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1. Full Text Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis
by Koper, Marc T.M
Journal of Electroanalytical Chemistry, ISSN 1572-6657, 09/2011, Volume 660, Issue 2, pp. 254 - 260
This paper summarizes the thermodynamic theory of multi-electron transfer reactions and its implications for electrocatalysis. We discuss the fundamental... 
Electron transfer | Oxygen evolution | Electrocatalysis | Thermodynamics | Oxygen reduction | Hydrogen evolution | OXIDATION | ELECTROCHEMISTRY | CATALYSIS | CHEMISTRY, ANALYTICAL | ELECTROLYTIC HYDROGEN EVOLUTION | EXCHANGE CURRENT | MODEL | DISSOCIATIVE ADSORPTION | TRENDS | REDUCTION | METAL-SURFACES | Evolution | Chemical properties | Electron transport | Hydrogen
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2. Full Text Localized Ti-III mediated dissociative electron transfer for carbon halogen bond activation on TiO2
by Zhu, Q and Wang, YY and Zhang, HN and Duan, R and Chen, CC and Song, WJ and Zhao, JC
APPLIED CATALYSIS B-ENVIRONMENTAL, ISSN 0926-3373, 12/2017, Volume 219, pp. 322 - 328
The reductive activation of the carbon halogen (C-X) bond is a key step in the transformation of organic halides via bond dissociation. Monochloroacetic acid... 
PHOTOCATALYTIC HYDROGENATION | MECHANISM | CHEMISTRY, PHYSICAL | CHLOROACETIC ACIDS | Carbon-halogen bond activation | Photocatalytic dehalogenation | ENGINEERING, CHEMICAL | RUTILE | Dissociative electron transfer | ENGINEERING, ENVIRONMENTAL | REDUCTIVE CLEAVAGE | KINETICS | ARYL HALIDES | ANATASE | DEGRADATION | TITANIUM-DIOXIDE | Monochloroacetic acid | Titanium dioxide
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3. Full Text Localized TiIII mediated dissociative electron transfer for carbon halogen bond activation on TiO2
by Zhu, Qian and Wang, Yuanyuan and Zhang, Hongna and Duan, Ran and Chen, Chuncheng and Song, Wenjing and Zhao, Jincai
Applied Catalysis B: Environmental, ISSN 0926-3373, 12/2017, Volume 219, pp. 322 - 328
The reductive activation of the carbon halogen (C-X) bond is a key step in the transformation of organic halides via bond dissociation. Monochloroacetic acid... 
Dissociative electron transfer | Carbon-halogen bond activation | Monochloroacetic acid | Titanium dioxide | Photocatalytic dehalogenation
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4. Full Text C-OH bond cleavage initiated by electron transfer: Electroreduction of 9-fluorenol
by Mendkovich, Andrey S and Syroeshkin, Mikhail A and Nasybullina, Darya V and Mikhailov, Mikhail N and Gultyai, Vadim P and Elinson, Mikhail N and Rusakov, Alexander I
Electrochimica Acta, ISSN 0013-4686, 02/2016, Volume 191, pp. 962 - 973
Cyclic voltammetry, chronoamperometry, coulometry, electrolysis, digital simulation, quantum chemical calculations of 9-fluorenol as an example, were used to... 
chronoamperometry | radical anion | cyclic volammetry | dissociative electron transfer | 9-Fluorenol | ELECTROCHEMISTRY | ROOM-TEMPERATURE | DIALKYL PEROXIDES | DISTONIC RADICAL-ANIONS | CARBON-HALOGEN BOND | ELECTROCHEMICAL REDUCTION | REAGENT FORMATION | SELF-PROTONATION | THERMOCHEMICAL PARAMETERS | BICYCLIC ENDOPEROXIDES | DRIVING-FORCE
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5. Full Text Supplemental activation method for high-efficiency electron-transfer dissociation of doubly protonated peptide precursors
by Swaney, Danielle L and McAlister, Graeme C and Wirtala, Matthew and Schwartz, Jae C and Syka, John E. P and Coon, Joshua J
Analytical Chemistry, ISSN 0003-2700, 01/2007, Volume 79, Issue 2, pp. 477 - 485
Electron-transfer dissociation (ETD) delivers the unique attributes of electron capture dissociation to mass spectrometers that utilize radio frequency... 
