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chemistry, organic (72) 72
chemistry, multidisciplinary (55) 55
c-h insertion (40) 40
dirhodium carboxylates (40) 40
catalysis (38) 38
dirhodium (37) 37
rhodium (34) 34
cyclopropanation (26) 26
asymmetric catalysis (22) 22
index medicus (22) 22
organic-synthesis (22) 22
asymmetric-synthesis (21) 21
carbon-hydrogen insertion (21) 21
chiral dirhodium carboxylates (21) 21
insertion (21) 21
diazo-compounds (20) 20
chemistry, inorganic & nuclear (19) 19
chemistry (18) 18
stereoisomerism (18) 18
ligands (17) 17
organic chemistry (17) 17
catalysts (16) 16
construction (16) 16
diazo compounds (16) 16
enantioselective synthesis (15) 15
metal carbene transformations (14) 14
selectivity (14) 14
enantiomers (13) 13
molecular structure (13) 13
rhodium - chemistry (13) 13
transformations (13) 13
alpha-diazo ketones (12) 12
chemical properties (12) 12
complexes (12) 12
activation (11) 11
analysis (11) 11
carbenoids (11) 11
carboxylates (11) 11
diazoacetates (11) 11
enantioselectivity (11) 11
esters (11) 11
olefins (11) 11
beta-keto-esters (10) 10
catalyst (10) 10
chiral catalysts (10) 10
chemistry, physical (9) 9
cycloaddition (9) 9
derivatives (9) 9
dirhodium complex (9) 9
homochiral rhodium carboxylates (9) 9
intramolecular cyclopropanation (9) 9
research (9) 9
1,3-dipolar cycloaddition (8) 8
alpha-diazocarbonyl compounds (8) 8
asymmetric cyclopropanation (8) 8
carbenes (8) 8
chemistry, medicinal (8) 8
synthesis (8) 8
acid (7) 7
chiral dirhodium catalysts (7) 7
copper (7) 7
crystal-structure (7) 7
diazo compound (7) 7
enantiocontrol (7) 7
intermolecular 1,3-dipolar cycloaddition (7) 7
pharmacology & pharmacy (7) 7
reactivity (7) 7
ruthenium (7) 7
silyl enol ethers (7) 7
amination (6) 6
asymmetric synthesis (6) 6
bonds (6) 6
c-h functionalization (6) 6
carbonyl ylides (6) 6
chemical sciences (6) 6
cyclopentane construction (6) 6
dirhodium complexes (6) 6
functionalization (6) 6
homogeneous catalysis (6) 6
letter (6) 6
methane - analogs & derivatives (6) 6
methane - chemistry (6) 6
models, molecular (6) 6
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nitrogen-atom-transfer (6) 6
organometallic compounds - chemistry (6) 6
rh catalyst (6) 6
rhodium carbenoids (6) 6
stereoselectivity (6) 6
alkenes (5) 5
alkyl-alpha-diazoesters (5) 5
aziridination (5) 5
bridging prolinate ligands (5) 5
c-h amination (5) 5
catalyzed-reactions (5) 5
chemistry, analytical (5) 5
cyclopropane compounds (5) 5
diazoacetamides (5) 5
diazocarbonyl compounds (5) 5
dirhodium catalysts (5) 5
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The Journal of Organic Chemistry, ISSN 0022-3263, 09/2009, Volume 74, Issue 17, pp. 6564 - 6571
Journal Article
Organic Letters, ISSN 1523-7060, 01/2013, Volume 15, Issue 2, pp. 310 - 313
The rhodium-catalyzed reaction of 2-diazo-5-arylpent-4-enoates can be controlled by the appropriate choice of catalyst and catalyst loading to form either... 
