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Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2018, Volume 47, Issue 4, pp. 1117 - 1121
Iron-chloride, -dinitrogen, and -methyl complexes bearing anionic carbazole-based PNP-type pincer ligands are designed, prepared and characterized by X-ray... 
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2011, Volume 3, Issue 2, pp. 120 - 125
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 2017, Volume 56, Issue 40, pp. 12268 - 12272
The reaction of trans-[M(N ) (dppe) ] (M=Mo, 1 , M=W, 1 ) with B(C F ) (2) provides the adducts [(dppe) M=N=N-B(C F ) ] (3) which can be regarded as M/B... 
boranes | silanes | dinitrogen | Group 6 metals | frustrated Lewis pairs
Journal Article
Nature chemistry, ISSN 1755-4330, 07/2014, Volume 6, Issue 7, pp. 590 - 595
Enzymatic haem and non-haem high-valent iron-oxo species are known to activate strong C-H bonds, yet duplicating this reactivity in a synthetic system remains... 
Ethane - chemistry | Models, Molecular | Oxidation-Reduction | Ethanol - chemistry | Iron - chemistry
Journal Article
by Ling, CY and Niu, XH and Li, Q and Du, AJ and Wang, JL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2018, Volume 140, Issue 43, pp. 14161 - 14168
Solar nitrogen (N-2) fixation is the most attractive way for the sustainable production of ammonia (NH3), but the development of a highly active, long-term... 
AMBIENT CONDITIONS | GRAPHITIC CARBON NITRIDE | AMMONIA-SYNTHESIS | FREE ELECTROCATALYSTS | DOPED CARBON | NITROGEN REDUCTION | GRAPHENE | DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY | PHOTOCATALYST | WATER
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 03/2017, Volume 334, Issue C, pp. 100 - 111
•The catalytic activity of a single metal can be enhanced by a supporting metal.•Supporting metals were varied across the first-row period and down Group... 
Lewis acid | Dinitrogen | Metal-metal bonding | Dihydrogen | Bimetallic
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, p. 11335
Ammonia (NH3) is one of the most widely produced chemicals worldwide. It has application in the production of many important chemicals, particularly... 
N-2 | HYDROGENATION | AMMONIA | TEMPERATURE | MULTIDISCIPLINARY SCIENCES | LIGHT | DINITROGEN | CHEMISTRY | SURFACE | AIR | WATER
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 48, pp. 12458 - 12463
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 36, pp. 12480 - 12487
The production of ammonia (NH3) from molecular dinitrogen (N2) under mild conditions is one of the most attractive and challenging processes in chemistry. Here... 
N-2 REDUCTION | AMMONIA-SYNTHESIS | PINCER LIGAND | CATALYTIC-REDUCTION | FE-N-2 COMPLEX | RECENT PROGRESS | COMPLEXES BEARING | UNIQUE BEHAVIOR | MOLECULAR DINITROGEN | CO OXIDATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 07/2019, Volume 58, Issue 14, pp. 8927 - 8932
We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a... 
SAMARIUM DIIODIDE | NITROGEN-FIXATION | N-2-TO-NH3 CONVERSION | REDUCTION | COUPLED ELECTRON-TRANSFER | PINCER LIGANDS | CHATT CYCLE | LIGATING DINITROGEN | BEARING | TUNGSTEN-DINITROGEN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2018, Volume 140, Issue 27, pp. 8497 - 8508
The fixation of atmospheric N2 to NH3 is an essential process for sustaining life. One grand challenge is to develop efficient catalysts to photofix N2 under... 
ELECTRON-EXCITATION | NANOCOMPOSITES | AMMONIA | REDUCTION | MOLECULAR NITROGEN | DINITROGEN | OXYGEN VACANCIES | GENERATION | PHOTOCATALYTIC CONVERSION | CHEMISTRY, MULTIDISCIPLINARY | FIXATION
Journal Article
Nature, ISSN 0028-0836, 03/2016, Volume 531, Issue 7593, pp. 225 - 228
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 03/2017, Volume 334, pp. 84 - 99
•Ligand–metal combinations designed for coordination and activation of dinitrogen.•Evolution of ligand design in the Fryzuk lab.•Groups 4 and 5... 
Titanium | Ligand design | Zirconium | Tantalum | Dinitrogen activation | Niobium | SIDE-ON | COORDINATION CHEMISTRY | DINUCLEAR TANTALUM COMPLEX | BOND FORMATION | BRIDGED DIAMIDOPHOSPHINE LIGAND | NITROGENASE FEMO COFACTOR | CHEMISTRY, INORGANIC & NUCLEAR | SINGLE MOLYBDENUM CENTER | END-ON | N-2 LIGAND | ON-BOUND DINITROGEN | Nitrogen | Fixation | Transition metal compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2009, Volume 48, Issue 40, pp. 7415 - 7419
Breaking up: Reduction of a trivalent titanium complex afforded NN cleavage with formation of TiIV nitride complexes (see structure), which can be converted... 
nitrides | reduction | dinitrogen cleavage | hydrogenation | titanium | Titanium | Nitrides | Dinitrogen cleavage | Reduction | Hydrogenation | SIDE-ON | IMIDO COMPLEXES | CATALYTIC-REDUCTION | MOLECULAR NITROGEN | COORDINATED DINITROGEN | CHEMICAL NITROGEN-FIXATION | ORGANONITROGEN COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | END-ON | N-2 HYDROGENATION | ON-BOUND DINITROGEN
Journal Article