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directed ortho borylation (35) 35
chemistry, multidisciplinary (31) 31
catalysis (24) 24
chemistry, organic (24) 24
functionalized arenes (22) 22
arenes (17) 17
borylation (17) 17
activation (15) 15
c-h activation (15) 15
derivatives (15) 15
directed ortho-metalation (14) 14
ligands (14) 14
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iridium (13) 13
index medicus (12) 12
heteroarenes (11) 11
ligand (10) 10
room-temperature (10) 10
arylation (9) 9
c-h borylation (9) 9
molecular structure (9) 9
boron compounds - chemistry (8) 8
cross-coupling reactions (8) 8
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article (7) 7
bisdiboron (7) 7
bond activation (7) 7
hindered ketones (7) 7
iridium - chemistry (7) 7
palladium (7) 7
bonds (6) 6
chemistry (6) 6
ch activation (6) 6
functionalization (6) 6
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rhodium (6) 6
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boron (5) 5
boronic acids (5) 5
catalysts (5) 5
chemical properties (5) 5
chemistry, applied (5) 5
cross-coupling reaction (5) 5
direct arylation (5) 5
iridium complex (5) 5
pyridine (5) 5
room-temperature reactions (5) 5
silylation (5) 5
supported iridium complex (5) 5
analysis (4) 4
arylboronic acids (4) 4
boranes (4) 4
boron compounds - chemical synthesis (4) 4
carbon - chemistry (4) 4
ch activation (4) 4
cross-coupling (4) 4
cross‐coupling (4) 4
functionalisation (4) 4
funktionalisierung (4) 4
halopyridinylboronic acids (4) 4
heterogeneous catalysis (4) 4
hydrogen - chemistry (4) 4
lithiation (4) 4
nitrogen (4) 4
organometallic compounds - chemistry (4) 4
ortho borylation (4) 4
palladium - chemistry (4) 4
pinacolborane (4) 4
reagents (4) 4
regioselectivity (4) 4
selectivity (4) 4
amides (3) 3
aromatic compounds (3) 3
aryl (3) 3
aryl halides (3) 3
bor (3) 3
c-h bonds (3) 3
carbon-carbon bonds (3) 3
carbon-hydrogen bonds (3) 3
catalyzed borylation (3) 3
chemical synthesis (3) 3
chemistry, physical (3) 3
construction (3) 3
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efficient (3) 3
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hydrosilylation (3) 3
inorganic chemicals (3) 3
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organic chemistry (3) 3
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Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 134 - 137
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2019, Volume 75, Issue 17, pp. 2547 - 2552
We report a rhodium-catalyzed ortho C(sp2)-H borylation of 2-phenylpyridines using commercially available N-heterocyclic carbenes (NHCs) as ligand and... 
N-heterocyclic carbene | C-H activation | Ortho borylation | Rhodium-catalyzed | Room temperature | ACTIVATION | ARYLATION | CHEMISTRY, ORGANIC | DIRECTED ORTHO BORYLATION | HETEROARENES | LIGANDS | C-H BORYLATION | FUNCTIONALIZED ARENES | DERIVATIVES | Rhodium | Chemical tests and reagents | Heterocyclic compounds
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2019, Volume 361, Issue 4, pp. 858 - 862
A convenient and ligand‐free iridium‐catalyzed dehydrogenative ortho C−H borylation of benzyl‐2‐pyridines has been developed. The reaction proceeds smoothly at... 
iridium | C−H activation | synthetic methods | borylation | organoboron | ACTIVATION | PHENOL | CHEMISTRY, ORGANIC | DIRECTED ORTHO BORYLATION | HETEROARENES | C-H activation | ESTERS | CHEMISTRY | REGIOSELECTIVE BORYLATION | CHEMISTRY, APPLIED | FUNCTIONALIZED ARENES | Pyridine | Pyridines | Dehydrogenation | Reagents | Ligands | Catalysis | Iridium | Functional groups | Room temperature
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2016, Volume 138, Issue 1, pp. 84 - 87
The ligand-enabled development of ortho and meta C–H borylation of aromatic aldehydes is reported. It was envisaged that while ortho borylation could be... 
HYDROCARBONS | ACIDS | DIRECTED ORTHO BORYLATION | BOND ACTIVATION | C-H BORYLATION | SUPPORTED IRIDIUM COMPLEX | FUNCTIONALIZED ARENES | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Ligands | Usage | Catalysis | Analysis
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 04/2011, Volume 40, Issue 4, pp. 1992 - 2002
The borylation of alkanes and arenes has become some of the most practical C-H bond functionalization chemistry. Most striking is the high regioselectivity of... 
FREE-RADICAL SUBSTITUTION | SATURATED-HYDROCARBONS | CHLORIDE COMPLEXES | IRIDIUM COMPLEXES | DIRECTED ORTHO BORYLATION | REGIOSPECIFIC FUNCTIONALIZATION | ALKYL ISOMERIZATION EQUILIBRIA | CATALYZED BORYLATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2019, Volume 141, Issue 13, pp. 5334 - 5342
Optically active organoboronic acids and their derivatives are an important family of target compounds in organic chemistry, catalysis, and medicinal... 
