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dialkoxyborane (73) 73
chemistry, organic (54) 54
aryl halides (47) 47
synthetic route (36) 36
cross-coupling reaction (29) 29
borylation (23) 23
route (22) 22
palladium-catalyzed borylation (19) 19
palladium (17) 17
catalysis (16) 16
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chemistry, multidisciplinary (15) 15
coupling reaction (14) 14
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arylboronic acids (11) 11
esters (10) 10
complexes (8) 8
chemistry (7) 7
cross-coupling (7) 7
derivatives (7) 7
ligands (7) 7
pinacolborane (7) 7
acids (6) 6
arylation (6) 6
boron (6) 6
boronic acids (6) 6
bromides (6) 6
index medicus (6) 6
organoboron compounds (6) 6
alkynes (5) 5
bisdiboron (5) 5
chemical properties (5) 5
chemistry, applied (5) 5
chlorides (5) 5
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room-temperature (5) 5
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alkenes (4) 4
aromatic compounds (4) 4
aryl chlorides (4) 4
arylboronic esters (4) 4
chemical reactions (4) 4
chemistry, inorganic & nuclear (4) 4
chemistry, medicinal (4) 4
coupling (4) 4
hydroboration (4) 4
letter (4) 4
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reagents (4) 4
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acyl chlorides (3) 3
analysis (3) 3
arylboronates (3) 3
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boron compounds - chemistry (3) 3
conductivity (3) 3
efficient (3) 3
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humans (3) 3
indole (3) 3
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metalation (3) 3
molecular-wire (3) 3
neopentylglycolborylation (3) 3
oligomers (3) 3
one-pot synthesis (3) 3
palladium - chemistry (3) 3
stereoisomerism (3) 3
suzuki (3) 3
acetates (2) 2
aldehydes (2) 2
alkaloids - chemical synthesis (2) 2
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Synlett, ISSN 0936-5214, 07/2014, Volume 25, Issue 11, pp. 1577 - 1584
Abstract A Sandmeyer borylation of arylamines via a SN 2 Ar pathway promoted by methanol with sodium nitrite and hydrochloric acid as diazotization agent has... 
letter | arylamines | methanol | arylboronic acids | diazotization | arylboronates | borylation | ROUTE | CROSS-COUPLING REACTION | COMPLEXES | CHEMISTRY, ORGANIC | ORGANOBORANES | PALLADIUM-CATALYZED BORYLATION | DIALKOXYBORANE | ARYL HALIDES | CHEMISTRY | C-H BORYLATION | METAL-FREE
Journal Article
Tetrahedron, ISSN 0040-4020, 2001, Volume 57, Issue 49, pp. 9813 - 9816
The cross-coupling reaction of bis(pinacolato)diboron with chloroarenes to yield pinacol arylboronates was carried out in 1,4-dioxane at 80°C in the presence... 
palladium and compounds | boron and compounds | aryl halides | coupling reactions | Coupling reactions | Palladium and compounds | Aryl halides | Boron and compounds | HALIDES | ACIDS | CHEMISTRY, ORGANIC | CONVENIENT | SOLID SUPPORT | DIALKOXYBORANE | CHEMISTRY | FACILE | ARYL CHLORIDES | BORYLATION | STRUCTURAL CHARACTERIZATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2017, Volume 359, Issue 4, pp. 616 - 622
Journal Article
Synlett, ISSN 0936-5214, 06/2012, Volume 23, Issue 9, pp. 1394 - 1396
Abstract Copper(I)-catalyzed cross-coupling reactions of aryl diazonium salts with bis(pinacolato)diboron can proceed smoothly in the water phase at room... 
letter | aryldiazonium salts | 4-carboxylphenylboronate ester | pinacol arylboronate | Sandmeyer reaction | borylation | ACIDS | CHEMISTRY, ORGANIC | SYNTHETIC ROUTE | ORGANOBORANES | PALLADIUM-CATALYZED BORYLATION | DIALKOXYBORANE | COUPLING REACTION | ARYL HALIDES | CHLORIDES
Journal Article
Synlett, ISSN 0936-5214, 8/2006, Volume 2006, Issue 12, pp. 1867 - 1870
Abstract The combination of Pd(dba) 2 and bis(2-di-TERT-butyl­phosphinophenyl)ether has proven to be efficient for the cross-­coupling of pinacolborane with... 