CHEMISTRY, ANALYTICAL | INFRARED MULTIPHOTON DISSOCIATION | PROTEIN-SEQUENCE ANALYSIS | NONERGODIC PROCESS | QUADRUPOLE ION-TRAP | TRANSFER ION/ION REACTIONS | GAS-PHASE | COLLISION-INDUCED DISSOCIATION | MULTIPLY-CHARGED IONS | TANDEM MASS-SPECTROMETRY | CAPTURE DISSOCIATION | Peptide Fragments - analysis | Protons | Amino Acid Sequence | Electron Transport | Molecular Sequence Data | Proteins - chemistry | Proteomics - methods | Dissociative Disorders | Mass Spectrometry - methods | Trypsin - chemistry | Atomic properties | Chemical properties | Peptides | Electron transport | Analysis | Analytical chemistry | Proteomics | Test methods | Electron transfer reactions | Comparative analysis | Mass spectrometry | Chromatography | Index Medicus
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6. Full Text Uncovering the intrinsic relationship of electrocatalysis and molecular electrochemistry for dissociative electron transfer to polychloroethanes at silver cathode
by Huang, Binbin and Zhu, Yuanyuan and Li, Jing and Zeng, Guangming and Lei, Chao
Electrochimica Acta, ISSN 0013-4686, 03/2017, Volume 231, pp. 590 - 600
The relationship between electrocatalysis and molecular electrochemistry for the reductive dechlorination of organic chlorides has been a central topic for... 
Electrocatalysis | Dechlorination | Dissociative electron transfer (DET) | Molecular electrochemistry | ELECTROCHEMISTRY | ACTIVATION | CLEAVAGE | REDUCTIVE DECHLORINATION | AQUEOUS-SOLUTION | CARBON-HALOGEN BONDS | HALIDE REDUCTION | KINETICS | RADICALS | VOLATILE ORGANIC-COMPOUNDS | C-H | Thermodynamics | Electrochemical reactions | Dichloropropane | Adsorption | Chlorides | Electrochemistry | Electron transport | Analysis | Halocarbons | Chlorination | Surface chemistry | Electron transfer | Free energy | Studies | Electrodes | Silver | Chemical bonds | Catalysis | Activation energy
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7. Full Text Electrocatalysis and electron transfer mechanisms in the reduction of organic halides at Ag
by Isse, Abdirisak Ahmed and Berzi, Giacomo and Falciola, Luigi and Rossi, Manuela and Mussini, Patrizia R and Gennaro, Armando
Journal of Applied Electrochemistry, ISSN 0021-891X, 11/2009, Volume 39, Issue 11, pp. 2217 - 2225
The reductive cleavage of a series of organic halides, including both aromatic and aliphatic compounds, has been investigated in acetonitrile at glassy carbon... 
Electrocatalysis | Dissociative electron transfer | Organic halides | Silver electrode | ELECTROCHEMISTRY | CARBON-HALOGEN BOND | SILVER CATHODES | CLEAVAGE | PRIMARY ALKYL IODIDES | BENZYL CHLORIDES | RESONANCE | KINETICS | ACETONITRILE | DICHLOROMETHANE | POLYCRYSTALLINE SILVER | Electrochemical reactions | Dichloropropane | Chlorides | Electrochemistry | Nitriles | Catalysis | Electron transport | Silver | Reduction | Halides | Electron transfer | Cleavage | Bonding
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8. Full Text Stepwise and concerted dissociative electron transfer onto a sigma-type orbital in polybrominated aromatics
by Rotko, G and Romanczyk, PP and Andryianau, G and Kurek, SS
ELECTROCHEMISTRY COMMUNICATIONS, ISSN 1388-2481, 06/2014, Volume 43, pp. 117 - 120
Convolution analysis of voltammetric data along with DFT calculations shows that the studied pentabromophenyl ethers undergo concerted dissociative electron... 