DIELS-ALDER | ENANTIOSELECTIVE SYNTHESIS | ARENES | C(SP)-H BORYLATION | REGIOSELECTIVE BORYLATION | DIRECTED ORTHO BORYLATION | BOND ACTIVATION | C-H BORYLATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION
Journal Article
Synlett, ISSN 0936-5214, 09/2016, Volume 27, Issue 14, pp. 2043 - 2050
Abstract A ligand-controlled discovery of ortho and meta C–H boryl­ation of aromatic aldehydes is described. In both cases, an amine is used and it was... 
synpacts | ortho borylation | benzaldehyde | C-H activation | meta borylation | iridium catalyst | ACID | CATALYZED REACTIONS | CHEMISTRY, ORGANIC | DIRECTED ORTHO BORYLATION | PHENOL DERIVATIVES | U-SHAPED TEMPLATE | BROMINATION | OLEFINATION | BOND ACTIVATION | SUPPORTED IRIDIUM COMPLEX | FUNCTIONALIZED ARENES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 08/2019, Volume 21, Issue 16, pp. 6476 - 6480
A double-fold ortho and remote C-H borylation of BINOL is described. The proposed mechanisms involved electrostatically and sterically directed ortho and... 
FUNCTIONALIZATION | META | SIMPLE SYNTHETIC APPROACH | ACTIVATION | DIRECTED ORTHO-METALATION | CHIRAL BRONSTED ACIDS | CHEMISTRY, ORGANIC | ARYL | NONCOVALENT INTERACTIONS | LIGAND | BORYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 23, pp. 7745 - 7748
An efficient strategy for the para-selective borylation of aromatic esters is described. For achieving high para-selectivity, a new catalytic system has been... 
FUNCTIONALIZATION | TRANSITION-METAL CATALYSIS | ROOM-TEMPERATURE | MOLECULAR RECOGNITION | SUBSTRATE | ARENES | BONDS | DIRECTED ORTHO BORYLATION | SUPPORTED IRIDIUM COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | ARTIFICIAL CYTOCHROME-P-450 | Ligands | Oxides | Research | Chemical properties | Chemical structure
Journal Article
Tetrahedron, ISSN 0040-4020, 03/2017, Volume 73, Issue 12, pp. 1576 - 1582
Morpholine amides are cheap and safe alternative to Weinreb amides as acylating agents of organometallic species. Herein, the in-situ lithiation/borylation of... 
In-situ trapping | Cross coupling | Selectivity | Lithiation | Borylation | N-METHYLAMIDES | EFFECTIVE ACYLATING AGENTS | DIRECTED ORTHO-METALATION | ARENES | CHEMISTRY, ORGANIC | ALDEHYDES | NANOPARTICLES | HETEROARENES | AMINES | ESTERS | AMIDES | Amides
Journal Article
Chemical Communications, ISSN 1359-7345, 06/2014, Volume 50, Issue 51, pp. 6782 - 6784
An easily prepared series of phenylindenyldihydridosilyl ruthenium complexes (2a-2d) was obtained by reaction of tertiary silanes with the... 
ACTIVATION | MECHANISM | HETEROCYCLES | SILANES | SILYLENE COMPLEXES | CONSTRUCTION | REACTIVITY | DIRECTED ORTHO BORYLATION | FUNCTIONALIZED ARENES | CHEMISTRY, MULTIDISCIPLINARY | ROOM-TEMPERATURE REACTIONS | Silanes | Chemical bonds | Activation | Ruthenium | Catalysts | Substrates
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 04/2014, Volume 12, Issue 13, pp. 2041 - 2044
The development of an Ir-catalyzed ortho-C-H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120... 
HETEROARENES | ORTHO ARYLATION | BIS(PINACOLATO)DIBORON | COMPLEXES | CHEMISTRY, ORGANIC | DIRECTED ORTHO BORYLATION | PROPARGYLIC AMINES | BOND ACTIVATION | FUNCTIONALIZED ARENES | ROOM-TEMPERATURE REACTIONS | SILYLATION
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 04/2014, Volume 12, Issue 13, pp. 2041 - 2044
The development of an Ir-catalyzed ortho-C-H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120 °C to... 
Boron Compounds - chemistry | Imines - chemistry | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Aniline Compounds - chemistry | Catalysis | Iridium - chemistry | Boronic Acids - chemical synthesis
Journal Article
Chemistry Letters, ISSN 0366-7022, 9/2011, Volume 40, Issue 9, pp. 1007 - 1008
ortho-Selective C–H borylation of aryl ketones with bis(pinacolato)diboron proceeded at 120 °C in octane in the presence of a catalytic amount of iridium(I)... 
ROOM-TEMPERATURE | HETEROARENES | ARENES | COMPLEXES | ESTERS | BOND FUNCTIONALIZATION | DIRECTED ORTHO BORYLATION | PINACOLBORANE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article