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1. Pd-catalyzed γ-arylation of γ,δ-unsaturated O-carbamates via an unusual haptotropic rearrangement (Electronic supplementary information (ESI) available: Full optimization tables, procedural, spectral and X-ray crystallographic (CIF) data. CCDC 1878132 and 1884922. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05058a)
by Titouan Royal and Olivier Baudoin
Chemical Science, ISSN 2041-6520, 01/2019, Volume 10, Issue 8, pp. 2331 - 2335
An unusual γ-selectivity was observed in the arylation of γ,δ-unsaturated O-carbamates involving directed lithiation, transmetallation to zinc and Negishi... 
Carbamates (tradename) | Aromatic compounds | Palladium | Selectivity | Crystallography
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2. Electrophilic Amination of Allylic Boranes with Azodicarboxylates: Synthesis of α,α-Disubstituted Allylic Amine Derivatives
by Kensuke Kiyokawa and Shunpei Kainuma and Satoshi Minakata
Chemistry Letters, ISSN 0366-7022, 01/2019, Volume 48, Issue 9, p. 1116
The electrophilic amination of allylic boranes, which are prepared from allenes and 9-borabicyclo[3.3.1]nonane (9-BBN), with azodicarboxylates as an aminating... 
Carbamates (tradename) | Synthesis | Reagents | Boranes | Hydrazides | Derivatives
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3. Full Text Synthesis and antimicrobial activity of bis(azolyl) urea derivatives
by Babu, Kayathi Narendra and Rekha, Tamatam and Sravya, G and Reddy, Putta Ramachandra and Padmavathi, Venkatapuram and Zyryanov, Grigory V
AIP Conference Proceedings, ISSN 0094-243X, 01/2019, Volume 2063, Issue 1
A variety of bis(azolyl) urea derivatives were prepared by the reaction of methyl benzazoyl carbamates with azolyl amines in the presence of mild base and... 
Substitutes | Carbamates (tradename) | Amines | Fungicides | Antimicrobial agents | Ureas | Derivatives
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4. One stone two birds: cobalt-catalyzed in situ generation of isocyanates and benzyl alcohols for the synthesis of N-aryl carbamates (Electronic supplementary information (ESI) available. See DOI: 10.1039/c9ob00924h)
by Sida Li and Ruhima Khan and Xia Zhang and Yong Yang and Zheting Wang and Yong Zhan and Yuze Dai and Yue-e Liu and Baomin Fan
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2019, Volume 17, Issue 24, pp. 5891 - 5896
An efficient method for the synthesis of N-aryl carbamates from N-Boc-protected amines has been developed. The cobalt-catalyzed in situ generation of... 
Isocyanates | Carbamates (tradename) | Amines | Synthesis | Aromatic compounds | Phosphine | Alcohol | Formates | Cobalt | Powder | Zinc | Alcohols
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5. An Fe3O4@SiO2/Schiff base/Cu(ii) complex as an efficient recyclable magnetic nanocatalyst for selective mono N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids (Electronic supplementary information (ESI) available. See DOI: 10.1039/c9nj00028c)
by Ali Reza Sardarian and Iman Dindarloo Inaloo and Milad Zangiabadi
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 22, pp. 8557 - 8565
An efficient, convenient and novel method for the selective mono N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides... 
Carbamates (tradename) | Imines | Halides | Aromatic compounds | Catalytic activity | Pharmacology | Catalysis | Iron oxides | Leaching | Silicon dioxide
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6. Carboxylation of terminal alkynes promoted by silver carbamate at ambient pressure (Electronic supplementary information (ESI) available: NMR data (Table S1). See DOI: 10.1039/c9nj02203a)
by Giulio Bresciani and Fabio Marchetti and Guido Pampaloni
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 27, pp. 10821 - 10825
Transition metal carbamates constitute a class of compounds with unique properties, however their catalytic potential has been sparingly explored so far. The... 
Silver | Transition metals | Carbamates (tradename) | Nuclear magnetic resonance--NMR | Catalysts | Carboxylation | Catalysis | Pressure | Alkynes
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7. CaI2-Catalyzed direct transformation of N-Alloc-, N-Troc-, and N-Cbz-protected amines to asymmetrical ureas (Electronic supplementary information (ESI) available: 1H and 13C NMR spectra of all compounds. See DOI: 10.1039/c9nj03111a)
by Van Hieu Tran and Hee-Kwon Kim
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 35, pp. 14093 - 14101
A novel and facile CaI2-catalyzed direct synthesis of asymmetrical ureas from N-Alloc-, N-Troc-, and N-Cbz-protected amines is developed. In this study, the... 
Carbamates (tradename) | Nuclear magnetic resonance--NMR | Amines | Asymmetry | Ureas | Catalysis | Chemical synthesis | Aliphatic compounds | Aliphatic amines
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8. Full Text Carbon dioxide-based facile synthesis of cyclic carbamates from amino alcohols
by Niemi, Teemu and Fernández, Israel and Steadman, Bethany and Mannisto, Jere K and Repo, Timo
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 25, pp. 3166 - 3169
We report herein a straightforward general method for the synthesis of cyclic carbamates from amino alcohols and carbon dioxide in the presence of an external... 
