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Angewandte Chemie, ISSN 0044-8249, 01/2018, Volume 130, Issue 1, pp. 325 - 329
In this work, we describe a palladium‐catalyzed intermolecular O acylation of α‐diazoesters with ortho‐bromobenzaldehydes. The C(sp2)−H bond activation of the... 
Acylierungen | Metallacyclen | Palladium | Carbenkomplexe | ortho-Brombenzaldehyde | Diazo compounds | Acylation | Hydrogen bonds | Modular units | Aromatic compounds
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2014, Volume 126, Issue 32, pp. 8567 - 8571
The CAAC [CAAC=cyclic (alkyl)(amino)carbene] family of carbene ligands have shown promise in stabilizing unusually low‐coordination number transition‐metal... 
Niederkoordinierte Komplexe | Eisen | CAAC‐Liganden | Carbenkomplexe | Cobalt
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 40, pp. 12432 - 12435
The first AuIII carbene complex was prepared by reacting a geminal dianion with a (P,C) cyclometalated AuIII precursor. Its structure and bonding situation... 
Gold(III) | Nukleophile Schrock-Carbene | Geminale Dianionen | Carbenkomplexe | C=C-Kupplungen
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2019, Volume 131, Issue 26, pp. 8926 - 8930
Gold carbenes of the general type [LAu=CR2]+ are sufficiently long‐lived for spectroscopic inspection only if the substituents compensate for the largely... 
Gold | Cyclopropane | Carbeniumionen | Carbenkomplexe | NMR-Spektroskopie | Analysis | Cyclopropane compounds | Organic chemistry | Spectroscopy | Anions | Profiling | Fluorine | Inspection | Bonding strength | Electron density | Carbenes | Substrates | Stilbene
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2019, Volume 131, Issue 11, pp. 3595 - 3599
Cyclopropanation reactions of styrene derivatives with donor–acceptor carbenes formed in situ are significantly more enantioselective when catalyzed by the... 
Dimetallkatalysatoren | Cyclopropanierung | Rhodium | Bismut | Carbenkomplexe | Bismuth | Enantiomers | Anisotropy | Cyclopropane compounds | Rhodium compounds | Catalysts | Leucine | Carbenes | Aromatic compounds | Styrene | Ligands | Catalysis | Binding sites
Journal Article
Angewandte Chemie, ISSN 0044-8249, 01/2014, Volume 126, Issue 4, pp. 1183 - 1187
Die Chemie der N‐heterocyclischen Carbene (NHCs) wird von N,N′‐dialkylierten oder ‐diarylierten Derivaten dominiert. Derartige Carbenliganden werden... 
Oxidative Additionen | Palladium | Carbenkomplexe | N‐heterocyclische Carbene | Cytokinins
Journal Article
Angewandte Chemie, ISSN 0044-8249, 12/2015, Volume 127, Issue 51, pp. 15672 - 15676
The dirhodium carbene derived from bis(4‐methoxyphenyl)diazomethane and [Rh(tpa)4]⋅CH2Cl2 (tpa=triphenylacetate) was characterized by UV, IR, and NMR... 
Gold | Homogene Katalyse | Rhodium | Carbenkomplexe | Transmetallierung | Diazo compounds | Crystals | Nuclear magnetic resonance spectroscopy | Catalysis | Structure | Methods | Infrared spectroscopy | Rhodium compounds | Diffraction | NMR spectroscopy | Carbenes | Crystal structure
Journal Article
1999, ISBN 3527296255, xxv, 283
There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene... 
Carbenes (Methylene compounds) | Synthesis | Organic compounds | Chemistry | Transition metals | Organometallic compounds
Book
Angewandte Chemie, ISSN 0044-8249, 01/2018, Volume 130, Issue 5, pp. 1320 - 1324
The [(P,P)Au=C(Ph)CO2Et]+ complex 3 [where (P,P) is an o‐carboranyl diphosphine ligand] was prepared by diazo decomposition at −40 °C. It is the first α‐oxo... 
Gold | Homogene Katalyse | Diazoverbindungen | Zweizähnige Liganden | Carbenkomplexe
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2016, Volume 128, Issue 34, pp. 10211 - 10214
The rhenium(I)‐catalyzed generation of α,β‐unsaturated carbene complex intermediates from easily available propargyl ethers was achieved for the concise... 
Vinylidene | Ungesättigte Carbenkomplexe | Rhenium | Cycloadditionen | Propargylether | Cycloaddition | Construction | Derivatives | Ethers | Carbenes
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2014, Volume 126, Issue 32, pp. 8572 - 8576
The combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of unprecedented low‐coordinate iron(0)... 
Alkenkomplexe | Niederkoordinierte Komplexe | Eisen | Carbenkomplexe | Cuba | Utilities | Olefins | Ligands | Reducing agents | Carbenes | Conversion | Furnishings | Dipping
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2010, Volume 122, Issue 28, pp. 4822 - 4837
Die Aktivierung einer einzelnen sp3‐C‐H‐Bindung von Alkanen und ihren Derivativen durch elektronenreiche Übergangsmetallkomplexe wurde seit den 1982... 
Iridium | C‐H‐Aktivierung | Carbenkomplexe | Osmium | Platin
Journal Article