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1. Full Text Polymer scission in turbulent flows
by Vincenzi, Dario and Watanabe, Takeshi and Ray, Samriddhi Sankar and Picardo, Jason R
Journal of fluid mechanics, ISSN 0022-1120, 04/2021, Volume 912
Turbulent flow | Direct numerical simulation | Probability distribution | Relaxation time | Reduction | Energy dissipation | Dynamics | Cleavage | Isotropic turbulence | Coupling | Kinetic energy | Polymers | Turbulence | Statistical analysis | Computational fluid dynamics | Reynolds number | Chain scission | Velocity | Survival | Dynamic tests | Simulation | Drag reduction | Stochasticity | Stochastic models | Design of experiments
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2. Full Text Effects of Chain Transfer Agent and Temperature on Branching and β‐Scission in Radical Polymerization of 2‐Ethylhexyl Acrylate
by Lena, Jean‐Baptiste and Deschamps, Michaël and Sciortino, Natasha F and Masters, Sarah L and Squire, Marie A and Russell, Gregory T
Macromolecular chemistry and physics, ISSN 1022-1352, 05/2018, Volume 219, Issue 9, pp. 1700579 - n/a
NMR | poly(2‐ethylhexyl acrylate) | electrospray ionization (ESI)‐mass spectrometry | branching | β‐scission | β-scission | poly(2-ethylhexyl acrylate) | electrospray ionization (ESI)-mass spectrometry | Polymer Science | Physical Sciences | Science & Technology | Temperature | Nuclear magnetic resonance--NMR | Bulk polymerization | Dodecane | Polymerization | Chain branching | Chain scission | Patching | Chain transfer | Ionization | Cleavage | Chemical synthesis | Mass spectrometry | Material chemistry | Chemical Sciences
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3. Full Text A Radical Intermediate in Tyrosine Scission to the CO and CN⁻ Ligands of FeFe Hydrogenase
by Jon M. Kuchenreuther and William K. Myers and Troy A. Stich and Simon J. George and Yaser NejatyJahromy and James R. Swartz and R. David Britt
Science (American Association for the Advancement of Science), ISSN 0036-8075, 10/2013, Volume 342, Issue 6157, pp. 472 - 475
Protons | Proteins | Enzymes | Spectroscopy | Electronic structure | REPORTS | Atoms | Ligands | Signals | Continuous spectra | Electrons | Science & Technology - Other Topics | Multidisciplinary Sciences | Science & Technology | Catalytic Domain | Bacterial Proteins - chemistry | Bacterial Proteins - genetics | Shewanella - enzymology | Iron-Sulfur Proteins - genetics | Carbon Monoxide - chemistry | S-Adenosylmethionine - chemistry | Catalysis | Hydrogenase - chemistry | Iron-Sulfur Proteins - chemistry | Tyrosine - chemistry | Spectrum analysis | Index Medicus | Tyrosine | Hydrogenase | Chains | Amino acids | Scission | Radicals
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4. Full Text Entropy‐Driven Selectivity for Chain Scission: Where Macromolecules Cleave
by Pahnke, Kai and Brandt, Josef and Gryn'ova, Ganna and Lin, Ching Y and Altintas, Ozcan and Schmidt, Friedrich G and Lederer, Albena and Coote, Michelle L and Barner‐Kowollik, Christopher
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2016, Volume 55, Issue 4, pp. 1514 - 1518
thermodynamics | entropic effects | cycloadditions | polymers | supramolecular chemistry | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Polymerization | Nuclear magnetic resonance spectroscopy | Polymers | Analysis | Entropy | Size exclusion chromatography | Addition polymerization | Macromolecules | Chain scission | Selectivity | Chains (polymeric) | Chromatography | Degradation | Magnetic resonance spectroscopy | Chain transfer | Covalence | Temperature effects | Reagents | Chemical bonds | Cleavage | Models | Mathematical models | NMR spectroscopy | Adducts
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5. Full Text Quantitative analysis of random scission and chain-end scission in the thermal degradation of polyethylene
by Ueno, Tomonaga and Nakashima, Erika and Takeda, Kunihiko
Polymer degradation and stability, ISSN 0141-3910, 2010, Volume 95, Issue 9, pp. 1862 - 1869
Radical transfer | Polyethylene | Random scission | β-Scission | Thermal degradation | Polymer Science | Physical Sciences | Science & Technology | Degradation | Applied sciences | Organic polymers | Physicochemistry of polymers | Chemical reactions and properties | Exact sciences and technology | Computer-generated environments | Computer simulation | Mechanical engineering | Analysis | Polyethylenes | Pathways | Chain scission | Chains (polymeric) | Radicals | Scission | Quantitative analysis
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6. Full Text Sonication-induced scission of molecular bottlebrushes: Implications of the “hairy” architecture
