUNCTIONALIZED 1,1-DIFLUORO-1-ALKENES
Journal Article
by He, Y and Lou, J and Wu, KK and Wang, HM and Yu, ZK
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 02/2019, Volume 84, Issue 4, pp. 2178 - 2190
Carbon-carbon bond formation is among the most important reactions in organic synthesis. Reconstruction of a carbon-carbon bond through ring-opening C-C bond... 
H CYANOALKYLATION | REAGENTS | CYCLOBUTANONE O-BENZOYLOXIMES | THIOBENZOYLKETENE S,N-ACETALS | CHEMISTRY, ORGANIC | IMINYL RADICALS | THIOAROYLKETENE S,N-ACETALS | RING-CLEAVAGE | KETENE N,S-ACETALS | ACCESS | N-TOSYLHYDRAZONES
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2/2019, Volume 43, Issue 8, pp. 3254 - 3264
Iminyl radicals have emerged as versatile synthons for N-heterocycle constructions and ring-opening reactions. Iminyl radicals are a special class of... 
FUNCTIONALIZATIONS | VINYL AZIDES | CYCLOBUTANONE O-BENZOYLOXIMES | ACYL OXIMES | QUINOLINES | GENERATION | CLEAVAGE | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | UNACTIVATED ALKENES | Radicals | Catalysis
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2018, Volume 360, Issue 9, pp. 1775 - 1779
Journal Article