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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 5, pp. 1625 - 1628
An unprecedented α‐allylation of amines was achieved by combining palladium catalysis and visible‐light photoredox catalysis. In this dual catalysis process,... 
palladium | radicals | photochemistry | synthetic methods | allylic compounds | Palladium | Synthetic methods | Allylic compounds | Radicals | Photochemistry | TRANSITION-METAL CATALYSIS | ORGANIC-SYNTHESIS | GOLD | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ALKENES | ALLYLIC ACETATES | C-H ARYLATION | MICHAEL ACCEPTORS | DUAL CATALYSIS | Amines | Catalysts | Merging | Derivatives | Catalysis | Allyl compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2014, Volume 136, Issue 14, pp. 5225 - 5228
We report a study involving the successful merger of two separate chiral catalytic cycles: a chiral anion phase-transfer catalysis cycle to activate... 
KETONES | BETA-KETOESTERS | ENANTIOSELECTIVE FLUORINATION | IMINES | CHLORIDES | CARBONYL-COMPOUNDS | ALDEHYDES | DUAL CATALYSIS | CENTERS | CHEMISTRY, MULTIDISCIPLINARY | Anions | Cyclohexanone | Asymmetry | Catalysts | Amino acids | Activation | Catalysis | Fluorination | Communication
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2013, Volume 52, Issue 9, pp. 2593 - 2598
The other side of the mountain: Changing the framework of diyne systems opens up new cyclization modes for dual gold catalysis. Instead of a 5‐endo cyclization... 
gold | CH activation | dual catalysis | computational chemistry | alkynes | C-H activation | C-H BOND | COMPLEXES | PLATINUM | TERMINAL ALKYNES | CASCADE | AROMATIZATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | CH activation | ENEDIYNES | CYCLOISOMERIZATION | Antirheumatic agents | Catalysis | Mountains | Gold | Pathways | Switches | Insertion | Activation | Carbenes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2014, Volume 20, Issue 14, pp. 3874 - 3886
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 12, pp. 4040 - 4043
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14450 - 14453
Herein we describe the auxiliary‐directed arylation of unactivated C(sp3)−H bonds with aryldiazonium salts, which proceeds under synergistic photoredox and... 
palladium | C−H activation | photoredox | metallaphotoredox | arylation | AMIDATION | CARBON-HYDROGEN BONDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC AMIDES | C-H activation | C-H ARYLATION | NICKEL | ARYL HALIDES | OXIDATIVE CYCLIZATION | C(SP)-H | DUAL CATALYSIS | Amides | Palladium | Catalysis | Salts | Quaternary | Selectivity | Aliphatic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 7, pp. 2139 - 2143
Under mild dual photoredox/copper catalysis, the reaction of N‐alkoxypyridinium salts with readily available silyl reagents (TMSN3, TMSCN, TMSNCS) afforded... 
alkoxy radical | C−H activation | dual catalysis | photoredox catalyst | 1,5-HAT | 5-HAT | DECOMPOSITION | HYDROGEN-ATOM | COPPER | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | C-H activation | BONDS | ALKOXYL RADICALS | GENERATION | RELAY CYCLIZATIONS | METAL-FREE | CHLORINATION | Salts | Halides | Reagents | Alcohol | Catalysis | Copper | Enantiomers | Alcohols
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2017, Volume 139, Issue 16, pp. 5627 - 5639
This Perspective presents an overview of catalytic enantio­selective transformations that allow convenient access to all stereo­isomers of a given product with... 
ACYCLIC STEREOSELECTION | DIVERSITY-ORIENTED SYNTHESIS | COOPERATIVE CATALYSIS | NONADJACENT STEREOCENTERS | SMALL MOLECULES | SYNERGISTIC CATALYSIS | ALDOL REACTIONS | ALPHA-ALLYLATION | DUAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | ALLYLIC SUBSTITUTIONS | Usage | Chemical properties | Catalysis | Chemical synthesis | Isomerism
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10333 - 10337
An efficient protocol for the direct allylic C(sp3)−H bond activation of unactivated tri‐ and tetrasubstituted alkenes and their functionalization with aryl‐... 
nickel | C−H activation | alkenes | photocatalysis | allylic compounds | HALIDES | ROOM-TEMPERATURE | PALLADIUM | ARYLATION | PHOTOREDOX/NICKEL DUAL CATALYSIS | 9-MESITYL-10-METHYLACRIDINIUM | OXIDATIVE ADDITION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | ACETATES | DERIVATIVES | Olefins | Nickel | Catalysis | Alkenes | Regioselectivity | Hydrogen bonds | Aromatic compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2018, Volume 24, Issue 42, pp. 10766 - 10772
An unprecedented, often almost quantitative access to tricyclic aromatic compounds by dual gold catalysis was developed. This synthetic route expands the scope... 
chemoselectivity | benzofulvenes | dual gold catalysis | gold vinylidenes | C−H insertion | ACTIVATION | PRECATALYSTS | COMPLEXES | POLYCYCLIC COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | VINYLIDENES | C-H insertion | GENERATION | RECENT ACHIEVEMENTS | 1,5-DIYNES | CYCLIZATION | DIYNES | Aromatic compounds | Catalysis | Competition | Gold | Hydrogen bonds | Computer applications | Insertion | Selectivity | Bonding | Intermediates
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2015, Volume 21, Issue 13, pp. 4962 - 4965
A novel and efficient CP bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and... 
CP bond formation | nickel | dual catalysis | radicals | photochemistry | Dual catalysis | C-P bond formation | Nickel | Radicals | Photochemistry | GOLD | STRATEGY | PHOTOCATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | H ARYLATION | FUNCTIONALIZATION | CHEMISTRY | PHOSPHINE OXIDES | METAL-FREE | Iodides | Methodology | Aromatic compounds | Oxides | Tolerances | Catalysis | Bonding
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 08/2015, Volume 13, Issue 30, pp. 8116 - 8162
In recent years, enantioselective cooperative catalytic reactions, wherein two catalysts work simultaneously to form products which cannot be obtained by the... 
BRONSTED ACID | TRANSITION-METAL CATALYSIS | N-HETEROCYCLIC CARBENE | ANION PHASE-TRANSFER | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | BAYLIS-HILLMAN CARBONATES | CHIRAL PHOSPHORIC-ACID | DUAL-CATALYSIS | ASYMMETRIC REDUCTIVE AMINATION | H INSERTION REACTION | Catalysis | Metals - chemistry | Stereoisomerism | Organic Chemicals - chemistry
Journal Article