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Angewandte Chemie - International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 12, pp. 3241 - 3244
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10091 - 10095
B(sp )-B(sp ) diborane species based on bis(catecholato)diboron and N-heterocyclic carbenes (NHCs) underwent catechol/bromide exchange selectively at the sp... 
diboranes | boron chains | diborenes | π-conjugation | N-heterocyclic carbenes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 48, pp. 17169 - 17172
Room temperature hydrogenation of an SIDep‐stabilized diboryne (SIDep=1,3‐bis(diethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene) and a cAAC‐supported diboracumulene... 
carbenes | main-group chemistry | reaction mechanism | hydrogenation | diborenes | ACTIVATION | HYDROBORATION | SINGLE | ANALOGS | COMPOUND | REACTIVITY | H-2 | CHEMISTRY, MULTIDISCIPLINARY | NEUTRAL DIBORENE | BORON TRIPLE BOND | Hydrogenation | Synthesis (chemistry) | Boron | Catalysts | Bridging | Mathematical analysis | Chemical bonds | Hydrides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2019, Volume 58, Issue 37, pp. 12893 - 12897
Singly NHC‐coordinated (aminoboryl)aminoborenium salts react with Na 2 [Fe(CO) 4 ] to yield stable coordination complexes of aminoborylene‐stabilized... 
low-valent compounds | borylenes | iron complexes | diboron complexes | diborenes | INSERTION | HYDROBORATION | COMPLEXES | REACTIVITY | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | CHALCOGENS | NEUTRAL DIBORENE | REDUCTION | GENERATION | Boron | Salts | Metals | Extrusion | Iron | Coordination compounds | Nucleophiles | Amino groups
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 12/2015, Volume 54, Issue 50, pp. 15084 - 15088
Huckel pi aromaticity is typically a domain of carbon-rich compounds. Only very few analogues with noncarbon frameworks are currently known, all involving the... 
density functional therory | ELECTRONS | DIBORENES | multiple bonding | ORGANOMETALLICS | BOND | boron | CHEMISTRY, MULTIDISCIPLINARY | aromaticity
Journal Article
by Lu, W and Xu, K and Li, YX and Hirao, H and Kinjo, R
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2018, Volume 57, Issue 48, pp. 15691 - 15695
Metal-free activation of homoatomic E-E sigma bonds (E = P, B) in white phosphorus (P-4) and bis(catecholato)diboron (B(2)cat(2)) with a 1,2-diboraallene 1 is... 
OXIDATION | catenation | INSERTION | BORON | REACTIVITY | STRUCTURAL-CHARACTERIZATION | diboration | diborene | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE | white phosphorus | NEUTRAL DIBORENE | sigma-bond activation | B-B | P-4 TETRAHEDRON | MULTIPLE BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent π‐diborene complexes of Cu and Ag. These observations included... 
intersystem crossing | coinage metals | fluorescence | boron | diborenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5947 - 5951
The room‐temperature, ambient‐pressure reactions of CO2 with two species containing boron–boron multiple bonds led to the incorporation of either one or two... 
carbon dioxide | diborynes | CO2 fixation | boron | diborenes | fixation | SINGLE | DIOXIDE | REACTIVITY | TRIPLE BOND | FRUSTRATED LEWIS PAIRS | DIBORENE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-MONOXIDE | CHEMISTRY | NITROGEN | OXIDES | Carbon dioxide | Boron | Cycloaddition | Reaction mechanisms | Molecular chains | Structural analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 27, pp. 8009 - 8013
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10091 - 10095
B(sp(2))-B(sp(3)) diborane species based on bis(catecholato)diboron and N-heterocyclic carbenes (NHCs) underwent catechol/bromide exchange selectively at the... 
SYSTEM | BORON | SINGLE | boron chains | REACTIVITY | diboranes | DIBORON COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | diborenes | CATIONS | pi-conjugation | CARBENES | MULTIPLE BONDS | DERIVATIVES | N-heterocyclic carbenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 35, pp. 9280 - 9283
An isolable phenylborylene species supported by two oxazol‐2‐ylidene ligands was synthesized and structurally characterized. Computational studies revealed the... 
borylenes | carbenes | reactive species | boron | nucleophiles | FORM | DIBORENES | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BULKY | TRANSITION-METAL BORYL | CHEMISTRY | ALKYL AMINO CARBENES | GENERATION | Chemical tests and reagents | Chromium | Boron | Conjugates | Computation | Ligands | Nucleophiles | Adducts | Fragmentation
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2019, Volume 58, Issue 29, pp. 9776 - 9781
Heterodiatomic multiple bonds have never been observed within Group 13. Herein, we disclose a method that generates [(CAAC) PhB= AlCp3t] (1), a complex... 
SINGLE | subvalent compounds | ANALOG | DIBORENES | COMPOUND | REACTIVITY | TRIPLE BOND | STRENGTH | aluminum | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | REDUCTION | multiple bonds | TRANS-BENT | boron | carbon dioxide reduction
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent pi-diborene complexes of Cu and Ag. These observations included... 
PALLADIUM COMPLEXES | coinage metals | COORDINATION | SILVER(I) | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | diborenes | DEPENDENCE | intersystem crossing | fluorescence | AZOBENZENE | PHOTOPHYSICS | DINITROGEN | boron | DOUBLE-BOND | Silver | Boron | Olefins | Luminescence | Fluorescence | Spin-orbit interactions | Coordination compounds | Copper | Carbon
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 2013, Volume 52, Issue 13, pp. 3574 - 3583
The construction of boronboron bonds, despite the intense synthetic interest in diboranes and the high BB bond enthalpy, is still difficult, uncontrollable,... 
HETEROCYCLIC CARBENE | MOLECULAR-STRUCTURE | multiple bonding | transition metals | DIBORENE | CHEMISTRY, MULTIDISCIPLINARY | boronboron bonds | AMINE-BORANE | REDUCTION | boron-centered ligands | BORYLENE TRANSFER | THERMAL CONDITIONS | CHEMISTRY | boron | RADICAL-ANION
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 87, pp. 11945 - 11947
Upon complexation to CuOTf, a PMe3-stabilized bis(9-anthryl) diborene slowly undergoes an intramolecular hydroarylation reaction at room temperature.... 
HYDROBORATION | BORON | SINGLE | NEUTRAL DIBORENE | ANALOGS | COMPLEXES | BONDS | CONSTRUCTION | GAP | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2017, Volume 53, Issue 87, pp. 11945 - 11947
Upon complexation to CuOTf, a PMe -stabilized bis(9-anthryl) diborene slowly undergoes an intramolecular hydroarylation reaction at room temperature.... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 12, pp. 3241 - 3244
Synthetic access to electron‐precise boron chains is hampered by the preferential formation of nonclassical structures. The few existing strategies for this... 
oxygen heterocycles | polyboranes | hydroboration | diborenes | sulfur heterocycles | METAL-PROMOTED REACTIONS | COMPLEX | COMPOUND | COORDINATION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | TRANSITION-METAL | BORON HYDRIDES | CHEMISTRY | Boron | Hydroboration | Synthesis | Coupling agents | Catalysts | Strategy | Reducing agents | Catalysis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2019, Volume 141, Issue 37, pp. 14898 - 14903
A compound with a boron-boron triple bond is shown to undergo stepwise hydroboration reactions with catecholborane to yield an unsymmetrical... 
DEPROTONATION | BORON | NEUTRAL DIBORENE | REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | COMPOUND
Journal Article