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2008, ISBN 9780470180969, xiii, 241
This definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions... 
Dihydrogen bonding | Science | Chemistry | Physical & Theoretical
Book
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2015, Volume 796, pp. 73 - 76
We report the synthesis and characterization of a μ-hydroxo NiRu complex as a model for the active site of (Ni–SIr) of [NiFe]hydrogenase. This is the first... 
Hydrogenase | Model | Dihydrogen
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2014, Volume 50, Issue 18, pp. 2321 - 2323
The first amido-distannyne, (LSnSnL dagger)-Sn-dagger (L-dagger = -N(Ar-dagger)(SiPr3i), Ar-dagger = C6H2{C(H)Ph-2}(2)Pr-i-2,6,4), has been prepared and shown... 
DIGERMYNE | DIHYDROGEN | ANALOGS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organometallics, ISSN 0276-7333, 05/2013, Volume 32, Issue 10, pp. 3053 - 3062
Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride... 
Metallaboratrane | non-noble metal hydrogenation catalysis | heterolytic dihydrogen activation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2007, Volume 46, Issue 15, pp. 2578 - 2592
Complexes in which a σ‐HE bond (E=H, B, Si, C) acts as a two‐electron donor to the metal center are called σ complexes. Clues that it is possible to... 
boranes | dihydrogen complexes | silanes | hydride ligands | homogeneous catalysis | Silanes | Boranes | Dihydrogen complexes | Homogeneous catalysis | Hydride ligands
Journal Article
Comptes Rendus Chimie, ISSN 1631-0748, 2011, Volume 14, Issue 11, pp. 1029 - 1053
Monodentate and bidentate phosphine supported transition metal-dihydrogen complexes were studied extensively in last three decades by using spectroscopic (IR,... 
Elongated dihydrogen | Dihydrogen activation | Dihydrogen complexes | Dihydrogen release | Phosphines | H-atom dynamics
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 05/2015, Volume 48, Issue 5, pp. 1494 - 1502
This is an Account of our development of iron-based catalysts for the asymmetric transfer hydrogenation (ATH) and asymmetric pressure hydrogenation (AH) of... 
TETRADENTATE LIGAND | KETONES | N-N-P | EFFICIENT CATALYST | DEHYDROGENATION | MECHANISM | ENANTIOSELECTIVE HYDROGENATION | TRANSITION-METAL | DIHYDROGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE
Journal Article
International Journal of Quantum Chemistry, ISSN 0020-7608, 11/2017, Volume 117, Issue 21, p. n/a
In line with previous work in which we established the factors that enhance attractive CH···HC dihydrogen interactions in alkanes, an extended theoretical... 
dihydrogen interactions | supramolecular chemistry | ab initio calculations
Journal Article
ChemPhysChem, ISSN 1439-4235, 2019, Volume 20, Issue 5, pp. 672 - 679
Proton spectroscopy in solid-state NMR on catalytic materials offers new opportunities in structural characterization, in particular of reaction products of... 
110 kHz MAS | proton detection | frustrated Lewis pair | NMR spectroscopy | dihydrogen splitting | SOLID-STATE NMR | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | H-1 | SPEED | DIHYDROGEN | SPECTROSCOPY | 100 KHZ MAS | PROTEINS | INTERMOLECULAR INTERACTIONS
Journal Article
International Journal of Hydrogen Energy, ISSN 0360-3199, 03/2012, Volume 37, Issue 5, pp. 4267 - 4273
The structure of (NH ) B H (1) was determined through powder XRD analysis. The thermal decomposition of 1 and (NH ) B H (2) was examined between 20 and 1000°C... 
Dihydrogen bond | STMBMS | NH
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 02/2015, Volume 48, Issue 2, pp. 306 - 316
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a strategy that enables main-group compounds to activate small molecules.... 
HETEROLYTIC DIHYDROGEN ACTIVATION | N-HETEROCYCLIC CARBENE | REDUCTION | CO2 SEQUESTRATION | SMALL-MOLECULE ACTIVATION | COMPLEXES | REACTIVITY | CHEMISTRY | METAL-FREE HYDROGENATION | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | Hydrogenation | Analysis | Catalysis
Journal Article
Physical Review B - Condensed Matter and Materials Physics, ISSN 1098-0121, 09/2009, Volume 80, Issue 11
Using first-principles calculations, we perform a search for high-capacity hydrogen storage media based on individually dispersed calcium atoms on doped or... 
PHYSICS, CONDENSED MATTER | MEDIA | COORDINATION | ENERGY | DIHYDROGEN | ADSORPTION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2019, Volume 141, Issue 5, pp. 1871 - 1876
While diamagnetic transition metal complexes that bind and split H-2 have been extensively studied, paramagnetic complexes that exhibit this behavior remain... 
NMR | DIHYDROGEN | MOLECULAR-HYDROGEN | REVERSIBLE HETEROLYTIC CLEAVAGE | OXIDATIVE ADDITION | H-H DISTANCES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | ETA-2-DIHYDROGEN | hydride, dihydrogen, EPR
Journal Article
Chemical Society reviews, ISSN 0306-0012, 10/2017, Volume 46, Issue 19, pp. 5689 - 5700
The past decade has seen the subject of transition metal-free catalytic hydrogenation develop incredibly rapidly, transforming from a largely hypothetical... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 10/2017, Volume 46, Issue 19, pp. 5689 - 57
The past decade has seen the subject of transition metal-free catalytic hydrogenation develop incredibly rapidly, transforming from a largely hypothetical... 
KETONES | N-HETEROCYCLIC CARBENE | ACTIVATION | DIHYDROGEN | MECHANISM | IMINES | REACTIVITY | BORANES | CHEMISTRY, MULTIDISCIPLINARY | ACIDITY | BASE
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 03/2017, Volume 334, Issue C, pp. 100 - 111
Many challenging chemical reactions require precious metal catalysts to proceed. Bio-inspired catalysts featuring multiple earth-abundant metals are an... 
Lewis acid | Dinitrogen | Metal-metal bonding | Dihydrogen | Bimetallic
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2017, Volume 23, Issue 5, pp. 979 - 979
Thiolate‐bridged diruthenium complexes bearing pendent ethers have been found to work as effective catalysts toward the oxidation of molecular dihydrogen into... 
dihydrogen | electron | oxidation | ruthenium | ether | proton | Protons
Journal Article
Applied Microbiology and Biotechnology, ISSN 0175-7598, 03/2019, Volume 103, Issue 5, pp. 2113 - 2120
With global CO emissions at their highest in several years, mitigation and possibly reduction of greenhouse gas buildup and concomitant production of renewable... 
Knallgas bacteria | Ralstonia eutropha | Biofuel | Dihydrogen | Carbon dioxide
Journal Article
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