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Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 32, pp. 11292 - 11295
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 9, pp. 2408 - 2412
A change in reaction pathway was achieved for the first time by tuning the cyclopentadienyl (Cp) ligand used for the rhodium‐catalyzed cyclization of... 
cyclopentadienyl ligands | reaction mechanisms | annulations | rhodium catalysis | Rhodium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 26, pp. 7714 - 7718
The rapid development of enantioselective C−H activation reactions has created a demand for new types of catalysts. Herein, we report the synthesis of a novel... 
cyclopentadienyl ligands | asymmetric catalysis | C−H activation | rhodium | FUNCTIONALIZATIONS | ALKYLATION | REACTIVITY | BOND FORMATION | HALF-SANDWICH COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | C-H activation | RUTHENIUM COMPLEXES | CHEMISTRY | Rhodium | Enantiomers | Catalysis | Stereoselectivity | Alkenes | Catalysts | Aromatic compounds | Proline | Chemical synthesis | Adducts
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 12/2007, Issue 46, pp. 4937 - 4939
Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal Ti=N-NR2 functional group are described,... 
CYCLOADDITION REACTIONS | ORGANIC-COMPOUNDS | COMPLEXES | REACTIVITY | TITANIUM IMIDO COMPOUNDS | HYDRAZIDO(2-) | HYDROAMINATION | CYCLOPENTADIENYL | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | Hydrazines - chemistry | Magnetic Resonance Spectroscopy | Models, Chemical | Crystallography, X-Ray | Indicators and Reagents | Ligands | Alkynes - chemistry | Physics | Chemical Physics
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2017, Volume 56, Issue 17, pp. 10824 - 10831
There are few examples of the isolation of analogous metal complexes bearing [η5-Cp*] and [η4-Cp*H] (Cp* = pentamethylcyclopentadienyl) complexes within the... 
PI-COORDINATION | CONVERSION | CONTROLLED SELECTIVITY | IRIDIUM(I) | SLIPPAGE | RHODIUM(I) COMPLEXES | CHEMISTRY | RING-OPENING ISOMERIZATION | METAL | CYCLOPENTADIENYL | CHEMISTRY, INORGANIC & NUCLEAR | Protons | Composition | Rhodium | Ligands | Chemical properties | Research | Electron configuration | Coordination compounds
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, pp. 31 - 36
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 23, pp. 7332 - 7342
A mixed ligated amidoyttrium complex, Y­(NBn2)­(L1)­(THF)2 (8, L1 = N,N’-bis­(2,6-diisopropylphenyl)­ethylenediamine), served as a catalyst for addition of the... 
CYCLOPENTADIENYL LIGANDS | ASYMMETRIC-SYNTHESIS | AROMATIC N-HETEROCYCLES | CRYSTAL-STRUCTURES | NICKEL/LEWIS ACID CATALYSIS | SELECTIVE ALKENYLATION | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEXES | ALKYL COMPLEXES | SIGMA-BOND METATHESIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 2, pp. 636 - 639
The lack of robust and tunable chiral versions of cyclopentadienyl (Cp) ligands hampers progress in the development of catalytic asymmetric versions of a... 
CYCLOPENTADIENYL LIGANDS | FUNCTIONALIZATION | ACTIVATION | ASYMMETRIC-SYNTHESIS | RHODIUM | BINAPHTHYLCYCLOPENTADIENE | COMPLEXES | 2+2+2 CYCLOADDITION | CHEMISTRY, MULTIDISCIPLINARY | ACCESS | COBALT | Rhodium | Analysis | Chirality | Catalysis | Phase transformations (Statistical physics) | Chemical properties | Structure
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 02/2017, Volume 456, pp. 24 - 33
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 9, pp. 2429 - 2434
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2016, Volume 138, Issue 12, pp. 3935 - 3941
Application of chiral derivatives of the versatile and ubiquitous cyclopentadienyl ligand has long remained an underdeveloped area in asymmetric catalysis. In... 
AMBIENT CONDITIONS | ALKENES | ACTIVATION | IRIDIUM COMPLEXES | BOND FORMATION | (ELECTRON-DEFICIENT ETA-CYCLOPENTADIENYL)RHODIUM(III) CATALYST | OXIDATIVE ANNULATION | 2+2+2 CYCLOADDITION | C-H FUNCTIONALIZATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Comparative analysis | Ligands | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11615 - 11619
The synthesis of the new m‐terphenyl‐substituted cyclopentadienyl ligand precursor 1‐cyclopentadiene‐2,6‐bis(2,4,6‐trimethylphenyl)benzene (TerMesCpH) is... 
chelates | cyclopentadienyl ligands | crystallography | bulky ligands | alkali metals | BENZENE | MAIN-GROUP | COMPOUND | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYLENE | NICKEL | REDUCTION | METALLOCENE | Cyclopentadiene | Cobalt | Chelates | Salts | Iodides | Alkali metals | X-ray diffraction | Cesium | Lithium | Isomers | Crystallography | Benzene | Ligands | Oxidation | Coordination compounds | Chemical synthesis | Metal complexes | Potassium
Journal Article