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European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2018, Volume 2018, Issue 20-21, pp. 2139 - 2154
Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp 2 –sp 2 ‐hybridized diborane(4) compounds... 
Boranes | Diborane | Boron–boron coupling | Hydrides | Diboration | Nucleophilicity | Chemical tests and reagents | Organic chemistry | Boron | Chemical reactions | Boron compounds | Nuclei
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2015, Volume 21, Issue 11, pp. 4267 - 4271
We have clarified and observed the high electron affinity of pinBBMes 2 ( 1 ; Mes=mesityl, pin=pinacolato). By using electrochemistry, it was shown that 1 has... 
boranes | density functional calculations | substituent effect | torsion angles | radical anions | SIGMA-BOND | CRYSTAL-STRUCTURE | COMPLEXES | REACTIVITY | PI-BOND | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | WITTIG REACTION | X-RAY | CHEMISTRY | RADICAL-ANION | Electrochemistry | Electrochemical reactions | Analysis | Spectrum analysis | Spectroscopy | Reduction | Anions | Electron affinity | Electron density | Bonding | Torsion | Radicals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 32, pp. 10368 - 10373
The desymmetrization of the cyclic (alkyl)(amino)carbene-supported diboracumulene B-2(cAAC(Me))(2) (cAAC(Me) =... 
INSERTION | FREE DIBORATION | ISOCYANIDE | B-B | UNSYMMETRICAL DIBORANE | BORON TRIPLE BOND | MULTIPLE BONDS | ALKYNES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS
Journal Article
Energy and Environmental Science, ISSN 1754-5692, 10/2012, Volume 5, Issue 11, pp. 9257 - 9268
The strong efforts devoted to the exploration of BNH compounds for hydrogen storage have led to impressive advances in the field of boron chemistry. This... 
HIGH-EXTENT DEHYDROGENATION | DIAMMONIATE | ENERGY & FUELS | CRYSTAL-STRUCTURE | SPENT FUEL | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | HYDRIDE TRANSFER | ENGINEERING, CHEMICAL | ENVIRONMENTAL SCIENCES | AMMONIA BORANE DEHYDROGENATION | AMINE-BORANES | ALKALI-METAL AMIDOBORANES | BNH compounds | hydrogen storage
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2010, Volume 132, Issue 24, pp. 8258 - 8260
In contrast to the common multiple bonding between carbon atoms, multiply bonded boron compounds have still been a synthetic challenge due to the electron... 
B=B DOUBLE-BOND | B2H4 | BORON | ANALOG | MOLECULAR-STRUCTURE | CHEMISTRY | ISOMERS | DIBORENE | PLANAR | ENERGIES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 11/2012, Volume 3, Issue 11, pp. 3183 - 3191
The structure of the amorphous aluminoborane compound AlB4H11 was identified through a collaborative study closely coupling a first-principles density... 
LIGANDS | MOLECULAR-STRUCTURE | AMMONIA TRIBORANE | DIBORANE PYROLYSIS | COMPLEXES | INTERCONVERSION | BORANES | THERMAL-DECOMPOSITION | ALUMINIUM BOROHYDRIDE | HYDROGEN STORAGE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 04/2012, Volume 14, Issue 7, pp. 1918 - 1921
Using bis(pinacolato)diboron, catalytic amounts of Cull, and various amine bases in water under atmospheric conditions at rt, acyclic and cyclic... 
BORATION | COUPLING REACTIONS | ENONES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | BOND FORMATION | DIBORON REAGENTS | ORGANOBORONIC ESTERS | DIBORANE COMPOUNDS | CONJUGATE ADDITION | AQUEOUS-SOLUTION
Journal Article
Journal of Power Sources, ISSN 0378-7753, 02/2018, Volume 377, pp. 93 - 102
Three ligand-stabilized Mg(BH ) –based complexes have been synthesized and evaluated as potential hydrogen storage media for portable fuel cell applications.... 
Borohydride hydrolysis | Diborane | New coordination compounds | Chemical hydrogen storage | Magnesium borohydride | Fuel cell
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 06/2015, Volume 21, Issue 25, pp. 9018 - 9021
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 6, pp. 2009 - 2017
Diborane(4) compounds are versatile reagents in synthetic chemistry. Generally, diboranes(4) with sp(2)-hybridized boron atoms react as electrophiles. By... 
