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Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 4, pp. 1367 - 1380
After their treatment with LiAlH4 and then alcohol, new iron dicarbonyl complexes mer-trans-[Fe­(Br)­(CO)2(P–CHN–P′)]­[BF4] (where P–CHN–P′ =... 
DENSITY FUNCTIONALS | DIHYDROGEN | MECHANISM | ACETOPHENONE | ENANTIOSELECTIVE HYDROGENATION | TRICARBONYL | COOPERATIVE TRANSITION-METAL | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | HETEROLYTIC CLEAVAGE | HYDRIDE | Density functionals | Usage | Iron compounds | Research | Nuclear magnetic resonance | Ketones
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10173 - 10177
{Rh(xantphos)}‐based phosphido dimers form by PC activation of xantphos (4,5‐bis(diphenylphosphino)‐9,9‐dimethylxanthene) in the presence of amine–boranes.... 
P ligands | X‐ray diffraction | homogeneous catalysis | amine–boranes | rhodium | X-ray diffraction | amine-boranes | MECHANISM | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURES | ADDUCTS | AMMONIA-BORANE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | DEHYDROGENATION | DIHYDROGEN | LIGANDS | METAL-COMPLEXES | Bimetals | Rhodium | Catalysts | Forming | Activation | Dimers | Formations | Catalysis | Communications
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2017, Volume 23, Issue 24, pp. 5682 - 5686
The first bis(σ‐zincane) complexes, heterotri‐ metallic species [M(CO)4(η2‐HZnBDI)2], have been prepared (BDI=κ2‐{2,6‐(iPr)2C6H3NCMe}2CH). For M=Cr, a single... 
σ-complexes | mechanism | zinc hydride | isomerisation | reaction pathways | sigma-complexes | X-RAY-STRUCTURE | DIHYDROGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | CARBONYL-COMPLEXES | SPECTROSCOPIC EVIDENCE | RUTHENIUM COMPLEXES | H BONDS | SECONDARY INTERACTIONS | TRANSITION-METAL CENTERS | HYDROGEN BOND | Activation entropy | Pathways | Stereoisomerism | Mathematical analysis | Isomerization | Ligands | Entropy | Isomers
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2011, Volume 133, Issue 23, pp. 8826 - 8829
The cationic zirconocene–phosphinoaryloxide complexes [Cp2ZrOC6H4P(t-Bu)2][B(C6F5)4] (3) and [Cp*2ZrOC6H4P(t-Bu)2][B(C6F5)4] (4) were synthesized by the... 
HYDROGENATION | DIHYDROGEN | ZIRCONIUM | CO2 | METAL | ADDUCTS | CHEMISTRY, MULTIDISCIPLINARY | Borane | Amines | Chemical properties | Catalysis | Dehydrogenation | Analysis
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 09/2014, Volume 20, Issue 40, pp. 12704 - 12718
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2003, Volume 125, Issue 44, pp. 13490 - 13503
Asymmetric hydrogenation of acetophenone with trans-RuH(η1-BH4)[(S)-tolbinap][(S,S)-dpen] (TolBINAP = 2,2‘-bis(di-4-tolylphosphino)-1,1‘-binaphthyl; DPEN =... 
LIGAND BIFUNCTIONAL CATALYSIS | OPPORTUNITIES NOBEL LECTURE | SELECTIVE HYDROGENATION | TRANSITION-METAL-COMPLEXES | SPECTROSCOPIC PROPERTIES | RUTHENIUM COMPLEXES | X-RAY STRUCTURE | CARBONYL-COMPOUNDS | STEREOSELECTIVE HYDROGENATION | DIHYDROGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | Ruthenium | Chemical properties | Research | Ketones | Structure | Hydrogenation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 24, pp. 8130 - 8133
The synthesis, characterization, and catalytic activity of nonclassical iron­(II) polyhydride complexes containing tridentate PNP pincer-type ligands is... 
ALCOHOLS | ORGANIC-SYNTHESIS | KETONES | DEHYDROGENATION | MILD CONDITIONS | NOBLE-METAL ACTIVITY | EFFICIENT HYDROGENATION | CATALYST | DIHYDROGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEXES
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2016, Volume 116, Issue 15, pp. 8848 - 8872
This review is a comprehensive survey of the last 10 years of research on ammonia–borane and amine–borane dehydrogenation mediated by complex metal hydrides... 
H BOND ACTIVATION | DIHYDROGEN PINCER COMPLEX | CATALYTIC DEHYDROGENATION | TRANSITION-METAL | AMIDOBORANE COMPLEXES | DIMETHYLAMINE-BORANE | DEHYDROCOUPLING REACTIONS | HYDROGEN STORAGE TANK | AMINOBORANE COMPLEXES | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2013, Volume 135, Issue 33, pp. 12448 - 12459
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2007, Volume 46, Issue 15, pp. 2578 - 2592
Complexes in which a σ‐HE bond (E=H, B, Si, C) acts as a two‐electron donor to the metal center are called σ complexes. Clues that it is possible to... 
boranes | dihydrogen complexes | silanes | hydride ligands | homogeneous catalysis | Silanes | Boranes | Dihydrogen complexes | Homogeneous catalysis | Hydride ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 42, pp. 13083 - 13087
The acid–base switching of complexes formed from anti‐electrostatic anion–anion homodimers of organophosphates and cyanostar macrocycles was investigated for... 
hydrogen bonding | molecular recognition | phosphate binding | macrocycles | anions | RECOGNITION | STABILIZATION | DIHYDROGEN PHOSPHATE | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | BINDING AFFINITY | SIZED MOLECULAR BOX | FORMS | OXOANIONS | MACROCYCLE | WATER | Phosphates | Hydrogen | Hydroxides | Triflic acid | Fidelity | Anions | Acids | Picric acid | Dimers | Switching | Organophosphates
Journal Article
Organometallics, ISSN 0276-7333, 04/2016, Volume 35, Issue 8, pp. 1160 - 1169
A series of (allyl)­palladium­(II) complexes of anionic N-heterocyclic carbenes that contain a weakly coordinating borate moiety (WCA-NHC) were prepared by... 
BACKBONE SYNTHESIS | C-N | DIHYDROGEN ACTIVATION | PHOSPHINE LIGAND | (NHC)PD(ALLYL)CL NHC | CHEMISTRY, ORGANIC | BOND | SUZUKI-MIYAURA | METAL-COMPLEXES | EXCHANGE-REACTIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article