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1. Full Text Reliably Regioselective Dialkyl Ether Cleavage with Mixed Boron Trihalides
by Atienza, Bren Jordan P and Truong, Nam and Williams, Florence J
Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 20, pp. 6332 - 6335
A protocol for the regioselective cleavage of unsymmetrical alkyl ethers to generate alkyl alcohol and alkyl bromide products is described. A mixture of... 
CHEMISTRY, ORGANIC | DEALKYLATION | BROMIDE | CHLORIDE
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2. Solvent-controlled chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines with tert-butyl nitrite (Electronic supplementary information (ESI) available. See DOI: 10.1039/c9qo00965e)
by Xuanhua Guo and Chengdong Lv and Qaiser Mahmood and Li Zhou and Guangqiang Xu and Qinggang Wang
Organic Chemistry Frontiers, ISSN 2052-4110, 01/2019, Volume 6, Issue 19, pp. 3401 - 3407
A metal-free, acid-free and chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines has been developed. tert-Butyl nitrite (TBN)... 
Nitration | Dealkylation | Nitrosation
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3. Full Text Visible-Light-Mediated Dealkylative Coupling of Trialkylamines with Dialkyl Acetylenedicarboxylates
by Liu, Fangnan and Zhang, Zhiguo and Bao, Zongbi and Su, Baogen and Xing, Huabin and Yang, Qiwei and Yang, Yiwen and Ren, Qilong
Synlett, ISSN 0936-5214, 06/2017, Volume 28, Issue 9, pp. 1116 - 1120
Abstract A dealkylative addition of trialkylamines to dialkyl acetylenedicarboxylates with eosin Y as a metal-free catalyst and molecular oxygen as the... 
letter | organocatalysis | dealkylation | photoredox reaction | dialkyl acetylenedicarboxylates | trialkylamines | addition | ORGANIC-SYNTHESIS | COMPLEX | OXIDATIVE N-DEALKYLATION | TERTIARY-AMINES | CHEMISTRY, ORGANIC | RHODIUM PORPHYRINS | BOND-CLEAVAGE | PHOTOREDOX CATALYSIS | FUNCTIONALIZATION | ACYLATIVE DEALKYLATION | ALIPHATIC-AMINES
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4. Full Text Selective phenol recovery via simultaneous hydrogenation/dealkylation of isopropyl- and isopropenyl-phenols employing an H-2 generator combined with tandem micro-reactor GC/MS
by Kumagai, S and Asakawa, M and Kameda, T and Saito, Y and Watanabe, A and Watanabe, C and Teramae, N and Yoshioka, T
SCIENTIFIC REPORTS, ISSN 2045-2322, 09/2018, Volume 8, Issue 1, p. 13994
The pyrolysis of bisphenol A (BPA), an essential process ingredient used in industry and many everyday life products, helps produce low-industrial-demand... 
DEALKYLATION-TRANSALKYLATION | MULTIDISCIPLINARY SCIENCES | TERT-BUTYLATION | TOLUENE | HYDROGEN-PRODUCTION | BISPHENOL-A | POLYCARBONATE | PYROLYSIS | CATALYST | ETHYLBENZENE DEALKYLATION | ZEOLITE
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5. Full Text A Single-Event MicroKinetic model for "ethylbenzene dealkylation/xylene isomerization" on Pt/H-ZSM-5 zeolite catalyst
by Toch, K and Thybaut, J.W and Vandegehuchte, B.D and Narasimhan, C.S.L and Domokos, L and Marin, G.B
Applied Catalysis A: General, ISSN 0926-860X, 05/2012, Volume 425-426, pp. 130 - 144
The Single-Event Microkinetic (SEMK) methodology has been applied towards "ethylbenzene dealkylation/xylene isomerization" under industrially relevant... 
Ethylbenzene dealkylation | Rational design | Xylene isomerization | Single-Event Microkinetic modeling | Catalyst optimization | Models | Zeolites | Analysis | Isomerization | Ethylbenzene | Catalysts | Dealkylation | Xylene | Mathematical models | Activation energy | Transalkylation
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6. Full Text Preparation of human drug metabolites using fungal peroxygenases
by Poraj-Kobielska, Marzena and Kinne, Matthias and Ullrich, René and Scheibner, Katrin and Kayser, Gernot and Hammel, Kenneth E and Hofrichter, Martin
Biochemical Pharmacology, ISSN 0006-2952, 2011, Volume 82, Issue 7, pp. 789 - 796
The synthesis of hydroxylated and - or -dealkylated human drug metabolites (HDMs) via selective monooxygenation remains a challenging task for synthetic... 
