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carboligation (63) 63
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ChemBioChem, ISSN 1439-4227, 03/2017, Volume 18, Issue 5, pp. 483 - 483
The inside back cover picture shows two positive variants of thermostable transketolase from Geobacillus stearothermophilus (TKGst) obtained by saturation... 
protein engineering | carboligation | biocatalysis | transketolases | directed evolution
Journal Article
Chemie Ingenieur Technik, ISSN 0009-286X, 08/2012, Volume 84, Issue 8, pp. 1397 - 1397
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2015, Volume 80, Issue 7, pp. 3597 - 3610
An exploration into the origin of chemoselectivity in the NHC-catalyzed cross-benzoin reaction reveals several key factors governing the preferred pathway. In... 
TRIAZOLIUM SALTS | ACYLOIN CONDENSATIONS | MECHANISM | C BOND FORMATION | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | STETTER REACTION | BENZALDEHYDE LYASE | AROMATIC-ALDEHYDES | CARBOLIGATION | CYANIDE
Journal Article
Chemie Ingenieur Technik, ISSN 0009-286X, 09/2010, Volume 82, Issue 9, pp. 1533 - 1533
Journal Article
by Kara, S
Chemie Ingenieur Technik, ISSN 0009-286X, 09/2010, Volume 82, Issue 9, pp. 1528 - 1529
Journal Article
Organic Letters, ISSN 1523-7060, 05/2013, Volume 15, Issue 9, pp. 2214 - 2217
An electron-deficient, valine-derived triazolium salt is shown to catalyze a highly chemo- and enantioselective cross-benzoin reaction between aliphatic... 
TRIAZOLIUM SALTS | INTERMOLECULAR STETTER REACTIONS | MOIETY | ACYLOIN CONDENSATIONS | CARBENE CATALYSTS | C BOND FORMATION | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | CARBOLIGATION | CYCLIZATION
Journal Article
Green Chemistry, ISSN 1463-9262, 12/2010, Volume 12, Issue 12, pp. 224 - 2245
The enzymatic carboligation of aldehydes (C-C bond formation) catalyzed by benzaldehyde lyase (BAL) affords chiral α-hydroxy-ketones under mild reaction... 
BIOTECHNOLOGY | KETONES | GREEN SOLVENTS | ASYMMETRIC-SYNTHESIS | CONVERSION | BIOTRANSFORMATIONS | CHEMISTRY | CARBOLIGATION | CHEMISTRY, MULTIDISCIPLINARY | BIOCATALYSIS
Journal Article
Free Radical Biology and Medicine, ISSN 0891-5849, 02/2018, Volume 115, pp. 136 - 145
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2018, Volume 130, Issue 19, pp. 5565 - 5569
Dihydroxyacetone phosphate (DHAP)‐dependent rhamnulose aldolases display an unprecedented versatility for ketones as electrophile substrates. We selected and... 
Verzweigte Zucker | Carboligation | Biokatalyse | Tertiäre Alkohole | Aldolasen | Phosphates | Enzymes | Ketones | Aldehydes | Fructose | Alcohols | Life Sciences | Biochemistry, Molecular Biology
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 21, pp. 7539 - 7542
Morpholinone- and piperidinone-derived triazolium salts are shown to catalyze highly chemoselective cross-benzoin reactions between aliphatic and aromatic... 
ASYMMETRIC-SYNTHESIS | ACYLOIN CONDENSATIONS | MECHANISM | AZOLIUMS | STETTER REACTION | AROMATIC-ALDEHYDES | CARBOLIGATION | BICYCLIC THIAZOLIUM SALTS | ALIPHATIC-ALDEHYDES | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | Research | Chemical properties | Catalysis | Aldehydes | Carbenes | Heterocyclic aromatic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2019, Volume 58, Issue 37, pp. 12960 - 12963
Pickering emulsions (PEs) are particle‐stabilized multiphase systems with promising features for synthetic applications. Described here is a novel, simplified... 
