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Tetrahedron, ISSN 0040-4020, 06/2013, Volume 69, Issue 25, pp. 5152 - 5159
Aryl dialkyl phosphate, which is readily available from phenol, was a good substrate for the Pd(II) catalyzed aryl–aryl coupling reaction through ortho-C–H... 
Directing group | C–H activation | Palladium catalyst | Phosphate | Diaryliodonium salt | C-H activation | ROOM-TEMPERATURE | PALLADIUM | DIALKYL SULFATES | MECHANISM | ONE-POT SYNTHESIS | ARENES | COMPLEXES | NAPHTHALENE-CATALYZED LITHIATION | CHEMISTRY, ORGANIC | DIRECT TRANSFORMATION | BOND ACTIVATION | Phosphates | Palladium | Palladium catalysts
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2013, Volume 78, Issue 8, pp. 3688 - 3696
A novel protocol for palladium-catalyzed arylation of the C­(sp2)–H bond directed by a N,N-dimethylaminomethyl group in the presence of AgOAc and Cu­(OAc)2·H2O... 
DIRECTING GROUP | FUNCTIONALIZATION | ACTIVATION | ARYL BOND FORMATION | MECHANISM | KINETICS | COUPLING REACTION | COMPLEXES | CHEMISTRY, ORGANIC | DIRECT C-2 ARYLATION | METATHESIS | Thermal properties | Spin coupling | Analysis | Copper compounds | Palladium | Catalysis | Chemical properties
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2019, Volume 361, Issue 17, pp. 3925 - 3929
Rhodium acetate effectively promotes the carboxylate‐directed ortho‐arylation of (hetero)aromatic carboxylates with aryl bromides. The main advantage of this... 
heteroarenes | aryl bromides | benzoic acids | biaryls | C−H arylation | rhodium | RH(I)-CATALYZED DIRECT ARYLATION | CHEMISTRY, ORGANIC | C-H arylation | TRACELESS DIRECTING GROUPS | HETEROCYCLES | BONDS | HETEROARYLATION | ARYL IODIDES | CHEMISTRY, APPLIED | EXCHANGE | CARBOXYLIC-ACIDS | BENZOIC-ACIDS | Benzoic acid | Palladium catalysts | Rankings | Rhodium | Bromides | Aromatic compounds | Substrates | Carboxylates
Journal Article
Organic Letters, ISSN 1523-7060, 06/2010, Volume 12, Issue 12, pp. 2694 - 2697
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 18, pp. 4586 - 4589
Ni­(II)-catalyzed ortho-arylation of aromatic and heteroaromatic carboxamides with triethoxy­(aryl)­silanes assisted by a removable bidentate auxiliary is... 
BIDENTATE-CHELATION ASSISTANCE | ALIPHATIC AMIDES | DIRECTING GROUPS | C(SP)-H BONDS | CROSS-COUPLING REACTIONS | CHEMISTRY, ORGANIC | RECENT PROGRESS | ORGANOSILICON REAGENTS | CARBON-HYDROGEN BONDS | DIRECT THIOLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2014, Volume 50, Issue 94, pp. 14862 - 14865
An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl... 
FUNCTIONALIZATION | ACTIVATION | METHYLATION | C-H BOND | CROSS-COUPLING REACTION | ARENES | N-METHOXYBENZAMIDES | DIRECT ACCESS | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 10/2014, Volume 50, Issue 94, pp. 14862 - 14865
An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl... 
Aromatic compounds | Amides
Journal Article
Synlett, ISSN 0936-5214, 10/2013, Volume 24, Issue 16, pp. 2153 - 2159
Abstract A palladium(II)-catalyzed oxidative ortho -arylation of 2-phenylpyridines via direct C–H activation with aryl boric acids is described. The reaction... 
letter | 2-phenylpyridines | palladium | arylboronic acid | C-H functionalization | ortho arylation | POLYMERS | NOBEL LECTURE | ARENES | CHEMISTRY, ORGANIC | CLEAVAGE | H BOND ACTIVATION | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | DERIVATIVES | CATALYZED DIRECT ARYLATION
Journal Article
Organometallics, ISSN 0276-7333, 09/2010, Volume 29, Issue 18, pp. 4058 - 4065
An efficient synthesis of ortho-arylated 2-phenoxypyridines catalyzed by palladium acetate is described. Treatment of 2-phenoxypyridines with two and a half... 
ROOM-TEMPERATURE | PALLADIUM | CROSS-COUPLING REACTIONS | MECHANISM | ALKYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | DERIVATIVES | ARYL CHLORIDES | CATALYZED DIRECT ARYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 52, pp. 18082 - 18086
Current approaches to achieve site selectivity in the CH activation of arenes involve the use of directing groups or highly electron-poor arenes. In contrast,... 
