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Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2014, Volume 53, Issue 37, pp. 9817 - 9821
The chemoselective addition of arenes and 1,3‐diketones to α‐aryldiazoesters was achieved through ligand‐controlled gold catalysis. Unlike a dirhodium catalyst... 
gold | carbenoids | diazo compounds | carbophilicity | carbocations | Gold | Catalysts | Aromatic compounds | Insertion | Inorganic salts | Ligands | Catalysis | Nucleophiles | Carbon
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11877 - 11881
Indoles are an important structural motif that is commonly found in biologically active molecules. In this work, conditions for divergent couplings between... 
ruthenium | transition-metal catalysis | indoles | C−H activation | diazo compounds | Diazo compounds | Ruthenium | Catalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11925 - 11929
A catalyst‐free approach for the generation of sulfonyl radicals from aryldiazonium tetrafluoroborates in the presence of DABCO⋅(SO2)2 is realized. The... 
sulfur | radicals | diazo compounds | heterocycles | synthetic methods | Coumarins | Diazo compounds | Air pollution | Sulfur dioxide
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2016, Volume 55, Issue 33, pp. 9671 - 9675
Indolyl α‐diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of... 
cyclizations | indoles | diazo compounds | spirocycles | synthetic methods
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2017, Volume 56, Issue 49, pp. 15570 - 15574
A metal‐free [2+2] cycloaddition and 1,4‐addition sequence induced by S‐centered radicals has been achieved by treating benzene‐linked allene‐ynes with... 
allenes | annulation | cycloaddition | radicals | diazo compounds | Sulfur compounds | Diazo compounds | Cycloaddition | Allene | Benzene | Metals | Sulfur | YneS protein | Sulfur dioxide
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2017, Volume 56, Issue 16, pp. 4569 - 4574
We disclose an efficient one‐pot transformation of trifluorodiazoethane and higher perfluorinated homologues with various nitroolefins. This method takes... 
regioselectivity | nitroolefins | pyrazoles | diazo compounds | traceless directing groups | Diazo compounds | Usage | Homology | Transformation | Regioselectivity | Pyrazoles
Journal Article
Green chemistry : an international journal and green chemistry resource : GC, ISSN 1463-9270, 2017, Volume 19, Issue 4, pp. 905 - 909
Fluorinated diazoalkanes can be obtained in either batch or continuous-flow reactions, depending on the substitution pattern. These diazo compounds were... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2018, Volume 57, Issue 34, pp. 11015 - 11019
A direct (3+2) cycloaddition between alkenes and vinyl diazo reagents using either Cr or Ru photocatalysis is described. The intermediacy of a radical cation... 
ruthenium | chromium | cycloaddition | diazo compounds | photocatalysis | Chromium | Diazo compounds | Catalysis | Olefins | Cycloaddition | Alkenes | Photocatalysis | Reagents | Cyclopentene | Cations | Interception | diazo compound
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2015, Volume 54, Issue 10, pp. 3056 - 3060
Intramolecular aromatic substitution and Büchner reaction have been established as powerful methods for the construction of polycyclic compounds. These... 
carbenes | Büchner reaction | diazo compounds | fluorenes | aromatic substitution | Diazo compounds | Aromatic substitution | Carbenes | Fluorenes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2015, Volume 54, Issue 7, pp. 2265 - 2269
The first radical alkoxycarboxylation of aryldiazonium salts using CO gas through visible‐light‐induced photoredox catalysis (16 W blue LEDs) has been... 
esters | radicals | diazo compounds | photocatalysis | synthetic methods | Diazo compounds | Esters | Synthetic methods | Photocatalysis | Radicals | Catalysis | Light-emitting diodes | Dyes | Carboxylation | Strategy | Carbon monoxide
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2011, Volume 50, Issue 33, pp. 7486 - 7500
Tosylhydrazones are useful synthetic intermediates that have been used in organic chemistry for almost 60 years. The recent discovery of a palladium‐catalyzed... 
palladium | cross‐coupling | diazo compounds | hydrazones | olefins | cross-coupling | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
Journal Article