by Li, Yuanchao and Niu, Zhenbin and Burdyńska, Joanna and Nese, Alper and Zhou, Yang and Kean, Zachary S and Dobrynin, Andrey V and Matyjaszewski, Krzysztof and Craig, Stephen L and Sheiko, Sergei S
Polymer (Guilford), ISSN 0032-3861, 02/2016, Volume 84, pp. 178 - 184
Sonication | Polymer brushes | Mechanochemistry | Polymer Science | Physical Sciences | Science & Technology | Polymers | Atomic force microscopy | Backbone | Solvents | Coronas | Architecture | Imaging | Chains (polymeric) | Scission | Constraining
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7. Full Text Kinetic Analysis of Mechanochemical Chain Scission of Linear Poly(phthalaldehyde)
by Peterson, Gregory I and Boydston, Andrew J
Macromolecular rapid communications., ISSN 1022-1336, 09/2014, Volume 35, Issue 18, pp. 1611 - 1614
mechanochemistry | polymers | depolymerization | materials | Depolymerization | Polymers | Mechanochemistry | Materials | Degradation | Applied sciences | Organic polymers | Physicochemistry of polymers | Chemical reactions and properties | Exact sciences and technology | Hydrolysis | o-Phthalaldehyde - chemistry | Sonication | Temperature | Models, Chemical | Time Factors | Models, Molecular | Polymerization | Polymers - chemistry | Molecular Structure | Kinetics | Index Medicus | Ceilings | Rate constants | Reagents | Chain scission | Molecular weight | Fragmentation
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8. Full Text Excellent Stability in Water of Single‐Chain Nanoparticles against Chain Scission by Sonication
by González‐Burgos, Marina and González, Edurne and Pomposo, José A
Macromolecular rapid communications., ISSN 1022-1336, 03/2018, Volume 39, Issue 6, pp. e1700675 - n/a
nanoparticles | chain scission | stability | ultrasound | sonication | Polymer Science | Physical Sciences | Science & Technology | Nanoparticles | Sonication | Prepolymers | Stability | Radiation | Irradiation | Cleavage | Chain scission | Polymers | Ultrasound | Index Medicus
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9. Full Text Cp2ZrHCl induced catalytic chain scission of diene-based polymers under mild conditions: Influence of chemical environment around C=C bonds
by Gu, Yang and Lin, Yichao and Zheng, Jun and Ye, Lin and Wang, Song and Li, Sanxi and Ma, Li and Cui, Dongmei and Tang, Tao
Polymer (Guilford), ISSN 0032-3861, 01/2019, Volume 161, pp. 181 - 189
Organometallic catalyst | Chain scission | β-alkyl elimination | Catalytic reactions | Waste rubbers | Polymer Science | Physical Sciences | Science & Technology
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10. Full Text Flow–induced chain scission in dilute polymer solutions: Algorithm development and results for scission dynamics in elongational flow
by Sim, H. G and Khomami, B and Sureshkumar, R
Journal of rheology (New York : 1978), ISSN 0148-6055, 11/2007, Volume 51, Issue 6, pp. 1223 - 1251
Midpoint scission | Kramers chain | Brownian dynamics | TABS model | Elongational flow | Polymer scission | Mechanics | Technology | Science & Technology | Solution and gel properties | Rheology | Exact sciences and technology | Applied sciences | Organic polymers | Physicochemistry of polymers | Properties and characterization | Physics | Cross-disciplinary physics: materials science; rheology
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11. Full Text Insight into Chain Scission and Release Profiles from Photodegradation of Polycarbonate Microplastics
by Shi, Yanqi and Liu, Peng and Wu, Xiaowei and Shi, Huanhuan and Huang, Hexinyue and Wang, Hanyu and Gao, Shixiang
Water research (Oxford), ISSN 0043-1354, 02/2021, p. 116980
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12. Full Text Epimerization and chain scission of polylactides in the presence of an organic base, TBD
by Meimoun, Julie and Favrelle-Huret, Audrey and Bria, Marc and Merle, Nicolas and Stoclet, Grégory and De Winter, Julien and Mincheva, Rosica and Raquez, Jean-Marie and Zinck, Philippe
Polymer degradation and stability, ISSN 0141-3910, 11/2020, Volume 181, p. 1
Racemization | Plastic recycling | Chain scission | Epimerization | Polylactide | Organocatalysis | Polymer Science | Physical Sciences | Science & Technology | Stereoisomers | Catalysis | Mass spectrometry | Analysis | Infrared spectroscopy | Nuclear magnetic resonance--NMR | Stereoisomerism | Toluene | Polylactic acid | Chemical reactions | Molecular weight | Studies | Reaction time | Polymers | Chemical synthesis
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