2-OXAZOLIDINONES | URETHANES | CONVERSION | ORGANOCATALYST | CO2 | CARBOXYLATIVE CYCLIZATION | OXAZOLIDIN-2-ONES | AZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | ATMOSPHERIC-PRESSURE | FIXATION | Stereoselectivity | Carbamates (tradename) | Synthesis | Carbon dioxide | Alcohol | Reaction mechanisms | Hydroxyl groups | Alcohols
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9. Inhibition of carbonic anhydrases by a substrate analog: benzyl carbamate directly coordinates the catalytic zinc ion mimicking bicarbonate binding
by Giuseppina De Simone and Andrea Angeli and Murat Bozdag and Claudiu T Supuran and Jean-Yves Winum and Simona Maria Monti and Vincenzo Alterio
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 73, pp. 10312 - 10315
N-Unsubstituted carbamates have scarcely been investigated so far as carbonic anhydrase inhibitors (CAIs). By means of kinetic and structural studies, in this... 
Binding | Bicarbonates | Carbamates (tradename) | Catalysis | Lead compounds | Carbonic anhydrase
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10. First catalyst-free CO2 trapping of N-acyliminium ions under ambient conditions: sustainable multicomponent synthesis of thia- and oxazolidinyl carbamates (Electronic supplementary information (ESI) available: 1H and 13C NMR spectra of all new compounds. See DOI: 10.1039/c8ob01865k)
by Max Franz and Timo Stalling and Henning Steinert and Jürgen Martens
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 37, pp. 8292 - 8304
The first trapping of N-acyliminium ions by in situ generated carbaminic acid (product of carbon dioxide (CO2) and amine) is reported. This catalyst-free... 
Trapping | Carbamates (tradename) | Nuclear magnetic resonance--NMR | Catalysts | Carbon dioxide | Catalysis | Chemical synthesis | Substrates
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11. Full Text Visible‐Light‐Initiated Manganese Catalysis for C−H Alkylation of Heteroarenes: Applications and Mechanistic Studies
by Nuhant, Philippe and Oderinde, Martins S and Genovino, Julien and Juneau, Antoine and Gagné, Yohann and Allais, Christophe and Chinigo, Gary M and Choi, Chulho and Sach, Neal W and Bernier, Louise and Fobian, Yvette M and Bundesmann, Mark W and Khunte, Bhagyashree and Frenette, Mathieu and Fadeyi, Olugbeminiyi O
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 48, pp. 15309 - 15313
A visible‐light‐driven Minisci protocol that employs an inexpensive earth‐abundant metal catalyst, decacarbonyldimanganese Mn2(CO)10, to generate alkyl... 
Minisci reaction | DFT studies | manganese | C−H alkylation | redox chemistry | HALIDES | FLEXIBLE APPROACH | RADICAL-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | HETEROCYCLES | SUBSTITUTIONS | CARBONYL | DIMANGANESE DECACARBONYL | LATE-STAGE FUNCTIONALIZATION | HETEROAROMATIC BASES | C-H alkylation | Carbamates | Catalysis | Drugs | Carbamates (tradename) | Iodides | Reaction mechanisms | Alkylation | Sugar | Functional groups | Iodine | Manganese
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12. Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors (Electronic supplementary information (ESI) available. See DOI: 10.1039/c8cy02235f)
by Sergio Rojas-Buzo and Pilar García-García and Avelino Corma
Catalysis Science & Technology, ISSN 2044-4753, 01/2019, Volume 9, Issue 1, p. 146
In this work, a catalytic method is presented for the synthesis of aromatic carbamates from aromatic amines using dimethyl carbonate instead of phosgene as a... 
Polyurethane resins | Diamines | Zirconium | Carbamates (tradename) | Nanocrystals | Amines | Catalysts | Phosgene | Catalysis | Chemical synthesis
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13. Electrochemical ruthenium-catalyzed alkyne annulations by C–H/Het–H activation of aryl carbamates or phenols in protic media (Electronic supplementary information (ESI) available. See DOI: 10.1039/c8cc07732k)
by Ruhuai Mei and Julian Koeller and Lutz Ackermann
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 91, pp. 12879 - 12882
Electrooxidative peri-C–H activation was accomplished by versatile ruthenium(ii) catalysis in terms of C–H/N–H and C–H/O–H functionalization. Thus, alkyne... 
Transition metals | Ruthenium | Oxidizing agents | Activation | Selectivity | Ruthenium compounds | Electrocatalysis | Carbamates (tradename) | Oxidants | Aromatic compounds | Phenols | Catalysis | Alkynes
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14. Carbon dioxide utilization in the efficient synthesis of carbamates by deep eutectic solvents (DES) as green and attractive solvent/catalyst systems (Electronic supplementary information (ESI) available. See DOI: 10.1039/c9nj02810b)
by Iman Dindarloo Inaloo and Sahar Majnooni
New Journal of Chemistry, ISSN 1144-0546, 01/2019, Volume 43, Issue 28, pp. 11275 - 11281
A green and eco-friendly solvent/catalyst system based on a deep eutectic solvent (DES) was devised and developed for the simple synthesis of carbamates... 
