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dabn (14) 14
pd catalyst (13) 13
asymmetric catalysis (7) 7
biphenylphosphine biphep ligand (7) 7
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Organic Letters, ISSN 1523-7060, 10/2004, Volume 6, Issue 21, pp. 3699 - 3701
The tropos (chirally flexible) or atropos (chirally rigid) nature of BIPHEP−Rh complexes at room temperature critically depends on the amines complexed. The... 
ASYMMETRIC CATALYSIS | CHEMISTRY, ORGANIC | ACTIVATION | DABN | PD CATALYST | ENYNES
Journal Article
Chemical Communications, ISSN 1359-7345, 2008, Issue 41, pp. 5095 - 5097
Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an... 
BINAP | LIGANDS | DIPHOSPHINES | ENANTIOMER-SELECTIVE ACTIVATION | DABN | ENANTIOSELECTIVE HYDROGENATION | RESOLUTION | LEWIS-ACID CATALYSIS | BEARING | CHEMISTRY, MULTIDISCIPLINARY | PD CATALYST
Journal Article
IEEE Transactions on Neural Networks and Learning Systems, ISSN 2162-237X, 07/2018, Volume 29, Issue 7, pp. 3301 - 3306
Journal Article
Chemical Communications, ISSN 1359-7345, 2006, Issue 22, pp. 2365 - 2367
The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the... 
KETONES | DIASTEREOISOMER INTERCONVERSION | DIPHOSPHINES | MECHANISM | DABN | RESOLUTION | BIPHENYLPHOSPHINE BIPHEP LIGAND | TROPOS | CHEMISTRY, MULTIDISCIPLINARY | NUPHOS | PD CATALYST
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2003, Volume 44, Issue 19, pp. 3801 - 3804
We report the synthesis of a novel class of planar chiral bidentate aryl[2.2]paracyclophane ligands. For the first time in the [2.2]paracyclophanyl series the... 
ASYMMETRIC CATALYSIS | SUBSTITUTION | PALLADIUM | DABN | RESOLUTION | CHEMISTRY, ORGANIC | PD CATALYST
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2005, Issue 46, pp. 5799 - 5801
Axial and center chirality of Pd complexes with tropos biphenyl secondary diamine ligands is shown to be controlled by chiral amide ( R)-DABNTf, which can... 
ASYMMETRIC CATALYSIS | ACTIVATION | ENANTIOSELECTIVITY | DIPHOSPHINES | DABN | CHEMISTRY, MULTIDISCIPLINARY | NUPHOS | PD CATALYST
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2006, Volume 47, Issue 36, pp. 6361 - 6364
The tropos (chirally flexible) or atropos (chirally rigid) nature of BIPHEP–Rh complexes critically depends on amines and alcohols complexed. The BIPHEP–Rh... 
ASYMMETRIC CATALYSIS | ACTIVATION | DABN | 2-AMINO-2-HYDROXY-1,1-BINAPHTHYL | RESOLUTION | 2,2-DIAMINO-1,1-BINAPHTHYL | CHEMISTRY, ORGANIC | BIPHENYLPHOSPHINE BIPHEP LIGAND | BEARING | PD CATALYST | ENYNES | Enantiomers
Journal Article
Organic Letters, ISSN 1523-7060, 10/2003, Volume 5, Issue 21, pp. 3863 - 3866
Palladium and platinum complexes of conformationally flexible 1,3-butadiene-bridged diphosphines NUPHOS can be resolved with (S)-BINOL at elevated temperatures... 
ACHIRAL LIGANDS | ENANTIOMER-SELECTIVE ACTIVATION | DABN | CHEMISTRY, ORGANIC | BIPHENYLPHOSPHINE BIPHEP LIGAND | INTERCONVERSION | 1,4-BIS(DIPHENYLPHOSPHINO)-1,3-BUTADIENE-BRIDGED DIPHOSPHINE | TROPOS | PD CATALYST
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2006, Issue 22, pp. 2365 - 2367
The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the... 
Benzophenones - chemistry | Stereoisomerism | Models, Molecular | Crystallography, X-Ray | Hydrogenation | Ketones - chemical synthesis | Ketones - chemistry | Diamines - chemistry | Ligands | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Rhodium - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2003, Volume 42, Issue 44, pp. 5458 - 5461
Both axial and helical chirality are generated by complexation of the novel tetrakis(phosphanyl)terphenyl (tetraphos) ligand to a metal center (see picture).... 
ene reaction | palladium | chirality | isomerization | helical structures | Palladium | Helical structures | Ene reaction | Chirality | Isomerization | 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL | RESOLUTION | BIPHENYLPHOSPHINE BIPHEP LIGAND | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | HIGHLY ENANTIOSELECTIVE HYDROGENATION | DABN | TROPOS | ENE-REACTIONS | PD CATALYST
Journal Article
Journal Article
Heterocycles, ISSN 0385-5414, 11/2008, Volume 76, Issue 2, pp. 1525 - 1535
The Ru complex with the tropos benzophenone-derived diphosphine ligand could be chirally controlled to a single chiral conformation instantaneously with a... 
Ru Catalyst | "Self-adaptation" of Catalyst | Asymmetric Hydrogenation and Activation | Tropos Benzophenone-derived Ligand | ASYMMETRIC CATALYSIS | ENANTIOCONTROL | ACTIVATION | COMPLEXES | CHEMISTRY, ORGANIC | BIPHENYLPHOSPHINE BIPHEP LIGAND | Self-adaption of Catalyst | DABN | BEARING | TROPOS | PD CATALYST
Journal Article
Journal of Molecular Catalysis. A, Chemical, ISSN 1381-1169, 2003, Volume 196, Issue 1, pp. 125 - 129
Journal Article
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, ISSN 1381-1169, 04/2006, Volume 248, Issue 1-2, pp. 42 - 47
An efficient direct activation method was developed to transfer diastereopure lambda-[(BIPHEP)Pt(S-BINOL)] to highly active and selective enantiopure Lewis... 
BIPHEP | ASYMMETRIC CATALYSIS | PRACTICAL ACCESS | enantioselectivity carbonyl-ene | ALPHA-HYDROXY ESTERS | CHEMISTRY, PHYSICAL | COPPER(II) COMPLEXES | platinum | PURITIES | DABN | DIELS-ALDER REACTION | GLYOXYLATE | LIGAND | activation | PD CATALYST
Journal Article
01/2011, Volume 2011, Issue 1, 6
Chirality transfer from (S)‐2‐(aminomethyl)pyrrolidine to the tropos biphenyl skeleton has been observed in the preparation of a chirally flexible... 
Michael addition | Nitro ­olefins | Organocatalysts | Diastereoselectivity | Enantio­selectivity | Nitro olefins | Enantioselectivity | ASYMMETRIC CATALYSIS | ORGANOCATALYST | COMPLEXES | CHEMISTRY, ORGANIC | LIGANDS | DABN | BEARING | PD CATALYST
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