TRANSITION | ELECTROCHEMISTRY | Convolution analysis | Dissociative electron transfer | OFT calculations | sigma Radical anions | Aromatic halides | Polybrominated aromatics | MECHANISMS | BOND
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9. Full Text Stepwise and concerted dissociative electron transfer onto a σ-type orbital in polybrominated aromatics
by Rotko, Grzegorz and Romańczyk, Piotr P and Andryianau, Gleb and Kurek, Stefan S
Electrochemistry Communications, ISSN 1388-2481, 06/2014, Volume 43, pp. 117 - 120
Convolution analysis of voltammetric data along with DFT calculations shows that the studied pentabromophenyl ethers undergo concerted dissociative electron... 
Aromatic halides | Polybrominated aromatics | Convolution analysis | Dissociative electron transfer | DFT calculations | σ Radical anions | Radical anions
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10. Full Text С-ОН bond cleavage initiated by electron transfer: electroreduction of 9-fluorenol
by Mendkovich, Andrey S and Syroeshkin, Mikhail A and Nasybullina, Darya V and Mikhailov, Mikhail N and Gultyai, Vadim P and Elinson, Mikhail N and Rusakov, Alexander I
Electrochimica Acta, ISSN 0013-4686, 02/2016, Volume 191, pp. 962 - 973
Сyclic voltammetry, chronoamperometry, coulometry, electrolysis, digital simulation, quantum chemical calculations of 9-fluorenol as an example, were used to... 
chronoamperometry | radical anion | cyclic volammetry | dissociative electron transfer | 9-Fluorenol
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11. Full Text Electron transfer and multi-atom abstraction reactions between atomic metal anions and NO, NO2 and SO2
by Butson, J.M and Curtis, S and Mayer, P.M
Chemical Physics Letters, ISSN 0009-2614, 05/2016, Volume 651, pp. 203 - 208
The atomic metal anions Fe , Cs , Cu and Ag were reacted with NO, NO and SO to form intact NO , NO and SO with no fragmentation. Yields for the molecular... 
TEMPERATURES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | GAS-PHASE | CHEMISTRY, PHYSICAL | DISSOCIATIVE ATTACHMENT | CHARGE-TRANSFER | AFFINITIES | IONIZATION | PHOTOELECTRON-SPECTROSCOPY | MOLECULES | OXALATES
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12. Full Text Relationship between supporting electrolyte bulkiness and dissociative electron transfer at catalytic and non-catalytic electrodes
by Gennaro, Armando and Isse, Abdirisak Ahmed and Giussani, Ester and Mussini, Patrizia Romana and Primerano, Irene and Rossi, Manuela
Electrochimica Acta, ISSN 0013-4686, 02/2013, Volume 89, pp. 52 - 62
Dissociative electron transfers (DETs) involving aryl halides in the presence of supporting electrolytes with tetraalkylammonium cations TAA of different... 
Dissociative electron transfer | Electrocatalytic silver electrode | Aryl halides | Supporting electrolyte effect | Electron tunnelling | ELECTROCHEMISTRY | ELECTROCATALYTIC REDUCTION | ELECTROCHEMICAL REDUCTION | APROTIC-SOLVENTS | SILVER CATHODES | BENZYL CHLORIDES | CYANOACETIC ACID | PALLADIUM CATHODE | TRANSFER KINETICS | POLYCRYSTALLINE SILVER | VOLATILE ORGANIC-COMPOUNDS | Electrodes | Electrolytes | Electron transport | Halides | Analysis | Reduction (electrolytic) | Electron transfer | Activation | Mathematical models | Cations | Catalysts | Aromatic compounds | Catalysis
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13. Full Text Electron attachment and intramolecular electron transfer in unsaturated chloroderivatives
by Modelli, Alberto
Physical Chemistry Chemical Physics, ISSN 1463-9076, 07/2003, Volume 5, Issue 14, pp. 2923 - 2930
The electron transmission (ET) and dissociative electron attachment (DEA) spectra of chloroalkyl ethene and ethyne derivatives are reported. B3LYP/6-31G*... 
