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Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 4/2016, Volume 45, Issue 16, pp. 7178 - 7178
Correction for 'EPR detection and characterisation of a paramagnetic Mo( iii ) dihydride intermediate involved in electrocatalytic hydrogen evolution' by... 
Dihydrides | Hydrogen evolution
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 50, pp. 9777 - 9780
A will of iron: An active well‐defined iron complex (see structure; gray C, white H, yellow B, green F, brown Fe, pink P) catalyzes the title reaction (see... 
carbon dioxide | formate | iron | homogeneous catalysis | hydrogenation | FORMIC-ACID | DIHYDRIDE | CONVERSION | COMPLEXES | CO2 | HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | HOMOGENEOUS HYDROGENATION | DIHYDROGEN | LIGAND | EFFICIENT
Journal Article
Science, ISSN 0036-8075, 9/2011, Volume 333, Issue 6050, pp. 1733 - 1736
Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner... 
Burettes | Solvents | Catalysts | Hydrogen | Dehydrogenation | Gas evolution | REPORTS | Ligands | Iron | Kinetics | Catalysis | STORAGE | DIHYDRIDE | DIHYDROGEN | MULTIDISCIPLINARY SCIENCES | COMPLEXES | DECOMPOSITION | HYDROGEN-PRODUCTION | GENERATION | PRINCIPLES | WATER | Properties | Formic acid | Methods | Chemical reactions | Chemical synthesis | Hydrogenation | Iron catalysts
Journal Article
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 32, pp. 10809 - 10826
This perspective reviews our efforts to use a mechanism-based approach to develop catalysts for the asymmetric hydrogenation of prochiral ketones and imines. A... 
ASYMMETRIC TRANSFER HYDROGENATION | N-HETEROCYCLIC CARBENE | SELECTIVE HYDROGENATION | KETONE HYDROGENATION | EFFICIENT HYDROGENATION | DIHYDRIDE COMPLEXES | PINCER COMPLEXES | TRANSITION-METAL HYDRIDE | PROTON-TRANSFER | DIHYDROGEN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 01/2009, Volume 42, Issue 1, pp. 183 - 191
Noble-gas chemistry has been undergoing a renaissance in recent years, due in large part to noble-gas hydrides, HNgY, where Ng = noble-gas atom and Y =... 
XENON DIHYDRIDE | HELIUM COMPOUND | AB-INITIO | NEUTRAL RARE-GAS | SOLID MATRICES | VIBRATIONAL SPECTROSCOPY | CHARGE-TRANSFER MOLECULES | DECOMPOSITION PATHWAYS | TRAPPING SITE STRUCTURES | MATRIX-ISOLATION | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Photolysis | Gases, Rare | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2008, Volume 47, Issue 21, pp. 3966 - 3968
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 34, pp. 14158 - 14164
Two isostructural, nonclassical Co(H2) complexes are prepared from their Co(N2) precursors using tris(phosphino)silyl and tris(phosphino)borane ancillary... 
DIHYDRIDE | CONSTANTS | 16-ELECTRON | DINITROGEN | CARBONYL | METAL | IRON | H-2 | HYDROGEN STORAGE | CHEMISTRY, MULTIDISCIPLINARY | SOLUBILITY | Measurement | Borane | Analysis | Crystals | Chemical properties | Structure | Hydrogen bonding | Surface energy
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 32, pp. 11272 - 11275
Though numerous catalysts for the dehydro­gen­ation of ammonia borane (AB) are known, those that release >2 equiv of H2 are uncommon. Herein, we report the... 
CHEMICAL HYDROGEN STORAGE | DIHYDRIDE | DINITROGEN | COORDINATION | METAL | LIGAND | DISPLACEMENT | TERPHENYL-DIPHOSPHINE COMPLEXES | CHROMIUM | DIHYDROGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Dehydrogenation | Molybdenum | Analysis | Ammonia | Valence | Synthesis | Boranes | Ligands | Releasing | Communication
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2015, Volume 5, Issue 1, pp. 187 - 191
Complex OsH2(CO)­(PiPr3)2, generated from OsH2(CO)­(η2-CH2CHEt)­(PiPr3)2 by dissociation of the olefin, promotes the release of 1 equiv of H2 from... 
