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Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2006, Volume 45, Issue 8, pp. 1248 - 1252
Additive‐free: The chemoselective amide‐bond‐forming ligation between N‐alkylhydroxylamines and α‐ketoacids requires no reagents and the only by‐products are... 
chemoselectivity | peptides | amides | ketoacids | ligation reactions | Ligation reactions | Amides | Ketoacids | Peptides | Chemoselectivity
Journal Article
Synthesis, ISSN 0039-7881, 02/2019, Volume 51, Issue 3, pp. 747 - 756
Abstract A facile and chemoselective SnCl 2 -mediated mild reduction of regioisomeric 3- and 4-nitrofuroxans for the synthesis of amino­furazans and... 
paper | chemoselectivity | furazans | reduction | heterocycles | furoxans
Journal Article
Synlett, ISSN 0936-5214, 11/2017, Volume 28, Issue 18, pp. 2411 - 2414
Abstract A chemoselective method for the catalytic hydrosilylation of nitriles to either the imine or amine oxidation level is reported. The chemoselectivity... 
cluster | hydrosilylation | chemoselectivity | silicon | cooperativity | reduction
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 36, pp. 12632 - 12637
Herein, we described a nickel-catalyzed monofluoroalkenylation through defluorinative reductive cross-coupling of gem-difluoroalkenes with alkyl halides. Key... 
Journal Article
Synthesis, ISSN 0039-7881, 02/2019, Volume 51, Issue 4, pp. 944 - 952
Abstract As a Group IVB transition metal Lewis acid, hafnium triflate [Hf(OTf) 4 ] exhibited exceptionally high potency in desilylations. Since the amounts of... 
paper | hafnium triflate | regioselectivity | chemoselectivity | mechanism | desilylation
Journal Article
Synlett, ISSN 0936-5214, 05/2016, Volume 27, Issue 8, pp. 1274 - 1276
Abstract A method for the nucleophilic displacement of the triflate leaving group attached to terminally functionalized alkyl groups with nucleophilic silicon... 
letter | chemoselectivity | copper | silicon | nucleophilic substitution | transmetalation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2018, Volume 57, Issue 38, pp. 12573 - 12577
Full control over multiple competing coupling sites would enable straightforward access to densely functionalized compound libraries. Historically, the site... 
chemoselectivity | C−C coupling | arenes | homogeneous catalysis | palladium(I) dimer | Coupling (molecular) | Historical account | Historic buildings & sites | Site selection | Aromatic compounds | Air temperature | Halogenated | Palladium | Dimers | Bonding | Substrates | Alkylation | Communications | Communication
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 48, pp. 16387 - 16391
Unprecedented hydroxy-alkynylation and -alkenylation reactions of arylalkenes have been developed through electrochemically enabled addition of an... 
Journal Article
Synlett, ISSN 0936-5214, 06/2015, Volume 26, Issue 9, pp. 1145 - 1152
Abstract Conjugated siloles represent an important class of photoluminescence material. Traditional synthesis of siloles often suffered from low functional... 
synpacts | Metalation | Silicon | Rhodium | Chemoselectivity | Tandem reactions
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 39, pp. 12692 - 12714
This Perspective illustrates the defining characteristics of free radical chemistry, beginning with its rich and storied history. Studies from our laboratory... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Oxidation-Reduction | Sulfinic Acids - chemistry | Free Radicals - chemistry | Free radical reactions | Research | Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2016, Volume 138, Issue 8, pp. 2629 - 2637
Sub-nanometric Pd clusters on porous nanorods of CeO2 (PN-CeO2) with a high Pd dispersion of 73.6% exhibit the highest catalytic activity and best... 
Palladium catalysts | Usage | Chemical properties | Hydrogenation
Journal Article
Synlett, ISSN 0936-5214, 04/2017, Volume 28, Issue 7, pp. 825 - 830
Abstract Ph 3 P/I 2 –Et 3 N-mediated one-pot two-step esterification–cyclization toward 3-aryl coumarins and 3-aryl-4-methylcoumarins is reported. The reaction... 
letter | chemoselectivity | cyclization | phosphorous | carboxylic acids
Journal Article
Synthesis, ISSN 0039-7881, 05/2015, Volume 47, Issue 10, pp. 1455 - 1460
Abstract The reactivity of (chloromethyl)magnesium chloride–lithium chloride (ClCH 2 MgCl·LiCl), a mixed lithium–magnesium carbenoid, in reactions with... 
paper | chemoselectivity | carbenoids | aldehydes | organometallic reagents | chlorohydrins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 38, pp. 13404 - 13413
A novel catalytic system for oxidative cross-coupling of readily oxidized phenols with poor nucleophilic phenolic partners based on an iron... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2018, Volume 140, Issue 8, pp. 2862 - 2868
The Diels–Alder (DA) reaction is a cornerstone of synthesis, yet Nature does not use catalysts for intermolecular [4+2] cycloadditions. Attempts to create... 
Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2015, Volume 137, Issue 17, pp. 5638 - 5641
A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted... 
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 09/2010, Volume 16, Issue 33, pp. 10240 - 10249
SmI2/H2O reduces cyclic 1,3‐diesters to 3‐hydroxyacids with no over reduction. Furthermore, the reagent system is selective for cyclic 1,3‐diesters over... 
radical reactions | chemoselectivity | samarium | reduction | cyclization | Reduction | Samarium | Cyclization | Radical reactions | Chemoselectivity
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2017, Volume 139, Issue 43, pp. 15548 - 15553
We report a Mn-catalyzed electrochemical dichlorination of alkenes with MgCl2 as the chlorine source. This method provides operationally simple, sustainable,... 
Usage | Analysis | Electrochemistry | Chemical bonds | Chemical reactions | Research | Electrophiles
Journal Article