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chemistry, inorganic & nuclear (16) 16
hydrogenation (12) 12
diphosphinite ligands (11) 11
hydroformylation (9) 9
asymmetric catalysis (8) 8
ligands (8) 8
asymmetric hydrogenation (7) 7
catalysis (7) 7
ruthenium (7) 7
chemistry, organic (6) 6
complexes (6) 6
diphosphinite (6) 6
catalysts (5) 5
chemistry, multidisciplinary (5) 5
diphosphinite ligand (5) 5
diphosphinites (5) 5
homogeneous catalysis (5) 5
olefins (5) 5
rhodium (5) 5
alkenes (4) 4
derivatives (4) 4
highly enantioselective hydrogenation (4) 4
phosphite ligands (4) 4
bisphosphinites (3) 3
chemistry (3) 3
chemistry, applied (3) 3
enantiomers (3) 3
enantioselective hydroformylation (3) 3
enantioselective hydrogenation (3) 3
esters (3) 3
ligand (3) 3
palladium (3) 3
phosphinite complexes (3) 3
reactivity (3) 3
rhodium-chiral diphosphinites (3) 3
selectivity (3) 3
suzuki-miyaura cross-coupling reactions (3) 3
tridentate phosphorus ligands (3) 3
acid (2) 2
acyclic imines (2) 2
allylic alkylation (2) 2
asymmetry (2) 2
biochemistry & molecular biology (2) 2
biphep (2) 2
bond-cleavage (2) 2
carbohydrate phosphinites (2) 2
catalytic asymmetric hydrogenation of ketones (2) 2
catalyzed asymmetric hydrogenation (2) 2
chemistry, physical (2) 2
chiral diphosphinite ligand (2) 2
chiral rhodium catalysts (2) 2
chiral rhodium complexes (2) 2
chiro-inositol (2) 2
cross-coupling reactions (2) 2
crystallography (2) 2
crystals (2) 2
cyclitols (2) 2
dehydrodipeptides (2) 2
diastereoselectivity (2) 2
dipeptides (2) 2
dipeptides - chemistry (2) 2
diphosphite ligands (2) 2
efficient ligands (2) 2
enamides (2) 2
furanoside ligands (2) 2
hydrolysis (2) 2
imine hydrogenation (2) 2
index medicus (2) 2
induction (2) 2
inositol (2) 2
iridium-catalyzed hydrogenation (2) 2
mechanism (2) 2
metal-complexes (2) 2
nuphos (2) 2
oxazoline ligands (2) 2
pd complex (2) 2
phosphines - chemistry (2) 2
phosphinite ligands (2) 2
platinum (2) 2
quinoline derivatives (2) 2
regioselective (2) 2
resolution (2) 2
stereoisomerism (2) 2
structure (2) 2
tropos (2) 2
vinyl esters (2) 2
x-ray crystal structure (2) 2
1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole (1) 1
2+2 photocycloadditions (1) 1
2,2 '-biphosphole (1) 1
2,2'-biphosphole ligand (1) 1
2,2'-biphospholes (1) 1
2,2-biphosphole (1) 1
2,2’-biphosphole (1) 1
2,2′-biphospholes (1) 1
acetate (1) 1
acid platinum complexes (1) 1
acids (1) 1
additive effect (1) 1
aldehyd (1) 1
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Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2018, Volume 874, pp. 74 - 82
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 09/2018, Volume 32, Issue 9, p. n/a
... Buchwald phosphine ligands (S‐Phos (L1), t‐Bu XPhos (L2), Ru‐Phos (L3), Johnphos (L4) and DavePhos (L5). Ru‐Phos (L3) ligand exhibited high impact on the hydroformylation of eugenol providing high selectivity... 
phosphines | biorenwable olefins | hydroformylation | homogeneous catalysis | rhodium | TANDEM HYDROFORMYLATION/ACETALIZATION | INTERNAL OLEFINS | RHODIUM COMPLEXES | REGIOSELECTIVE HYDROFORMYLATION | DIPHOSPHINITE LIGANDS | CHEMISTRY, INORGANIC & NUCLEAR | HYDROGEN | ALKENES | ALLYLIC ALCOHOLS | ISOMERIZATION-HYDROFORMYLATION | ALLYLBENZENE | CHEMISTRY, APPLIED | Aldehydes | Olefins | Catalysis | Alkenes | Rhodium | Ligands | Selectivity | Catalytic converters | Synthesis gas
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 24, pp. 6969 - 6972
The first catalytic enantioselective synthesis of cyclobutylboronates, by using a chiral copper(I) complex, is reported. A broad variety of cyclobutanes have... 
cyclobutanes | copper | asymmetric catalysis | boron | cyclobutenes | HYDROBORATION | 2+2 PHOTOCYCLOADDITIONS | VINYLARENES | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITION | ALKENES | CYCLOBUTANE DERIVATIVES | DIPHOSPHINITE | LIGANDS | ARYL | Enantiomers | Copper | Catalysis
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 2005, Volume 282, Issue 1, pp. 215 - 220
Diphosphinite ligands 2 and 3, easily prepared from inexpensive d(+)-xylose in few steps, were tested in the Rh-catalyzed asymmetric hydroformylation of several vinyl arenes... 