letter | Ligands | Boron | Palladium | Cross-coupling | Catalysis | ORGANOBORON COMPOUNDS | ligands | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | catalysis | SYNTHETIC ROUTE | BROMIDES | IODIDES | DIALKOXYBORANE | PHOSPHINES | cross-coupling | CHLORIDES | palladium | boron
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2014, Volume 356, Issue 18, pp. 3897 - 3911
Journal Article
Organic Letters, ISSN 1523-7060, 11/2008, Volume 10, Issue 21, pp. 4879 - 4882
Two-step, one-pot neopentylglycolborylation of aryl iodides and bromides catalyzed by NiCl2(dppe) and NiCl2(dppp) is reported. Electron-rich and... 
CHEMISTRY, ORGANIC | DIALKOXYBORANE | ARENESULFONATES | SYNTHETIC ROUTE | BORYLATION
Journal Article
Synthesis, ISSN 0039-7881, 04/2012, Volume 44, Issue 8, pp. 1233 - 1236
Abstract The nickel-catalyzed borylation of aryl halides with 5-(TERT-butyldimethylsiloxymethyl)-5-methyl-1,3,2-dioxaborinane, prepared in situ, was achieved.... 
paper | hydroboranes | cross-coupling | aryl halides | carbon-boron bond formation | nickel catalysis | SYSTEM | ROUTE | NEOPENTYLGLYCOLBORYLATION | COMPLEXES | ARYLATION | CHEMISTRY, ORGANIC | DIALKOXYBORANE | COUPLING REACTION | MESYLATES
Journal Article
Synlett, ISSN 0936-5214, 10/2010, Volume 2010, Issue 16, pp. 2403 - 2406
Abstract The combination of 4,4,6-trimethyl-1,3,2-dioxaborinane, a particularly stable and inexpensive borylation reagent, and Buchwald’s palladium catalyst... 
letter | arylboronic | catalysis | palladium | boron | Suzuki | SYSTEM | HYDROBORATION | ACTIVATION | CHEMISTRY, ORGANIC | SYNTHETIC ROUTE | BROMIDES | BORONIC ACIDS | PALLADIUM-CATALYZED BORYLATION | DIALKOXYBORANE | COUPLING REACTION | CHLORIDES | Organic chemistry | Chemical Sciences
Journal Article
中国化学快报:英文版, ISSN 1001-8417, 2014, Volume 25, Issue 5, pp. 715 - 719
A convenient,efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed.The protocol uses... 
芳基硼酸 | 过氧化氢 | 合成 | | 含金属 | 碳酸氢铵 | 苯酚 | 室温 | Oxidative | Metal-free | Substituted phenols | Arylboronic acids | Synthetic method | PALLADIUM-CATALYZED HYDROXYLATION | ORGANOCATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | VISIBLE-LIGHT | ETHERS | DIALKOXYBORANE | OXIDATIVE HYDROXYLATION | ARYL HALIDES | COUPLING REACTION | DERIVATIVES
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 10/2014, Volume 69, Issue 9, pp. 982 - 986
A metal-free, PPh -mediated borylation reaction of arenediazonium salts with bis(pinacolato)diborane has been developed under mild conditions. The process... 
Arylboronates | Arenediazonium Salts | Borylation | ORGANOBORON COMPOUNDS | ROOM-TEMPERATURE | CROSS-COUPLING REACTION | COMPLEXES | CHEMISTRY, ORGANIC | SYNTHETIC ROUTE | CHEMISTRY, INORGANIC & NUCLEAR | PALLADIUM-CATALYZED BORYLATION | DIALKOXYBORANE | ARYLBORONIC ESTERS | ARYL HALIDES | METAL-FREE
Journal Article
by Yan, GB and Yang, MH and Yu, J
LETTERS IN ORGANIC CHEMISTRY, ISSN 1570-1786, 01/2012, Volume 9, Issue 1, pp. 71 - 75
The CuBr-catalyzed cross-coupling reaction of aryl iodides with B(2)pin(2) in the absence of ligand has been developed for the preparation of arylboronates.... 
