X
Search Filters
Format Format
Format Format
X
Sort by Item Count (A-Z)
Filter by Count
Journal Article (307) 307
Publication (27) 27
Book Chapter (9) 9
Book Review (2) 2
Conference Proceeding (2) 2
Data Set (1) 1
Dissertation (1) 1
more...
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, organic (178) 178
chemistry, multidisciplinary (115) 115
catalysis (91) 91
alkylation (85) 85
palladium (54) 54
index medicus (50) 50
decarboxylative allylation (49) 49
carboxylic-acids (47) 47
allylic alkylation (38) 38
esters (35) 35
allylation (33) 33
ketones (31) 31
synthesis (31) 31
photoredox catalysis (30) 30
asymmetric catalysis (29) 29
construction (29) 29
chemistry, applied (26) 26
derivatives (26) 26
organic chemistry (25) 25
stereoisomerism (25) 25
decarboxylative alkylation (22) 22
enantiomers (22) 22
cross-coupling reactions (21) 21
heteroaromatic bases (21) 21
organic-synthesis (21) 21
enantioselective synthesis (20) 20
stereoselective-synthesis (20) 20
asymmetric-synthesis (19) 19
c-h activation (19) 19
radical decarboxylative alkylation (19) 19
activation (18) 18
article (18) 18
beta-ketoacids (18) 18
arylation (17) 17
carbon (17) 17
molecular structure (17) 17
regioselective decarboxylative addition (17) 17
terminal alkynes (17) 17
alpha-amino-acids (16) 16
ligands (16) 16
natural products (16) 16
quaternary stereocenters (16) 16
room-temperature (16) 16
substrates (16) 16
aldehydes (15) 15
alkaloids (15) 15
chemistry (15) 15
conjugate addition (15) 15
decarboxylation (15) 15
decarboxylative coupling (15) 15
natural-products (15) 15
one-pot synthesis (15) 15
organocatalysis (15) 15
regioselectivity (15) 15
trivalent iodine compounds (15) 15
asymmetric allylic alkylation (14) 14
c-h functionalization (14) 14
chemical reactions (14) 14
complexes (14) 14
decarboxylative alkynylation (14) 14
decarboxylative arylation (14) 14
heterocycles (14) 14
metal-free (14) 14
palladium - chemistry (14) 14
vinylethylene carbonates (14) 14
acid (13) 13
acids (13) 13
alkylierung (13) 13
aromatic compounds (13) 13
asymmetry (13) 13
cross-coupling (13) 13
nickel catalysis (13) 13
nucleophiles (13) 13
organic compounds (13) 13
oxidation (13) 13
radicals (13) 13
alcohols (12) 12
alpha-oxocarboxylic acids (12) 12
c-h bonds (12) 12
catalyzed decarboxylative allylation (12) 12
chemical properties (12) 12
chemical synthesis (12) 12
indoles (12) 12
allylic substitution (11) 11
carbonates (11) 11
cyclization (11) 11
enantioselective construction (11) 11
functionalization (11) 11
imines (11) 11
reagents (11) 11
total synthesis (11) 11
alkynes (10) 10
amines (10) 10
arylboronic acids (10) 10
asymmetric decarboxylative cycloaddition (10) 10
beta-ketoesters (10) 10
bond formation (10) 10
c-h alkylation (10) 10
carbon quaternary stereocenters (10) 10
catalysts (10) 10
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 15869 - 15872
Herein we present a novel strategy based on palladium-catalyzed allylic alkylation by taking advantage of the nucleophilic addition of external fluoride onto... 
DECARBOXYLATIVE ALLYLATION | IRIDIUM | ENANTIOSELECTIVE FLUORINATION | CATALYZED ALLYLATION REACTION | REGIO | ALPHA-ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | DIASTEREO | ACTIVATED OLEFINS | TRIFLUOROMETHYLATION
Journal Article
Chemical science, ISSN 2041-6520, 10/2016, Volume 7, Issue 10, pp. 6407 - 6412
A photoredox-mediated Minisci C-H alkylation reaction of -heteroarenes with alkyl boronic acids is reported. A broad range of primary and secondary alkyl... 
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2014, Volume 356, Issue 14‐15, pp. 3231 - 3236
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5332 - 5335
The cooperative palladium/l-proline-catalyzed direct α-allylic alkylation of ketones with alkynes is achieved. This reaction exhibits high atom economy since a... 