BORON | REDUCTION | APPROXIMATION | RING-EXPANSION | MOLECULAR-STRUCTURES | COMPLEXES | CORRELATION-ENERGY | BASIS-SETS | DIBORON COMPOUNDS | BOND | CHEMISTRY, INORGANIC & NUCLEAR | Diborane | Adiabatic flow | Quantum chemistry | Ionization | Reagents | Chemical properties | Boron compounds | Chemical synthesis | Nuclei
Journal Article
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, ISSN 1434-1948, 06/2018, Issue 20-21, pp. 2139 - 2154
Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp(2)-sp(2)-hybridized diborane(4) compounds... 
HYDRIDE ABSTRACTION | ORGANIC-SYNTHESIS | BASE-STABILIZED DIBORANE | Diboration | CRYSTAL-STRUCTURE | TRIPLE BOND | Hydrides | B-B BOND | STRUCTURAL MOTIFS | DIBORON COMPOUNDS | HOMOLYTIC CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR | Diborane | BORYL ANION | Boranes | Boron-boron coupling | Nucleophilicity
Journal Article
JOURNAL OF POWER SOURCES, ISSN 0378-7753, 02/2018, Volume 377, pp. 93 - 102
Journal Article
Organometallics, ISSN 0276-7333, 06/2018, Volume 37, Issue 12, pp. 1992 - 1998
Reaction of the bis-catecholatodiboron-NHC adducts B(2)Cat(2 )(NHC) (NHC = IMe (tetramethylimidazol-2ylidene), IMes (1,3-dimesitylimidazol-2-ylidene), IDIPP... 
BORON | RING-EXPANSION | REACTIVITY | CHEMISTRY, ORGANIC | FRUSTRATED LEWIS PAIRS | N-HETEROCYCLIC CARBENES | B-B BOND | BORENIUM CATIONS | CONJUGATE ADDITIONS | SOLID-STATE | DIBORANE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 05/2011, Volume 76, Issue 10, pp. 3997 - 4007
A novel sp(2)-sp(3) diboron reagent has been developed for the copper-catalyzed beta-boration of alpha,beta-unsaturated conjugated compounds. The reaction... 
LEWIS-BASE ADDUCTS | TRANSITION-METAL-COMPLEXES | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | COPPER(I) BORYL COMPLEXES | CARBONYL-COMPOUNDS | TETRAALKOXY DIBORANE COMPOUNDS | PLATINUM-CATALYZED DIBORATION | C-H BONDS | BETA-BORATION | SMALL-MOLECULE SYNTHESIS
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY C, ISSN 1932-7447, 01/2009, Volume 113, Issue 1, pp. 2 - 11
Aluminoborane compounds AlB4H11, AlB5H12, and AlB6H13 were reported by Himpsl and Bond in 1981, but they have eluded the attention of the worldwide hydrogen... 
BOROHYDRIDES | NMR | COMPLEX | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | SHIFTS | SPECTRA | BORANES | DIBORANE | ALUMINUM-HYDRIDE
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 03/2017, Volume 46, Issue 11, pp. 3661 - 3680
In this detailed study we report on the structures of the widely employed diboron(4) compounds bis(pinacolato) diboron (B(2)pin(2)) and bis(neopentyl... 
LEWIS-BASE ADDUCTS | ROOM-TEMPERATURE | BORON CONJUGATE ADDITION | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | N-HETEROCYCLIC CARBENES | TETRAALKOXY DIBORANE COMPOUNDS | CATALYZED BETA-BORATION | METAL-FREE DIBORATION | BIS-DITHIOCATECHOLATE | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 12/2017, Volume 129, Issue 50, pp. 16126 - 16131
A series of crystalline sp 3 ‐sp 3 diboron(4) compounds were synthesized and shown to promote the facile reduction of water with dihydrogen formation. The... 
Strukturaufklärung | Diborane | Reduktionen | Wasser | Wasserstoff | Chemical tests and reagents | Aldehydes
Journal Article