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Chemical Reviews, ISSN 0009-2665, 12/2017, Volume 117, Issue 23, pp. 13810 - 13889
Transition-metal-catalyzed cross-coupling reactions have been well-established as indispensable tools in modern organic synthesis. One of the major research... 
ONE-POT REACTION | ALPHA-DIAZOCARBONYL COMPOUNDS | RH(I)-CATALYZED DIRECT ARYLATION | N-TOSYLHYDRAZONES BEARING | TERMINAL ALKYNES SYNTHESIS | ENE-YNE-KETONES | CARBON QUATERNARY CENTERS | C-H ACTIVATION | ARYL HALIDES SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | DIAZO-COMPOUNDS APPROACH
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4672 - 4676
A catalytic, metal-free O–H bond insertion of α-diazoesters in water in the presence of B­(C6F5)3·nH2O (2 mol %) was developed, affording a series of... 
FUNCTIONALIZATION | ACID | SI-H | CHEMISTRY, ORGANIC | METAL-FREE HYDROGENATION | FRUSTRATED LEWIS PAIRS | B(C6F5)-CATALYZED TRANSFER | CARBENOID INSERTION | DIRECT MANNICH | AROMATIC C-H | FACILE PROTOCOL
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2019, Volume 58, Issue 39, pp. 13865 - 13868
The incorporation of CO2 into organometallic and organic molecules represents a sustainable way to prepare carboxylates. The mechanism of reductive... 
reaction mechanisms | carbon dioxide | nickel | structure elucidation | reduction | Carbon dioxide | Organic chemistry | Halides | Carboxylation | Direct reduction | Insertion | Chemical reactions | Species | Zinc | Carboxylates
Journal Article
Organic Letters, ISSN 1523-7060, 09/2009, Volume 11, Issue 18, pp. 4248 - 4250
Exposure of aromatic carboxamides 1e−1m, heteroaromatic carboxamides 1n−1p, and α,β-unsaturated carboxamides 1q−1s to 1,1-dimethylallene in the presence of the... 
FUNCTIONALIZATION | ORGANIC-SYNTHESIS | ALLYL METAL REAGENTS | ACTIVATION | COMPLEX | DIRECT ARYLATION | REVERSE PRENYLATION | TRYPROSTATIN-B | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | CLEAVAGE | Prenylation | Hydrocarbons, Aromatic - chemistry | Oxidants - chemistry | Oxidation-Reduction | Stereoisomerism | Molecular Structure | Catalysis | Alkadienes - chemistry | Hydrogenation | Iridium - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 3957 - 3961
Journal Article
Organic Letters, ISSN 1523-7060, 05/2014, Volume 16, Issue 10, pp. 2772 - 2775
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 11/2018, Volume 54, Issue 89, pp. 12561 - 12569
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2013, Volume 78, Issue 2, pp. 638 - 646
The ruthenium-catalyzed coupling reactions of benzamides with alkynes in the presence of acetic acid as a promoter smoothly proceeded regio- and... 
ROOM-TEMPERATURE | ORGANIC-SYNTHESIS | ORTHO OLEFINATION | DIRECT ARYLATION | INTRAMOLECULAR ARYLATION | REMOVABLE DIRECTING GROUP | COUPLING REACTION | RHODIUM CARBONYL | CHEMISTRY, ORGANIC | PROTON-ABSTRACTION MECHANISM | ORTHO-ALKENYLATION | Thermal properties | Ruthenium | Analysis | Catalysis | Chemical properties | Hydrogen bonding | Alkylation
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 22, pp. 7121 - 7124
Benzyne insertion to build the privileged scaffold of a [6.8.6]-tricyclic framework on polycyclic and sp3-rich natural products has been developed. The... 
ARYNE INSERTION | DIRECT ACYL-ALKYLATION | COMPLEX | ACID | LICORICE | ARYLATION | CHEMISTRY, ORGANIC | GLYCYRRHIZIN
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 89, pp. 12561 - 12569
Recent advances in the sulfonylation of C-H bonds with the insertion of sulfur dioxide are summarized. Usually, a sulfur dioxide surrogate, DABCO·(SO ) , is... 
Journal Article
Chemical Science, ISSN 2041-6520, 05/2012, Volume 3, Issue 5, pp. 1634 - 1639
A detailed investigation is presented to understand the catalytic pathway of our recently reported Rh(III)-catalyzed N-tosylaldimine insertion into aryl C-H... 
FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ARENES | ALDEHYDES | ASYMMETRIC HYDROGENATION | ALKYNES | CLEAVAGE | UNSATURATED MOLECULES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article