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Chemistry Letters, ISSN 0366-7022, 01/2019, Volume 48, Issue 9, p. 1116
The electrophilic amination of allylic boranes, which are prepared from allenes and 9-borabicyclo[3.3.1]nonane (9-BBN), with azodicarboxylates as an aminating... 
Carbamates (tradename) | Synthesis | Reagents | Boranes | Hydrazides | Derivatives
Journal Article
AIP Conference Proceedings, ISSN 0094-243X, 01/2019, Volume 2063, Issue 1
A variety of bis(azolyl) urea derivatives were prepared by the reaction of methyl benzazoyl carbamates with azolyl amines in the presence of mild base and... 
Substitutes | Carbamates (tradename) | Amines | Fungicides | Antimicrobial agents | Ureas | Derivatives
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2019, Volume 17, Issue 24, pp. 5891 - 5896
An efficient method for the synthesis of N-aryl carbamates from N-Boc-protected amines has been developed. The cobalt-catalyzed in situ generation of... 
Isocyanates | Carbamates (tradename) | Amines | Synthesis | Aromatic compounds | Phosphine | Alcohol | Formates | Cobalt | Powder | Zinc | Alcohols
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 27, pp. 10821 - 10825
Transition metal carbamates constitute a class of compounds with unique properties, however their catalytic potential has been sparingly explored so far. The... 
Silver | Transition metals | Carbamates (tradename) | Nuclear magnetic resonance--NMR | Catalysts | Carboxylation | Catalysis | Pressure | Alkynes
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 35, pp. 14093 - 14101
A novel and facile CaI2-catalyzed direct synthesis of asymmetrical ureas from N-Alloc-, N-Troc-, and N-Cbz-protected amines is developed. In this study, the... 
Carbamates (tradename) | Nuclear magnetic resonance--NMR | Amines | Asymmetry | Ureas | Catalysis | Chemical synthesis | Aliphatic compounds | Aliphatic amines
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 25, pp. 3166 - 3169
We report herein a straightforward general method for the synthesis of cyclic carbamates from amino alcohols and carbon dioxide in the presence of an external... 
2-OXAZOLIDINONES | URETHANES | CONVERSION | ORGANOCATALYST | CO2 | CARBOXYLATIVE CYCLIZATION | OXAZOLIDIN-2-ONES | AZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | ATMOSPHERIC-PRESSURE | FIXATION | Stereoselectivity | Carbamates (tradename) | Synthesis | Carbon dioxide | Alcohol | Reaction mechanisms | Hydroxyl groups | Alcohols
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 73, pp. 10312 - 10315
N-Unsubstituted carbamates have scarcely been investigated so far as carbonic anhydrase inhibitors (CAIs). By means of kinetic and structural studies, in this... 
Binding | Bicarbonates | Carbamates (tradename) | Catalysis | Lead compounds | Carbonic anhydrase
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 37, pp. 8292 - 8304
The first trapping of N-acyliminium ions by in situ generated carbaminic acid (product of carbon dioxide (CO2) and amine) is reported. This catalyst-free... 
Trapping | Carbamates (tradename) | Nuclear magnetic resonance--NMR | Catalysts | Carbon dioxide | Catalysis | Chemical synthesis | Substrates
Journal Article
Catalysis Science & Technology, ISSN 2044-4753, 01/2019, Volume 9, Issue 1, p. 146
In this work, a catalytic method is presented for the synthesis of aromatic carbamates from aromatic amines using dimethyl carbonate instead of phosgene as a... 
Polyurethane resins | Diamines | Zirconium | Carbamates (tradename) | Nanocrystals | Amines | Catalysts | Phosgene | Catalysis | Chemical synthesis
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 91, pp. 12879 - 12882
Electrooxidative peri-C–H activation was accomplished by versatile ruthenium(ii) catalysis in terms of C–H/N–H and C–H/O–H functionalization. Thus, alkyne... 
Transition metals | Ruthenium | Oxidizing agents | Activation | Selectivity | Ruthenium compounds | Electrocatalysis | Carbamates (tradename) | Oxidants | Aromatic compounds | Phenols | Catalysis | Alkynes
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 28, pp. 11275 - 11281
A green and eco-friendly solvent/catalyst system based on a deep eutectic solvent (DES) was devised and developed for the simple synthesis of carbamates... 
Solvents | Carbamates (tradename) | Synthesis | Amines | Catalysts | Halides | Choline | Carbon dioxide | Zinc chlorides | Catalysis | Aliphatic compounds | Aliphatic amines
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 2, pp. 390 - 407
Two carbenoids combine to generate an olefin by a mechanism involving formation of an ate complex, 1,2‐metalate rearrangement, and β‐elimination. As each stage... 
stereochemistry | carbenoids | stereoablation | stereospecific transformations | alkene synthesis | Carbamates | Olefins | Cross coupling | Carbamates (tradename) | Reviews | Alkenes | Hybridization | Epoxides | Isomers | Dimerization
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 25, pp. 4615 - 4618
An electrochemical Hofmann rearrangement is reported. With the mediation of NaBr, highly corrosive and toxic halogens are avoided. Moreover, this efficient and... 
Amantadine | Carbamates (tradename) | Halogens | Electrochemistry | Amides | Biocompatibility | Hofmann rearrangement
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12422 - 12426
A copper‐catalyzed decarboxylative amination/hydroamination sequence of propargylic carbamates with various nucleophiles is described for the first time. It... 
copper | indoles | synthetic methods | alkynes | hydroamination | SULFUR YLIDES | SUBSTITUTION | PROPARGYLIC ESTERS | ENANTIOSELECTIVE SYNTHESIS | 2-(AMINOMETHYL)INDOLES | QUATERNARY STEREOCENTERS | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | FORMAL 3+2 CYCLOADDITION | AMINES | ACETATES | Carbamates | Copper | Carbamates (tradename) | Amination | Catalysts | Efficiency | Metals | Indoles | Nucleophiles | Chemical synthesis | Intermediates
Journal Article
ChemSusChem, ISSN 1864-5631, 07/2019, Volume 12, Issue 13, pp. 3103 - 3114
4‐Propylcatechol carbonate is a shelf‐stable, renewable C1 reactant. It is easily prepared from renewable 4‐propylcatechol (derived from wood) and dimethyl... 
carbamates | renewable resources | acid catalysts | zinc | C1 building blocks | building blocks | Usage | Carbonates | Organic compounds | Distillation | Lewis acid | Solvents | Carbamates (tradename) | Amines | Shelves | Alcohol | Alcohols
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12285 - 12289
1‐Aryl‐1,2‐dialkylethenes were generated by a sequence of electrophilic substitution, 1,2‐metalate rearrangement, and β‐elimination initiated by the addition... 
carbenoids | stereoablation | organometallic reagents | alkenes | metalate rearrangements | Substitution reactions | Carbamates | Enantiomers | Olefins | Cross coupling | Carbamates (tradename) | Alkenes | Aromatic compounds | Bias | Yield | Coupling | Hybridization
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 40, pp. 5110 - 5113
An asymmetric synthesis of various trifluoromethyl cyclopropanes from olefins, such as vinyl ferrocene, vinyl ethers, vinyl amines, vinyl carbamates and... 
Amines | Alkenes | Catalysts | Vinyl ethers | Enantiomers | Stereoselectivity | Carbamates (tradename) | Cyclopropane | Catalysis | Ethers | Dienes | Chemical synthesis | Organic compounds
Journal Article
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