DIRECTING GROUP | FUNCTIONALIZATION | ROOM-TEMPERATURE | NATURAL-PRODUCTS | ARYL HALIDES | BOND ACTIVATION | UNACTIVATED ARENES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | CARBOXYLIC-ACIDS | BENZOIC-ACIDS | Construction | Aromatic compounds | Anisole | Biocompatibility | Activation | Selectivity | Scaffolds | Tuning
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2016, Volume 18, Issue 23, pp. 6094 - 6097
Direct arylations of pyridines are challenging transformations due to the high Lewis basicity of the sp(2)-nitrogen. The use of carboxylates as directing... 
C3-SELECTIVE ARYLATION | ELECTRON-DEFICIENT HETEROCYCLES | C-H ARYLATION | ARYL HALIDES | CHEMISTRY, ORGANIC | SELECTIVE ARYLATION | BOND ACTIVATION | ARYLBORONIC ACIDS | CATALYZED DIRECT ARYLATION | CARBOXYLIC-ACIDS | BENZOIC-ACIDS
Journal Article
Organic Letters, ISSN 1523-7060, 04/2011, Volume 13, Issue 8, pp. 2008 - 2011
Purine is utilized as a new directing group for the Pd-catalyzed monoarylation of 6-arylpurines with simple aryl iodides via C−H bond activation in good... 
PALLADIUM | CROSS-COUPLING REACTIONS | NUCLEOSIDES | CYTOSTATIC ACTIVITY | CHEMISTRY, ORGANIC | SODIUM PERSULFATE | BOND ACTIVATION | ORGANIC HALIDES | N-OXIDES | SIMPLE ARENES | CATALYZED DIRECT ARYLATION | Purines - chemistry | Stereoisomerism | Iodides - chemistry | Molecular Structure | Catalysis | Hydrogen - chemistry | Palladium - chemistry | Carbon - chemistry
Journal Article
ChemCatChem, ISSN 1867-3880, 09/2012, Volume 4, Issue 9, pp. 1345 - 1352
The direct arylation of N‐(2‐pyridyl) substituted anilines is described. Arylation takes place in ortho position to the amine functionality and is directed by... 
amines | CH activation | palladium | homogeneous catalysis | heterocycles | ACTIVATION | ACIDS | ALKYLATION | CHEMISTRY, PHYSICAL | MULTIPLE ARYLATION | C?H activation | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | H BONDS | ARYL | SP | CATALYZED DIRECT ARYLATION | C—H activation | Full Papers
Journal Article
Synthesis, ISSN 0039-7881, 11/2009, Volume 2009, Issue 22, pp. 3757 - 3764
Abstract An efficient one-pot synthesis of ORTHO-arylated 2-phenylpyridine and pyridine derivatives by use of potassium aryltri­fluoroborates is presented. The... 
paper | Pyridines | Arylations | Palladium catalyst | C-H functionalization | Potassium trifluoroborate | ORGANIC-SYNTHESIS | PALLADIUM | ACTIVATION | potassium trifluoroborate | palladium catalyst | CHEMISTRY, ORGANIC | BOND FORMATION | ARYLBORONIC ACIDS | BORONIC ACIDS | CROSS-COUPLING REACTIONS | pyridines | arylations | ARYL | CATALYZED DIRECT ARYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2009, Volume 50, Issue 11, pp. 1229 - 1235
Journal Article
Synthesis, ISSN 0039-7881, 10/2008, Volume 2008, Issue 19, pp. 3013 - 3039
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2015, Volume 51, Issue 15, pp. 3127 - 3130
Salicylic acids are shown to be readily available and versatile starting materials that easily undergo a tandem arylation-protodecarboxylation process under... 
H BOND ACTIVATION | DIRECT ORTHO-ARYLATION | DIRECTING GROUP | FREE-AMINE | CATALYZED ORTHO-ARYLATION | SELECTIVE ARYLATION | ARYL IODIDES | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H | PHENOL DERIVATIVES
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 02/2015, Volume 51, Issue 15, pp. 3127 - 3130
Salicylic acids are shown to be readily available and versatile starting materials that easily undergo a tandem arylation-protodecarboxylation process under... 
Salicylic acid | Palladium | Synthesis | Versatility
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 50, pp. 15636 - 15639
The first methodology for Au­(I/III)-catalyzed oxidative cross-coupling of arenes via double C–H activation has been developed. The reaction is fully selective... 
ORGANIC GOLD COMPOUNDS | FUNCTIONALIZATION | POLYFLUOROARENES | ARYL HALIDES | CHEMISTRY | BOND ACTIVATION | ORTHO-ARYLATION | OXIDATIVE ADDITION | DIRECT ALKYNYLATION | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
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