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carbopalladation (315) 315
chemistry, organic (222) 222
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cascade carbopalladation (25) 25
ketones (25) 25
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1,1‐disubstituted alkenes (24) 24
addition–elimination (24) 24
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alkynylpalladation–reductive elimination (24) 24
allylpalladation (24) 24
arene substitution (24) 24
aryl ketones (24) 24
carbopalladation via palladacyclopropanes (24) 24
carbopalladation via palladacyclopropenes (24) 24
carbopalladation–dehydropalladation (24) 24
intermolecular heck reaction (24) 24
molecular structure (24) 24
palladium‐carbene complexes (24) 24
palladium‐carbyne complexes (24) 24
palladium‐catalyzed carbozincation (24) 24
palladium‐catalyzed tandem (24) 24
related carbopalladation reactions (24) 24
related reactions of alkenes (24) 24
related reactions of alkynes (24) 24
related reactions of dienes (24) 24
synthesis of natural products (24) 24
π‐compounds (24) 24
aryl halides (22) 22
domino reactions (21) 21
chemical reactions (20) 20
iodides (20) 20
palladium catalysts (20) 20
anion capture processes (19) 19
c-h activation (19) 19
metal-promoted cyclization (19) 19
arylation (18) 18
asymmetric-synthesis (18) 18
domino reaction (18) 18
stereoisomerism (18) 18
analysis (17) 17
aryl (17) 17
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heteroannulation (17) 17
olefins (17) 17
synthesis (17) 17
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chemistry, applied (16) 16
chemistry, inorganic & nuclear (16) 16
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cascade carbopalladation reaction (14) 14
cycloisomerization (14) 14
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activation (13) 13
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Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14389 - 14393
A palladium‐catalyzed cascade reaction based on the trapping of transient alkyl–PdII intermediates with arynes encompassing a C−H activation step has been... 
cascade reactions | aryne | C−H activation | carbopalladation | spirocycles
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4119 - 4123
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 8, pp. 2154 - 2157
We disclose a Pd-catalyzed reaction protocol that regioselectively difunctionalizes unactivated olefins with aryl iodides and tethered enolates. The current... 
ALCOHOLS | HALIDES | COUPLING REACTIONS | TANDEM ARYLATION | CHEMISTRY, ORGANIC | CARBOPALLADATION | ARYL | DIARYLATION | DERIVATIVES | TERMINAL ALKENES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2018, Volume 83, Issue 24, pp. 15361 - 15371
A syn-arylative nickelation followed by nucleophilic syn-selective cyclization of o-propargyloxy benzaldehydes is achieved toward the synthesis of chromanol... 
1,6-ENYNES | CHEMISTRY, ORGANIC | CARBOPALLADATION | TANDEM CYCLIZATION | COUPLINGS | ASYMMETRIC ARYLATIVE CYCLIZATION | DERIVATIVES | EFFICIENT
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2017, Volume 359, Issue 14, pp. 2407 - 2413
Journal Article
Organic Letters, ISSN 1523-7060, 12/2013, Volume 15, Issue 23, pp. 5940 - 5943
A simple and efficient palladium-catalyzed oxidative coupling between 2-alkynyl anilines and allylic alcohols is described by using cheap and green dioxygen as... 
PALLADIUM | ALKENES | CARBONYLATION | CHEMISTRY, ORGANIC | CATALYZED CYCLIZATION | CARBOPALLADATION | BENZOFURANS | ALKYNES | EFFICIENT | DERIVATIVES | C DOUBLE-BONDS
Journal Article
Synthesis, ISSN 0039-7881, 11/2019, Volume 51, Issue 22, pp. 4137 - 4146
Abstract Development of strategies for molecule functionalization by dearomatization has surged in the last two decades. The benefits of overcoming the... 
short review | nickel | migratory insertion | dearomatization | CATALYTIC ASYMMETRIC DEAROMATIZATION | CHEMISTRY, ORGANIC | palladium | difunctionalization | carbopalladation | INDOLES
Journal Article
Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 7, pp. 1720 - 1723
A new rhodium-catalyzed asymmetric arylative cyclization of nitrogen-tethered alkyne-enoate with arylboronic acids is described. In this process two new... 
ASYMMETRIC 1,4-ADDITION | TANDEM | CONSTRUCTION | COMPLEXES | CHEMISTRY, ORGANIC | DIENE LIGANDS | CARBOPALLADATION | ALDEHYDES | EFFICIENT | ARYLBORONIC ACIDS | TRANSFORMATIONS
Journal Article
Organic Letters, ISSN 1523-7060, 03/2018, Volume 20, Issue 6, pp. 1538 - 1541
A novel palladium-catalyzed domino cyclization/alkylation of terminal alkynes was achieved for the synthesis of alkynyl-functionalized 3,3-disubstituted... 
