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dealkylative carbonylation (15) 15
chemistry, organic (9) 9
activation (5) 5
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palladium (5) 5
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Journal of organic chemistry, ISSN 1520-6904, 2020, Volume 85, Issue 4, pp. 2672 - 2679
A novel and efficient synthesis of isatoic anhydride derivatives was developed via palladium-catalyzed multistep tandem carbonylation/N-dealkylation/carbonylation reaction with alkyl as the leaving... 
FUNCTIONALIZATION | DEALKYLATIVE CARBONYLATION | ACTIVATION | TERTIARY-AMINES | CHEMISTRY | CHEMISTRY, ORGANIC | CLEAVAGE | DERIVATIVES | C-H BONDS | OXALYL AMIDE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2016, Volume 81, Issue 12, pp. 4974 - 4980
The first highly effective Pd/C-catalyzed oxidative N-dealkylation/carbonylation of various aliphatic as well as cyclic tertiary amines with alkynes has been described... 
DEALKYLATIVE CARBONYLATION | CARBON | CARBONYLATION REACTIONS | ALLYLIC AMINES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | BOND ACTIVATION | ARYL IODIDES | AMINOCARBONYLATION | C-H | Palladium catalysts | Amides | Usage | Carbonylation | Chemical properties
Journal Article
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 23, pp. 6432 - 6435
A novel method of palladium-catalyzed oxidative carbonylation of ketones, amines, and carbon monoxide for the synthesis of 4-quinolones has been developed... 
DEALKYLATIVE CARBONYLATION | 2-ARYL-4-QUINOLONES | ATOM ECONOMY | ANILINES | GREEN CHEMISTRY | CHEMISTRY, ORGANIC | OPTIMIZATION | DERIVATIVES | C-H BONDS | METAL-FREE | CYCLIZATION
Journal Article
by Yin, ZP and Xu, JX and Wu, XF
ACS catalysis, ISSN 2155-5435, 06/2020, Volume 10, Issue 11, pp. 6510 - 6531
Carbonylation, an efficient and straightforward approach for installing a carbonyl group into their parent compounds, is an important area in modern organic synthesis... 
nitrogen radical | OXIDATIVE CARBONYLATION | C(SP)-H BONDS | C-N bond activation | amide synthesis | ARENEDIAZONIUM SALTS | DIAZONIUM SALTS | TERTIARY-AMINES | CHEMISTRY, PHYSICAL | C-H BONDS | coupling | DEALKYLATIVE CARBONYLATION | CARBON-MONOXIDE | PALLADIUM-CATALYZED CARBONYLATION | carbonylation | METAL-FREE
Journal Article
Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 9, pp. 6266 - 6273
Transition-metal-catalyzed oxidative C-H cyclization of anilines has been an attractive and powerful strategy for the efficient construction of N-heterocycles.... 
DIOXYGEN ACTIVATION | DEALKYLATIVE CARBONYLATION | CARBONYLATION REACTIONS | ALLYLIC AMINES | ARYL HALIDES | INTERNAL ALKYNES | H BOND FUNCTIONALIZATION | SELECTIVE ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | INTRAMOLECULAR ANNULATION | MOLECULAR-OXYGEN
Journal Article
New journal of chemistry, ISSN 1369-9261, 2019, Volume 43, Issue 46, pp. 18072 - 18078
Palladium-catalyzed oxidative cross double carbonylation reaction between tertiary amines and alcohols using oxidant O 2 and KI as the additive affords oxamates... 
DEALKYLATIVE CARBONYLATION | ETHYLENE-GLYCOL | CONVERSION | ACIDS | ESTERS | SELECTIVE SYNTHESIS | LIGAND | AMINOLYSIS | SYNGAS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2018, Volume 25, Issue 10, pp. 2423 - 2441
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2018, Volume 360, Issue 18, pp. 3502 - 3506
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2019, Volume 10, Issue 40, pp. 9292 - 9301
An unprecedented and multiple C–H activation/ -dealkylative C–N bond activation provides a direct and facile access to indolo[1,2- ]quinoxalin-6-ones and... 
FUNCTIONALIZATION | DEALKYLATIVE CARBONYLATION | PALLADIUM | ACTIVATION | CATALYZED OXIDATIVE CARBONYLATION | COUPLING REACTIONS | ACIDS | ARYLATION | EFFICIENT SYNTHESIS | AMINOCARBONYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 31, pp. 4130 - 4137
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2016, Volume 81, Issue 3, pp. 1223 - 1228
This work reports oxidative N-dealkylation/carbonylation of tertiary amines to tertiary amides by using molecular oxygen as a sole oxidant using a Pd/C catalyst... 
REUSABLE CATALYST | DEALKYLATIVE CARBONYLATION | PALLADIUM | MONOXIDE-FREE AMINOCARBONYLATION | ORGANIC-CHEMICALS | CARBON-MONOXIDE | COUPLING REACTIONS | ALLYLIC AMINES | CHEMISTRY, ORGANIC | SUPPORTED GOLD | EFFICIENT
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 22, pp. 6260 - 6263
.... Notably, the catalyst loading could be lowered from 5 to 0.1 mol %, which represents the lowest catalyst loading among the reported work on carbonylation via C–N bond... 
MONO(AMINE) COMPLEXES | DEALKYLATIVE CARBONYLATION | SAMARIUM DIIODIDE | ACTIVATION | ANILINE DERIVATIVES | AMINALS | CARBON-NITROGEN BOND | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED AMIDES | ARYL IODIDES
Journal Article
ChemistrySelect (Weinheim), ISSN 2365-6549, 2019, Volume 4, Issue 12, pp. 3500 - 3504
A novel method of the synthesis of tertiary aromatic amides from tertiary benzylamines with high atom utilization has been developed. The reaction undergoes a... 
Amide | C−N bond cleavage | Synthesis | Catalysts | ACTIVATION | CATALYZED CARBONYLATION REACTIONS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | DEALKYLATIVE CARBONYLATION | BENZAMIDES | C-N bond cleavage | ALLYLIC AMINES | ARYL IODIDES | METHYLARENES | POT OXIDATIVE AMIDATION
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 08/2018, Volume 7, Issue 8, pp. 1571 - 1574
..., Rieche, Friedel–Crafts acylations, as well as transition‐metal catalyzed carbonylation reactions have been developed towards the synthesis of formylarenes. However... 
regioselectivity | N,N-substituted anilines | formylation | oxidant-induced | PALLADIUM | FRIEDEL-CRAFTS ACYLATIONS | CHEMISTRY, ORGANIC | ALDEHYDES | REIMER-TIEMANN REACTION | PHOTOREDOX CATALYSIS | TISHCHENKO REACTION | H BOND ACTIVATION | DEALKYLATIVE CARBONYLATION | VILSMEIER-HAACK REACTION | REDUCTIVE AMINATION
Journal Article
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