silicone | cells | carboligation | emulsions | biocatalysis | CATALYSIS | WATER EMULSIONS | PARTICLES | WETTABILITY | CHEMISTRY, MULTIDISCIPLINARY | Cells | Catalysis | Stereoselectivity | Aquatic environment | Emulsions | E coli | Benzaldehyde | Hydrophobicity | Biocatalysts | Silicones | Substrates | Benzoin
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2017, Volume 129, Issue 19, pp. 5442 - 5447
Enzyme, die asymmetrische C‐C‐Verknüpfungen katalysieren, sind typischerweise hoch spezifisch für ihre nukleophilen Donorsubstrate. Mittels strukturbasierter... 
Asymmetrische Synthesen | Acyloine | Carboligation | Biokatalyse | Protein-Engineering
Journal Article
Biotechnology Progress, ISSN 8756-7938, 11/2019, Volume 35, Issue 6, pp. e2868 - n/a
The kinetic description of enzyme‐catalyzed reactions is a core task in biotechnology and biochemical engineering. In particular, mechanistic kinetic models... 
parameter estimation | branched reaction networks | ThDP‐dependent enzymes | cross‐carboligation | kinetic modeling | Biotechnology | Enzymes | Pathways | Thiamine diphosphate | Benzaldehyde | Chemical reactions | Pseudomonas fluorescens | Enantiomers | Reaction mechanisms | Biochemical engineering | Thiamine
Journal Article
Green Chemistry, ISSN 1463-9262, 2017, Volume 19, Issue 2, pp. 380 - 384
(S)-Phenylacetylcarbinol [(S)-PAC] and its derivatives are valuable intermediates for the synthesis of various active pharmaceutical ingredients (APIs), but... 
Naturvetenskap | Natural Sciences | Kemi | Chemical Sciences
Journal Article
Green Chemistry, ISSN 1463-9262, 2017, Volume 19, Issue 2, pp. 380 - 384
(S)-Phenylacetylcarbinol [(S)-PAC] and its derivatives are valuable intermediates for the synthesis of various active pharmaceutical ingredients (APIs), but... 
KETONES | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | ENZYME | BIOCATALYTIC STRATEGIES | CARBOLIGATION | ACETALDEHYDE | CHEMISTRY, MULTIDISCIPLINARY | Carbon-carbon composites | Enzymes | Synthesis | Asymmetry | Ingredients | Derivatives | Bonding | Optimization
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 2015, Volume 357, pp. 1715 - 1720
Transketolase (TK) from various origins (including Escherichia coli and yeast) has been described to be fully enantiomer specific for (2R)-hydroxyaldehyde... 
Chemical Sciences
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 08/2012, Volume 2, Issue 8, pp. 1580 - 1589
Although biotransformations implementing alcohol dehydrogenases (ADHs) are widespread, enzymes which catalyse the reduction and oxidation of sterically... 
2-HYDROXY KETONES | ACYLOIN CONDENSATIONS | REDUCTION | CATALYZED ENANTIOSELECTIVE DIBORATION | C BOND FORMATION | HYDROXY KETONES | ASYMMETRIC DIHYDROXYLATION | CHEMISTRY, PHYSICAL | BENZALDEHYDE LYASE | ENZYMATIC CARBOLIGATION | SIMPLE ALKENES
Journal Article
Chemical Physics Letters, ISSN 0009-2614, 06/2017, Volume 677, pp. 30 - 34
[Display omitted] •The biosynthesis of R-phenylacetyl carbinol (R-PAC) is addressed theoretically for first time.•The protonation states of the N1′ and N4′... 
CATALYSIS | ALPHA-HYDROXY KETONES | ACETOHYDROXYACID SYNTHASE | ENZYME | CARBOLIGATION REACTION | SUBSTRATE | ESCHERICHIA-COLI | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | INTERMEDIATE | Synthesis | Organic compounds | Methanol | Pyrimidines | Specific gravity | Force and energy | Density functionals | Nitrogen
Journal Article
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