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Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2014, Volume 53, Issue 12, pp. 3241 - 3244
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10091 - 10095
B(sp )-B(sp ) diborane species based on bis(catecholato)diboron and N-heterocyclic carbenes (NHCs) underwent catechol/bromide exchange selectively at the sp... 
diboranes | boron chains | diborenes | π-conjugation | N-heterocyclic carbenes
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 48, pp. 17169 - 17172
Room temperature hydrogenation of an SIDep‐stabilized diboryne (SIDep=1,3‐bis(diethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene) and a cAAC‐supported diboracumulene... 
carbenes | main-group chemistry | reaction mechanism | hydrogenation | diborenes | Hydrogenation | Synthesis (chemistry) | Boron | Catalysts | Bridging | Mathematical analysis | Chemical bonds | Hydrides
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2017, Volume 56, Issue 45, pp. 14287 - 14292
Under a CO atmosphere, the dihydrodiborene [(cAAC)HB=BH(cAAC)] underwent coordination of CO concomitant with reversible hydrogen migration from boron to the... 
insertion | cyclic (alkyl)(amino)carbenes | ring expansion | diborenes | CO activation | Hydrogen | Insertion | Cleavage | Boron | Carbon monoxide | Migration | Alkynes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent π‐diborene complexes of Cu and Ag. These observations included... 
intersystem crossing | coinage metals | fluorescence | boron | diborenes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2020, Volume 59, Issue 1, pp. 325 - 329
The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans‐dihydrotriboranes by formal hydrogenation and... 
Cations | Hydroboration | Triboranes | Diborenes | Photoisomerization | Aromatic compounds | Boranes | Index Medicus | Communications | Communication
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5947 - 5951
The room‐temperature, ambient‐pressure reactions of CO2 with two species containing boron–boron multiple bonds led to the incorporation of either one or two... 
carbon dioxide | diborynes | CO2 fixation | boron | diborenes | fixation | Carbon dioxide | Boron | Cycloaddition | Reaction mechanisms | Molecular chains | Structural analysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2017, Volume 56, Issue 33, pp. 9829 - 9832
A zwitterionic boraalkenyl boronium 3 was synthesized by reduction of cyclic (alkyl)(amino)carbene (cAAC) and trimethylphosphine (PMe3)‐coordinated... 
allenes | multiple bonds | boron | isoelectronic analogs | diborenes | Surface active agents | Reduction | Diffraction | Computer applications | X-ray diffraction | Chemical bonds | Cleavage | Crystal structure
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4469 - 4473
The reaction of the bisboracumulene (CAAC)2B2 (CAAC=1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) with excess tert‐butylisocyanide... 
main‐group elements | multiple bonds | thermolysis | boron | diborenes | main-group elements | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Telomerase | Ligands | Complexation | Boron | Electrochemical analysis | Heating | Electronics | Voltammetry | Formations | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2017, Volume 56, Issue 3, pp. 889 - 892
Unsaturated bridges that link the two cyclopentadienyl ligands together in strained ansa metallocenes are rare and limited to carbon–carbon double bonds. The... 
density functional calculations | strained molecules | boron | diborenes | metallocenes | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Density functionals | Chemical properties | Metallocenes | Specific gravity | Fatty acids | Olefins | Boron
Journal Article
Coordination chemistry reviews, ISSN 0010-8545, 11/2019, Volume 399, p. 213021
Diborane(6), diborane(4) and diborene(2) complexes of various transition metals. [Display omitted] •Diboranes are valuable compounds for numerous synthetic... 
Boron | Diborane | Metallaborane | Transition metal complexes | Diborene | Physical Sciences | Chemistry, Inorganic & Nuclear | Chemistry | Science & Technology
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2017, Volume 56, Issue 27, pp. 8009 - 8013
The diborene 1 was synthesized by reduction of a mixture of 1,2‐di‐9‐anthryl‐1,2‐dibromodiborane(4) (6) and trimethylphosphine with potassium graphite. The... 
C−H functionalization | boron | HOMO–LUMO gap | diborenes | borylation | Selenium | Anthracene | Phosphine | Molecular orbitals | Intercalation | Engineering | Absorption | Graphite | Oxidation | Absorption spectra | Conjugation | Potassium | Bonding | Conformation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2015, Volume 54, Issue 1, pp. 359 - 362
Despite the fundamental importance of radical‐anion radical‐cation pairs in single‐electron transfer (SET) reactions, such species are still very rare and... 
electron transfer | diborene | borole | radical‐anion radical‐cation pair | redox chemistry | Electron transfer | Borole | Radical-anion radical-cation pair | Redox chemistry | Diborene | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Ions | Boron | Reduction | Anions | Synthesis | Electrode potentials | Radicals
Journal Article