ROOM-TEMPERATURE | REAGENTS | CROSS-COUPLING REACTION | Aryl and benzyl halides | borylation | COMPLEXES | CHEMISTRY, ORGANIC | SYNTHETIC ROUTE | ORGANOBORANES | DIALKOXYBORANE | ARYLBORONIC ESTERS | arylboronates | DIBORATION
Journal Article
Transition Metal Chemistry, ISSN 0340-4285, 3/2009, Volume 34, Issue 2, pp. 175 - 179
Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes were found to be very efficient catalysts for the one-pot borylation/Suzuki cross-coupling... 
Chemistry | Inorganic Chemistry | Catalysis | Physical Chemistry | HALIDES | SUZUKI | DIALKOXYBORANE | ONE-POT SYNTHESIS | CRYSTAL-STRUCTURES | SYNTHETIC ROUTE | EFFICIENT | BORYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal Article
Synthesis, ISSN 0039-7881, 2/2007, Volume 2007, Issue 3, pp. 351 - 354
ABSTRACT The palladium-catalyzed borylation of aryl iodides with 4,4,6-trimethyl-1,3,2-dioxaborinane is described. The mild reaction conditions employed allow... 
paper | Boron | Palladium | Cross-coupling | Catalysis | Aryl halides | ORGANOBORON COMPOUNDS | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | catalysis | PINACOLBORANE | SYNTHETIC ROUTE | ARYLBORONIC ACIDS | BIARYLS | DIALKOXYBORANE | aryl halides | cross-coupling | palladium | boron
Journal Article
Synthesis, ISSN 0039-7881, 4/2008, Volume 2008, Issue 7, pp. 1121 - 1125
ABSTRACT The bromine-lithium exchange in bromophenothiazines followed by transmetalation with trimethyl borate and addition of palladium catalyst, 1.2... 
paper | Oligomers | Heterocycles | Metalation | Cross-coupling | Borylations | One-pot reactions | one-pot reactions | INTRAMOLECULAR ELECTRON-TRANSFER | oligomers | CHEMISTRY, ORGANIC | metalation | FREE-RADICALS | borylations | DIALKOXYBORANE | heterocycles | ACID-SOLUTIONS | CONDUCTIVITY | MOLECULAR-WIRE | ARYL HALIDES | cross-coupling | ION RADICALS | DERIVATIVES | PHENOTHIAZINE
Journal Article
Organic Letters, ISSN 1523-7060, 01/2006, Volume 8, Issue 2, pp. 261 - 263
The coupling reaction of pinacolborane with aryl iodides under the catalysis of 10 mol % CuI and the action of sodium hydride in THF works at room temperature... 
HALIDES | PALLADIUM | DIALKOXYBORANE | PHENOLS | ESTERS | CHEMISTRY | CHEMISTRY, ORGANIC | BOND FORMATION | COPPER | SYNTHETIC ROUTE | EFFICIENT
Journal Article
Green Chemistry, ISSN 1463-9262, 2007, Volume 9, Issue 2, pp. 139 - 145
A facile and environmentally benign method for the formation of boronic acid esters from corresponding boronic acids is reported. Simple grinding of a 1 : 1... 
FUNCTIONALIZATION | PALLADIUM-CATALYZED BORYLATION | SUZUKI | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | DIALKOXYBORANE | CROSS-COUPLING REACTION | AROMATIC HALIDES | BIS(PINACOLATO)DIBORON | ARYL HALIDES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE
Journal Article
by Wu, CZ and Ge, SZ
CHEMICAL SCIENCE, ISSN 2041-6520, 03/2020, Volume 11, Issue 10, pp. 2783 - 2789
We report a stereoselective regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes with pinacolborane (HBpin) in the presence of cobalt... 
Z-SELECTIVE HYDROSILYLATION | DIALKOXYBORANE | VINYLARENES | COUPLING REACTION | ARYL HALIDES | STEREOSELECTIVE HYDROSILYLATION | SYNTHETIC ROUTE | BITE ANGLE | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ALKENE HYDROSILYLATION
Journal Article
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