CARBENE | DIRHODIUM(II) | BICYCLOBUTANE | INSERTION REACTIONS | ADAMANTYLGLYCINE | CONSTRUCTION | CHEMISTRY, ORGANIC | CATALYST | ALPHA-DIAZOESTERS | REARRANGEMENTS | CARBONYL YLIDES
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2015, Volume 71, Issue 21, pp. 3237 - 3246
A new synthetic protocol for the preparation of 3-aryl-3-methoxycarbonyl cyclopropenes with an unsubstituted double bond has been developed that allowed for... 
Acetylenes | Cyclopropenes | Rhodium | Diazoesters | Cyclopropenation | DIRHODIUM(II) | EASY ACCESS | REACTIVITY | CHEMISTRY, ORGANIC | CATALYST | ALKYNES | ALKENES | TANDEM RING | CONSTRUCTION | EFFICIENT | METATHESIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 436 - 442
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2012, Volume 41, Issue 2, pp. 644 - 650
Two new diruthenium(II,III) tetramidate compounds, Ru(2)(NHOCC(CH(3))(2))(4)Cl (1) and Ru(2)(NHOCCH(2)CH(3))(4)Cl (2) have been prepared and structurally... 
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2012, Volume 45, Issue 8, pp. 1365 - 1377
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2012, Volume 2, Issue 6, pp. 1221 - 1225
A general method for the synthesis of chiral heteroleptic rhodium(II) tetracarboxylate catalysts is reported. The chlorinated TCPT unit was found to be an... 
halogen bond | dirhodium | heteroleptic catalyst | asymmetric catalysis | cyclopropanation | mixed ligand | INSERTION | MOLECULAR-STRUCTURE | HYDROGEN-BOND | CHEMISTRY, PHYSICAL | C-H FUNCTIONALIZATION | DIRHODIUM(II) CARBOXYLATES | AZAVINYL CARBENES | ALKENES | 1,3-DIPOLAR CYCLOADDITION | ALKYL-ALPHA-DIAZOESTERS | YLIDE
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 08/2012, Volume 16, Issue 15, pp. 1808 - 1836
Journal Article
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 12/2018, Volume 2018, Issue 44, pp. 6150 - 6157
We have developed a short and efficient bottom-up synthesis of acrylic and styrylic polymer beads containing dirhodium(II) tetracarboxylates. The solid... 
Cyclopropanation | Heterogeneous catalysis | Carbene ligands | DIRHODIUM(II) COMPLEX | Rhodium | STRATEGY | Immobilization | CHEMISTRY, ORGANIC | Bottom-up synthesis | IONIC LIQUID | CATALYST | C-H INSERTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 33, pp. 9868 - 9871
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 07/2013, Volume 9, Issue 1, pp. 1407 - 1413
In this work, we introduce a new class of halodiazocarbonyl compounds, alpha-halodiazoacetamides, which through a metal-free, ambient-temperature thermolysis... 
Halocarbonylcarbene | α-halo-β-lactam | Diazo | Halogenation | Thermolysis | ORGANIC-SYNTHESIS | CARBENE | diazo | CARBON | halocarbonylcarbene | HETEROCARBENES | CHEMISTRY, ORGANIC | halogenation | DIRHODIUM(II) CARBOXYLATES | THERMAL-DECOMPOSITION | ETHYL DIAZOACETATE | alpha-halo-beta-lactam | thermolysis | ACYLDIAZOMETHANES | CONDENSATION | STEREOSELECTIVE-SYNTHESIS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2001, Volume 66, Issue 24, pp. 8139 - 8144
The relative rate constants for the Rh(II)-mediated diazo decomposition of a series of para- or meta-substituted diazophenylacetates were measured through... 
REACTIVITIES | DIAZOACETATES | DECOMPOSITIONS | CARBON-HYDROGEN INSERTION | CONSTRUCTION | CHEMISTRY, ORGANIC | DIRHODIUM(II) CARBOXYLATES | CARBENOID INSERTION | CHEMOSELECTIVITY | TRANSFORMATIONS | C-H INSERTION | Chemistry, Organic | Rhodium | Catalysts | Physiological aspects | Esters | Research | Decomposition (Chemistry)
Journal Article
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