DFT | ammonia-borane dehydrogenation | dihydrogen | dihydride | osmium | kinetic | mechanism | ROUTE | BORON-NITROGEN BONDS | PHOSPHINE | DEHYDROCOUPLING/DEHYDROGENATION | CHEMISTRY, PHYSICAL | ADDUCTS | HYDROGEN STORAGE | AMINE-BORANES | AMINOBORANES | CATALYZED DEHYDROGENATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2011, Volume 50, Issue 32, pp. 7278 - 7282
Alcohol and CO: A new process for hydrogenating CO2 to formic acid has been developed. Calorimetric studies were carried out to clarify the role of the alcohol... 
formic acid | reaction mechanisms | thermodynamics | carbon dioxide | ruthenium | RUTHENIUM(II)-CATALYZED HYDROGENATION | DIHYDRIDE | CARBON-DIOXIDE HYDROGENATION | RUTHENIUM TRIMETHYLPHOSPHINE COMPLEXES | H-2 | CHEMISTRY, MULTIDISCIPLINARY | HOMOGENEOUS HYDROGENATION | PRESSURE | CATALYZED HYDROGENATION
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2013, Volume 52, Issue 24, pp. 14391 - 14403
Two cobalt(tetraphosphine) complexes [Co(P nC‑PPh2 2NPh 2)(CH3CN)](BF4)2 with a tetradentate phosphine ligand (P nC‑PPh2 2NPh 2 =... 
HYDRIDE DONOR | COBALOXIME CATALYSTS | CYCLIC DIPHOSPHINE LIGANDS | H-2 PRODUCTION | H BOND | ELECTRODE-POTENTIALS | DITHIOLENE COMPLEXES | TRANS-DIHYDRIDE COMPLEX | FUNCTIONAL MODELS | DIHYDROGEN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Thermal properties | Amines | Chemical properties | Hydrogen
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 8, pp. 1873 - 1876
H2 & Co.: A new pincer complex of CoII has been synthesized. Reduction of this complex in the absence of additional ligands results in the formation of a... 
hydrides | density functional calculations | cobalt | pincer ligands | tridentate ligands | IRIDIUM | DIHYDRIDE COMPLEXES | SUSCEPTIBILITY | POLYHYDRIDES | AMMONIA-BORANE | CHEMISTRY, MULTIDISCIPLINARY | ALKYL COMPLEXES | PINCER COMPLEXES | METAL | TRANSFER DEHYDROGENATION | CATALYSTS
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 05/2016, Volume 11, Issue 9, pp. 1357 - 1360
An unsymmetrically protonated PN3‐pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective... 
formic acid | ruthenium | pincer ligands | hydrogen | homogeneous catalysis | ROOM-TEMPERATURE | DIHYDRIDE | STORAGE MATERIAL | CHEMISTRY, MULTIDISCIPLINARY | MILD | DEHYDROGENATION | PD-AU/C | REVERSIBLE HYDROGENATION | PINCER COMPLEXES | CATALYZED DECOMPOSITION | CARBON-DIOXIDE | Ruthenium | Catalysis | Nitrogen | Hydrogen | Formic acid | Organic acids
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2013, Volume 42, Issue 36, pp. 12832 - 12835
Addition of H-2 to [Rh((Bu2PCH2CH2PBu2)-Bu-i-Bu-i)(NBD)][BAr4Cl] (NBD = norbornadiene, Ar-Cl = 3,5-Cl2C6H3) in the solid-state results in the rapid formation... 
DIHYDRIDE | COMPLEX | REACTIVITY | PLATINUM | OXIDATIVE ADDITION | BOND-CLEAVAGE | BARF | ARYL CHLORIDES | RHODIUM(I) | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2011, Volume 40, Issue 20, pp. 5458 - 5463
A stable silicon(II) monohydride is accomplished through a covalent shared interaction of the silylene lone-pair and a sp(3)-hybridized boron atom of the Lewis... 
REAGENT | SILYLENE | HYDRIDE COMPLEX | WAVE-FUNCTIONS | LIGANDS | X-RAY | REACTIVITY | DIFFRACTION | BOND | THEORETICAL CHARGE-DENSITY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 12/2014, Volume 33, Issue 24, pp. 7279 - 7283
X-ray analysis of [(Ph3P)4Ru­(H)2] (1) prepared by a literature procedure [ Young R. ; Wilkinson G. Inorg. Synth. 1990, 28, 337 ] shows that 1 is... 
HYDROGEN | DIHYDRIDE | KETONES | TRIPHENYLPHOSPHINE COMPLEXES | NITROGEN | CHEMISTRY, ORGANIC | RUTHENIUM | ETHANOL | PHOSPHINE COMPLEXES | C-H | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article