Diphosphinite ligands | Asymmetric hydroformylation | Furanoside ligands | PHOSPHITE LIGANDS | ENVIRONMENTAL SCIENCES | furanoside ligands | CHEMISTRY, PHYSICAL | OLEFINS | STYRENE | diphosphinite ligands | asymmetric hydroformylation | ENANTIOSELECTIVE HYDROFORMYLATION | DIPHOSPHITE LIGANDS
Journal Article
Catalysis Communications, ISSN 1566-7367, 02/2014, Volume 46, pp. 109 - 112
Simple and efficient diphosphinite ligands were evaluated in rhodium catalyzed hydroformylation of vinyl acetate... 
Regioselective | Diphosphinite ligand | Homogeneous catalysis | Vinyl esters | Hydroformylation
Journal Article
CATALYSIS COMMUNICATIONS, ISSN 1566-7367, 02/2014, Volume 46, pp. 109 - 112
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 12/2014, Volume 43, Issue 45, pp. 17163 - 17171
The monophosphinite ligands, 1D-1,2;5,6-di-O-cyclopentylidene-3-O-methyl-4-O-diphenylphosphino-chiro-inositol (D-P1... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 12/2014, Volume 43, Issue 45, pp. 17163 - 17171
The monophosphinite ligands, 1D-1,2; 5,6-di-O-cyclopentylidene-3-O-methyl-4-O-diphenylphosphinochiro- inositol (D-P1), 1D-1,2... 
ACID | CYCLITOLS | BISPHOSPHINITES | ESTERS | REACTIVITY | BOND-CLEAVAGE | METAL-COMPLEXES | DIPHOSPHINITE LIGANDS | INOSITOL | CHEMISTRY, INORGANIC & NUCLEAR | Ruthenium | Asymmetry | Catalysts | Chlorides | Decomposition reactions | Ligands | Catalysis | Hydrogenation
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2003, Volume 345, Issue 1‐2, pp. 169 - 171
Iridium complexes incorporating xylose diphosphinite 1 and diphosphite 2, 3 ligands as source of chirality are active catalysts for the hydrogenation of imines providing moderate ee... 
iridium | diphosphinite | imines | asymmetric catalysis | diphosphite | hydrogenation | P‐ligands | Diphosphinite | Diphosphite | Imines | P-ligands | Iridium | Asymmetric catalysis | Hydrogenation | COMPLEXES | CHEMISTRY, ORGANIC | ASYMMETRIC HYDROGENATION | CHEMISTRY, APPLIED | HYDROFORMYLATION | PHOSPHINITES
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 10/2015, Volume 190, Issue 10, pp. 1668 - 1679
The novel 10-membered chelated metal complexes have been synthesized by the reaction of known ligand 1, CH 2 (o-C 6 H 4 OPPh 2 ) 2 , and 2, PPh 2 O(CH 2... 
diphosphinite ligands | Suzuki-Miyaura cross-coupling reactions | Tridentate phosphorus ligands | phosphinite complexes
Journal Article
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, ISSN 1042-6507, 10/2015, Volume 190, Issue 10, pp. 1668 - 1679
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 09/2019, Volume 495, p. 118959
... (R = H, Me) with a chiral phosphinite bidentate ligand. Reaction of [RuCl(η5-C5Me5)L] and [RuCl(η5-C9H7)L] (L = 1,2-[bis(diphenyl) phosphanyloxy]-1,2-diphenylethane) with an excess of GeCl2... 
Germyl ligand | Diphosphinite ligand | Ruthenium | Half-sandwich complexes | HYDROGENATION | CRYSTAL | OXIDATIVE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR | Optical activity | Germanium chlorides | Lithium aluminum hydrides | Crystal structure | Ruthenium compounds
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2014, Volume 43, Issue 2, pp. 584 - 591
The equimolar reaction between 2(2'-hydroxy)phenyloxazoline (1) and PPhCl2 in the presence of triethylamine afforded an unexpected cyclic product,... 
CATALYZED ASYMMETRIC HYDROGENATION | REARRANGEMENT | PHOSPHORUS LIGANDS | ALKENES | DIPHOSPHINITE | ETHYLENE OLIGOMERIZATION | ENANTIOSELECTIVE HYDROGENATION | CHEMISTRY | OXAZOLINE LIGANDS | DERIVATIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Coordination Chemistry, ISSN 0095-8972, 02/2010, Volume 63, Issue 3, pp. 373 - 393
Treatment of [RuCl 2 (COD)] n with the chiral diphosphinite ligand (1S,2S)-1,2-trans-bis-(O-diphenylphosphino)cyclohexane [(1S,2S)-14] and triethylamine gives the bis... 
X-ray crystal structure | Ruthenium | Chiral diphosphinite ligand | Chiro-inositol | Catalytic asymmetric hydrogenation of ketones | CARBOHYDRATE PHOSPHINITES | PRECATALYSTS | DERIVATIVES | HYDROFORMYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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