TRANSITION-METAL CATALYSIS | DUAL ACTIVATION | HYDROGEN-BOND ACTIVATION | C-C COUPLINGS | ALLYLATION | ASYMMETRIC ALKYLATION | SIMPLE OLEFINS | CHEMISTRY, ORGANIC | REGIOSELECTIVE DECARBOXYLATIVE ADDITION | BETA-KETOACIDS | ALDEHYDES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 3, pp. 1040 - 1043
A catalytic enantioselective method for the synthesis of α-quaternary Mannich-type products is reported. The two-step sequence of (1) Mannich reaction followed... 
KETONES | AMINOMETHYLATION | DECARBOXYLATIVE ALLYLATION | ASYMMETRIC-SYNTHESIS | BETA-KETOESTERS | FORMAL SYNTHESIS | IMINES | (+)-ISONITRAMINE | CARBAZOLONES | CHEMISTRY, MULTIDISCIPLINARY | ISONITRAMINE | Communication
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2019, Volume 361, Issue 17, pp. 4126 - 4132
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2016, Volume 2016, Issue 18, pp. 3090 - 3096
A palladium‐catalyzed ortho‐directed alkylation of O‐methyl ketoximes that proceeds through a regioselective ring‐opening reaction of epoxides has been... 
C–H activation | Palladium | Regioselectivity | Epoxides | Alkylation | HALIDES | C-H ALKYLATION | ACTIVATION | NATURAL-PRODUCTS | ARENES | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | BIDENTATE-CHELATION ASSISTANCE | C-H activation | AROMATIC AMIDES | DECARBOXYLATIVE ORTHO-ACYLATION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2017, Volume 82, Issue 4, pp. 2059 - 2066
A photoredox catalytic method has been developed for the direct C2 alkylation of pyridine N-oxides. This reaction is compatible with a range of synthetically... 
H BOND ACTIVATION | DIRECT ARYLATION | HYPERVALENT IODINE(III) REAGENTS | TRANSITION-METAL-COMPLEXES | PHOTOREDOX/NICKEL DUAL CATALYSIS | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | ALPHA-KETO ACIDS | CARBOXYLIC-ACIDS | DECARBOXYLATIVE ALKYNYLATION | Pyridine | Research | Catalysis | Chemical properties | Alkylation
Journal Article
Organic Letters, ISSN 1523-7060, 01/2017, Volume 19, Issue 1, pp. 14 - 17
The Pd-catalyzed asymmetric allylic alkylation (Pd-AAA) of enol carbonates derived from γ-butyrolactones is reported, affording the corresponding... 
AAA | DECARBOXYLATIVE ALLYLATION | ACID | SCOPE | CONSTRUCTION | CHEMISTRY, ORGANIC | CENTERS | ENANTIOSELECTIVE TOTAL-SYNTHESIS | MOLECULES
Journal Article
ChemMedChem, ISSN 1860-7179, 10/2018, Volume 13, Issue 20, pp. 2159 - 2165
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2018, Volume 13, Issue 17, pp. 2522 - 2528
A variety of alkyl peresters and alkyl diacyl peroxides, which are readily accessible from carboxylic acids, are utilized as general primary, secondary, and... 
natural products | iron | homogeneous catalysis | radicals | synthesis design | HALIDES | DECARBOXYLATIVE HECK REACTION | DIRECT FUNCTIONALIZATION | PHOTOREDOX | BOND FORMATION | ABSOLUTE RATE CONSTANTS | CHEMISTRY, MULTIDISCIPLINARY | COUPLING REACTIONS | RADICAL-CATION | REDOX-ACTIVE ESTERS | ALIPHATIC CARBOXYLIC-ACIDS | Peroxides | Synthesis | Catalysis | Organic acids | Organic compounds
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2014, Volume 70, Issue 27-28, pp. 4208 - 4212
The palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4- -butylcyclohexanone is described. These experiments... 
Ketoesters | Palladium | Allylic | Decarboxylative | Alkylation | ALLYLATION | CHEMISTRY, ORGANIC | INNER-SPHERE | Tetrahedrons | Selectivity | Catalysis | Catalysts
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2017, Volume 82, Issue 18, pp. 9794 - 9800
The first deacylative allylic C–H alkylation has been established by employing the palladium-catalyzed allylic C–H activation and decarboxylative nucleophile... 
FUNCTIONALIZATION | RETRO-CLAISEN CONDENSATION | CATALYSIS | ACTIVATION | LIGANDS | DECARBOXYLATIVE COUPLING REACTIONS | STRATEGY | ALKYNYL CARBOXYLIC-ACIDS | ALLYLATION | CHEMISTRY, ORGANIC | BOND-CLEAVAGE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 45, pp. 14106 - 14110
Journal Article