BENZENE-DERIVATIVES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | TEMPORARY ANION STATES | NEGATIVE-ION STATES | DISSOCIATIVE ATTACHMENT | CHLOROALKANES | ENERGIES | SPECTRA | TRANSMISSION SPECTROSCOPY | AFFINITIES | CHLOROBENZENE
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14. Full Text Elucidation of the Electron Transfer Reduction Mechanism of Anthracene Endoperoxides
by Donkers, Robert L and Workentin, Mark S
Journal of the American Chemical Society, ISSN 0002-7863, 02/2004, Volume 126, Issue 6, pp. 1688 - 1698
The homogeneous and heterogeneous reductions of the endoperoxides 9,10-diphenyl-9,10-epidioxyanthracene (DPA-O-2) and 9,10-dimethyl-9,10-epidioxyanthracene... 
DIALKYL PEROXIDES | HETEROCOERDIANTHRONE ENDOPEROXIDE | DISSOCIATIVE REDUCTION | ACTIVATION PARAMETERS | ORGANOMETALLIC ELECTROCHEMISTRY | AROMATIC ENDOPEROXIDES | SINGLET OXYGEN | BICYCLIC ENDOPEROXIDES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL SWEEP VOLTAMMETRY | EXCITED-STATES | Electron transport | Analysis | Photochemistry
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15. Full Text A model for bond-breaking electron transfer at metal electrodes
by Santos, E and Koper, M.T.M and Schmickler, W
Chemical Physics Letters, ISSN 0009-2614, 2006, Volume 419, Issue 4, pp. 421 - 425
A model Hamiltonian is proposed for bond-breaking electrochemical electron transfer to an adsorbed molecule. The theory is applied to a homonuclear molecule,... 
MOLECULAR-DYNAMICS | REDUCTION | INTERFACE | KINETICS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | POLAR-SOLVENTS | SIMULATION | DISSOCIATIVE ADSORPTION | SURFACES | Electron transport | Analysis
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16. Full Text Electron transfer to sulfides
by Meneses, Ana Belèn and Antonello, Sabrina and Arévalo, Maria Carmen and Maran, Flavio
Electrochimica Acta, ISSN 0013-4686, 2005, Volume 50, Issue 5, pp. 1207 - 1215
The problem of characterizing the steps associated with the dissociative reduction of sulfides has been addressed. The electrochemical reduction of... 
Intrinsic barrier | Dissociative electron transfer | Bond cleavage | Sulfide reduction | Self-protonation
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17. Full Text Dissociative electron transfer to diphenyl-substituted bicyclic endoperoxides: The effect of molecular structure on the reactivity of distonic radical anions and determination of thermochemical parameters
by Magri, David C and Workentin, Mark S
Molecules, ISSN 1420-3049, 2014, Volume 19, Issue 8, pp. 11999 - 12010
The heterogeneous electron transfer reduction of the bicyclic endoperoxide 1,4-diphenyl-2,3-dioxabicyclo[2.2.1]hept-5-ene (4) was investigated in... 