Solvents | Carbamates (tradename) | Synthesis | Amines | Catalysts | Halides | Choline | Carbon dioxide | Zinc chlorides | Catalysis | Aliphatic compounds | Aliphatic amines
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15. Full Text Formation of Olefins by Eliminative Dimerization and Eliminative Cross‐Coupling of Carbenoids: A Stereochemical Exercise
by Blakemore, Paul R and Hoffmann, Reinhard W
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 2, pp. 390 - 407
Two carbenoids combine to generate an olefin by a mechanism involving formation of an ate complex, 1,2‐metalate rearrangement, and β‐elimination. As each stage... 
stereochemistry | carbenoids | stereoablation | stereospecific transformations | alkene synthesis | Carbamates | Olefins | Cross coupling | Carbamates (tradename) | Reviews | Alkenes | Hybridization | Epoxides | Isomers | Dimerization
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16. Electrochemical Hofmann rearrangement mediated by NaBr: practical access to bioactive carbamates
by Lijun Li and Mengyu Xue and Xin Yan and Wenmin Liu and Kun Xu and Sheng Zhang
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 25, pp. 4615 - 4618
An electrochemical Hofmann rearrangement is reported. With the mediation of NaBr, highly corrosive and toxic halogens are avoided. Moreover, this efficient and... 
Amantadine | Carbamates (tradename) | Halogens | Electrochemistry | Amides | Biocompatibility | Hofmann rearrangement
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17. Full Text A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles
by Li, Tian‐Ren and Cheng, Bei‐Yi and Wang, Ya‐Ni and Zhang, Mao‐Mao and Lu, Liang‐Qiu and Xiao, Wen‐Jing
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12422 - 12426
A copper‐catalyzed decarboxylative amination/hydroamination sequence of propargylic carbamates with various nucleophiles is described for the first time. It... 
copper | indoles | synthetic methods | alkynes | hydroamination | SULFUR YLIDES | SUBSTITUTION | PROPARGYLIC ESTERS | ENANTIOSELECTIVE SYNTHESIS | 2-(AMINOMETHYL)INDOLES | QUATERNARY STEREOCENTERS | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | FORMAL 3+2 CYCLOADDITION | AMINES | ACETATES | Carbamates | Copper | Carbamates (tradename) | Amination | Catalysts | Efficiency | Metals | Indoles | Nucleophiles | Chemical synthesis | Intermediates
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18. Full Text Carbamate Synthesis Using a Shelf‐Stable and Renewable C1 Reactant
by Dobi, Zoltán and Reddy, B. Narendraprasad and Renders, Evelien and Van Raemdonck, Laurent and Mensch, Carl and De Smet, Gilles and Chen, Chen and Bheeter, Charles and Sergeyev, Sergey and Herrebout, Wouter A and Maes, Bert U. W
ChemSusChem, ISSN 1864-5631, 07/2019, Volume 12, Issue 13, pp. 3103 - 3114
4‐Propylcatechol carbonate is a shelf‐stable, renewable C1 reactant. It is easily prepared from renewable 4‐propylcatechol (derived from wood) and dimethyl... 
carbamates | renewable resources | acid catalysts | zinc | C1 building blocks | building blocks | Usage | Carbonates | Organic compounds | Distillation | Lewis acid | Solvents | Carbamates (tradename) | Amines | Shelves | Alcohol | Alcohols
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19. Full Text Stereospecific Synthesis of Alkenes by Eliminative Cross‐Coupling of Enantioenriched sp3‐Hybridized Carbenoids
by Wu, Zhenhua and Sun, Xun and Potter, Kristin and Cao, Yang and Zakharov, Lev N and Blakemore, Paul R
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12285 - 12289
1‐Aryl‐1,2‐dialkylethenes were generated by a sequence of electrophilic substitution, 1,2‐metalate rearrangement, and β‐elimination initiated by the addition... 
carbenoids | stereoablation | organometallic reagents | alkenes | metalate rearrangements | Substitution reactions | Carbamates | Enantiomers | Olefins | Cross coupling | Carbamates (tradename) | Alkenes | Aromatic compounds | Bias | Yield | Coupling | Hybridization
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20. Highly enantioselective synthesis of trifluoromethyl cyclopropanes by using Ru(ii)–Pheox catalysts
by Manato Kotozaki and Soda Chanthamath and Takuji Fujii and Kazutaka Shibatomi and Seiji Iwasa
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 40, pp. 5110 - 5113
An asymmetric synthesis of various trifluoromethyl cyclopropanes from olefins, such as vinyl ferrocene, vinyl ethers, vinyl amines, vinyl carbamates and... 
Amines | Alkenes | Catalysts | Vinyl ethers | Enantiomers | Stereoselectivity | Carbamates (tradename) | Cyclopropane | Catalysis | Ethers | Dienes | Chemical synthesis | Organic compounds
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