HALIDES | IODIDES | CARBOPALLADATION/C-H FUNCTIONALIZATION | INTRAMOLECULAR CARBOLITHIATION | INDOLINES | OXINDOLES | CHEMISTRY, ORGANIC | BOND FORMATION | EFFICIENT | BROMIDES | CARBOXYLIC-ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2019, Volume 141, Issue 1, pp. 560 - 571
Understanding the structure-property relationships in antiaromatic molecules is crucial for controlling their electronic properties and designing new organic... 
SINGLET DIRADICAL CHARACTER | PENTALENE DERIVATIVES | DIBENZOPENTALENES | CASCADE CARBOPALLADATION REACTION | CRYSTAL-STRUCTURES | SYSTEMS | AROMATIC CHARACTER | CURRENT DENSITIES | CLOSED-SHELL | CHEMISTRY, MULTIDISCIPLINARY | HYDROCARBON
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2010, Volume 46, Issue 1, pp. 130 - 132
Pd/PtBu(3)-catalysed intramolecular nucleophilic addition of aryl halides to alpha-ketoamides in the presence of nBuOH and base has been realized with high... 
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 11, pp. 4350 - 4354
A Pd-catalyzed domino process involving a double norbornene insertion/annulation reaction was developed for the expeditious synthesis of overcrowded olefins.... 
KETONES | HELICAL ALKENES | SWITCHES | CARBOPALLADATION/C-H-ACTIVATION | ANNULATION | CHEMISTRY, ORGANIC | ELIMINATION | CASCADE | DERIVATIVES | ARTIFICIAL MOLECULAR MACHINES | CYCLIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 4, pp. 1331 - 1335
A novel type of π‐helicenes is reported, in which the π‐system is truncated to an all‐s‐cis all‐Z oligoene chain. A domino sequence was developed, consisting... 
helicenes | carbopalladation | domino reaction | Carbopalladation | Helicenes | Domino reaction
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 24, pp. 6946 - 6950
A novel palladium(0)‐catalyzed dearomative cyclization reaction of bromophenols with (1,n)‐diynes has been developed for building two new types of tricyclic... 
cyclizations | palladium | arenes | alkynes | dearomatization | NAPHTHOLS | OXIDATIVE DEAROMATIZATION | CARBOPALLADATION | METAL-CATALYZED CYCLOISOMERIZATIONS | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALLYLIC DEAROMATIZATION | PHENOLS | CONSTRUCTION | DOMINO APPROACH | DERIVATIVES | Enantiomers | Palladium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 9, pp. 3189 - 3192
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2016, Volume 81, Issue 5, pp. 2087 - 2093
The benzoyl peroxide (BPO) promoted carboannulation of ynones with alkanes is developed, affording a series of 2-alkyl-3-aryl indenones in moderate to good... 
6-MEMBERED HETEROCYCLIC RINGS | CHLORIDES | CHEMISTRY, ORGANIC | MEOTF-INDUCED CARBOANNULATION | BOND FORMATION | CARBOPALLADATION | C-H FUNCTIONALIZATION | ALKYNES | PALLADIUM-CATALYZED ANNULATION | CYCLIZATION | 1,3-DIARYLPROPYNONES | Chemical bonds | Alkanes | Usage | Chemical properties | Chemical synthesis | Analysis
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2016, Volume 116, Issue 14, pp. 8256 - 8311
Journal Article
Organic Letters, ISSN 1523-7060, 12/2006, Volume 8, Issue 26, pp. 5987 - 5990
A cationic palladium complex catalyzed addition of arylboronic acids to nitriles to yield aryl ketones with moderate to good yields was developed. A one-step... 
BENZOCYCLIC KETONES | PALLADIUM | PD(II) COMPLEXES | METAL-CATALYSTS | CHEMISTRY, ORGANIC | CATALYZED CYCLIZATION | CARBONYL-COMPOUNDS | CARBOPALLADATION | ARYL KETONES | ALKYNES | DERIVATIVES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 12, pp. 3270 - 3274
Pentalenes represent highly reactive Hückel antiaromatics with 8π electrons. Usually, pentalenes are stabilized by incorporation of two benzene rings in a... 
antiaromaticity | pentalenes | dehydroannulenes | π-conjugation | transannular cyclization | ELECTRON-TRANSFER OXIDATION | CASCADE CARBOPALLADATION REACTION | ENERGY-GAP | CHEMISTRY, MULTIDISCIPLINARY | FIELD-EFFECT TRANSISTORS | pi-conjugation | AROMATICITY | CONJUGATED POLYMERS | GEM-DIBROMOOLEFINS | SYSTEMS | DERIVATIVES | INDEPENDENT CHEMICAL-SHIFTS | Hydrocarbons
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 05/2005, Volume 38, Issue 5, pp. 413 - 422
The domino-type combination of consecutive palladium-catalyzed cross-coupling reactions with subsequent pericyclic transformations offers a very fast access to... 
BENZENE-DERIVATIVES | ORGANIC-SYNTHESIS | CYCLIC CARBOPALLADATION | COUPLING REACTIONS | DIELS-ALDER REACTION | CONSTRUCTION | VERSATILE SYNTHESIS | COPE REARRANGEMENT | SUBSTITUTION-REACTIONS | TWOFOLD HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article