Cyclic voltammetry | Endoperoxide | Electrode interface | Convolution analysis | Distonic radical ion | Dissociative electron transfer | TRANSFER REDUCTION | BREAKING | DIALKYL PEROXIDES | MECHANISM | ELECTROREDUCTION | CHEMISTRY, ORGANIC | BOND FORMATION | CYCLOPROPYLCARBINYL | distonic radical ion | REARRANGEMENTS | FORCE RELATIONSHIPS | convolution analysis | cyclic voltammetry | endoperoxide | electrode interface | KINETICS | dissociative electron transfer | Electron Transport | Oxidation-Reduction | Peroxides - chemistry | Anions - chemistry | Carbon - chemistry | Electrodes | Bridged Bicyclo Compounds - chemistry | Peroxides - chemical synthesis | Molecular Structure | Biphenyl Compounds - chemistry | Kinetics | Dimethylformamide - chemistry | Electrons | Index Medicus | Anions | Reduction (electrolytic) | Molecular structure | Electron transfer | Bonding | Glassy carbon | Radicals
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18. Full Text Dynamical steering in an electron transfer surface reaction: Oriented NO(v = 3, 0.08 < Ei < 0.89 eV) relaxation in collisions with a Au(111) surface
by Bartels, Nils and Golibrzuch, Kai and Bartels, Christof and Chen, Li and Auerbach, Daniel J and Wodtke, Alec M and Schäfer, Tim
Journal of Chemical Physics, ISSN 0021-9606, 2014, Volume 140, Issue 5, pp. 054710 - 054710
We report measurements of the incidence translational energy dependence of steric effects in collisions of NO(v = 3) molecules with a Au(111) surface using a... 
ROTATIONAL-EXCITATION | VIBRATIONAL-RELAXATION | ORIENTATION | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | LIF | ENERGY-TRANSFER | NO SCATTERING | DISSOCIATIVE ADSORPTION | PHOTODESORPTION | PHOTODISSOCIATION | MOLECULES | Beams (radiation) | Resonance scattering | Steering | Ionization | Collisions | Dependence | Electron transfer | Steric effects | Orientation | Incidence | ELECTRON TRANSFER | DISTRIBUTION | NITRIC OXIDE | VIBRATIONAL STATES | INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY | RELAXATION | COLLISIONS | PHOTOIONIZATION | SPECTROSCOPY | ENERGY DEPENDENCE | SURFACES
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19. Full Text Electronic state selectivity in dication-molecule single electron transfer reactions: NO2+ + NO
by Parkes, Michael A and Lockyear, Jessica F and Schröder, Detlef and Roithová, Jana and Price, Stephen D
Physical Chemistry Chemical Physics, ISSN 1463-9076, 11/2011, Volume 13, Issue 41, pp. 18386 - 18392
The single-electron transfer reaction between NO2+ and NO, which initially forms a pair of NO+ ions, has been studied using a position-sensitive coincidence... 
CHEMICAL-REACTIONS | BIMOLECULAR REACTIONS | NEUTRAL CO2 | DISSOCIATIVE PHOTOIONIZATION | KINETIC-ENERGY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | NITRIC-OXIDE | GAS-PHASE | CHEMISTRY, PHYSICAL | BOND-FORMING PROCESSES | CHARGED IONS | PHOTOELECTRON-SPECTROSCOPY | Electron states | Precursors | Carbon dioxide | Physical chemistry | Electron transfer | Selectivity | Single electrons | Collision dynamics
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20. Full Text On the possibility of STM-control of dissociative electron transfer
by Kuznetsov, Alexander M and Medvedev, Igor G
Electrochemistry Communications, ISSN 1388-2481, 2007, Volume 9, Issue 7, pp. 1624 - 1628
A novel physical mechanism of control of the rate of the electrochemical dissociative electron transfer with the use of the STM arrangement is proposed. The... 
Tunneling | Dissociative electron transfer | Anti-bonding orbital | in situ STM | HALIDES | ELECTROCHEMISTRY | METAL-ELECTRODES | ACTIVATION | ENERGY | anti-bonding orbital | POLAR-SOLVENTS | tunneling | REDUCTION | KINETICS | SCANNING-TUNNELING-MICROSCOPY | dissociative electron transfer | BOND-BREAKING | CHARGE | Electron transport
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