Peroxidase | Peroxygenation | N-Dealkylation | Hydroxylation | Cytochrome P450 | O-Dealkylation | PROPRANOLOL | 1A2 | CYTOCHROMES P450 | TAMOXIFEN | TOXICITY | HUMAN LIVER-MICROSOMES | QUANTITATIVE-DETERMINATION | CYP2D6 | ENZYMES | PHARMACOLOGY & PHARMACY | NAPROXEN | Hydrogen Peroxide - chemistry | Oxygen Isotopes | Oxidation-Reduction | Stereoisomerism | Dealkylation | Pharmaceutical Preparations - chemistry | Mixed Function Oxygenases - chemistry | Kinetics | Agaricales - enzymology | Agrocybe - enzymology | Metabolites | Life Sciences | Pharmacology | Pharmaceutical sciences
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7. Full Text The mechanism of aromatic dealkylation in methanol-to-hydrocarbons conversion on H-ZSM-5: What are the aromatic precursors to light olefins?
by Ilias, Samia and Bhan, Aditya
Journal of Catalysis, ISSN 0021-9517, 03/2014, Volume 311, pp. 6 - 16
Aromatic dealkylation in methanol-to-hydrocarbons conversion on HZSM-5 occurs via the paring mechanism and 1,2,4,5 tetramethylbenzene is the predominant... 
Propylene | Isotopic experiments | Methanol-to-olefins | Ethylene | Side-chain mechanism | Zeolite | Paring mechanism | Aromatic dealkylation | MTO REACTION | PRODUCT SELECTIVITY | CATALYSIS | CHEMISTRY, PHYSICAL | ELIMINATION | ENGINEERING, CHEMICAL | ZEOLITE H-BETA | CO-REACTION | CHEMISTRY | ETHENE | SAPO-34 | INSIGHTS | Alkylbenzene | Olefins | Methanol
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8. Full Text Enantioselective Oxidative Aerobic Dealkylation of N‐Ethyl Benzylisoquinolines by Employing the Berberine Bridge Enzyme
by Gandomkar, Somayyeh and Fischereder, Eva‐Maria and Schrittwieser, Joerg H and Wallner, Silvia and Habibi, Zohreh and Macheroux, Peter and Kroutil, Wolfgang
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 50, pp. 15051 - 15054
N‐Dealkylation methods are well described for organic chemistry and the reaction is known in nature and drug metabolism; however, to our knowledge,... 
enzyme catalysis | asymmetric synthesis | N‐dealkylation | alkaloids | enantioselective | N-dealkylation | COMPLEX | MECHANISM | TERTIARY-AMINES | BOND FORMATION | N,N-DIMETHYLANILINES | CHEMISTRY, MULTIDISCIPLINARY | OXIDASE | ISOQUINOLINE | DEMETHYLATION | LIVER-MICROSOMES | Amines - chemistry | Isoquinolines - metabolism | Biocatalysis | Oxidation-Reduction | Stereoisomerism | Molecular Conformation | Amines - metabolism | Alkylation | Oxygen - metabolism | Oxidoreductases, N-Demethylating - chemistry | Isoquinolines - chemistry | Eschscholzia - enzymology | Oxygen - chemistry | Oxidoreductases, N-Demethylating - metabolism | Physiological aspects | Enzymes | Synthesis | Catalysis | Enantiomers | Organic compounds
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9. Full Text Amine Oxidative N‑Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry
by Kim, Sunghee and Ginsbach, Jake W and Lee, Jung Yoon and Peterson, Ryan L and Liu, Jeffrey J and Siegler, Maxime A and Sarjeant, Amy A and Solomon, Edward I and Karlin, Kenneth D
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 8, pp. 2867 - 2874
Copper(II) hydroperoxide species are significant intermediates in processes such as fuel cells and (bio)chemical oxidations, all involving stepwise reduction... 
BINUCLEAR COPPER SITE | THERMAL-STABILITY | OXYGEN ACTIVATION | ELECTRONIC-STRUCTURES | ALPHA-HYDROXYLATING MONOOXYGENASE | MONONUCLEAR COPPER | HYDROGEN-BONDING INTERACTION | END-ON | CATALYTIC MECHANISM | CHEMISTRY, MULTIDISCIPLINARY | DOPAMINE BETA-MONOOXYGENASE | Amines - chemistry | Hydrogen Peroxide - chemistry | Copper - chemistry | Oxidation-Reduction | Hydroxyl Radical - chemistry | Dealkylation | Iron - chemistry | Molecular Conformation | Peroxides - chemistry | Models, Molecular | Binding Sites | Chlorine compounds | Copper compounds | Amines | Chemical properties | Cu–O homolysis | Fenton reaction | Copper(II)-hydroperoxide | DFT calculations | oxidative N-dealkylation
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10. Full Text Theoretical elucidation of the metabolic mechanisms of phenothiazine neuroleptic chlorpromazine catalyzed by cytochrome P450 isoenzyme 1A2
by Xue, Zhiyu and Zhang, Yan and Tao, Jing and Kang, Yuan and Chen, Zeqin and Xue, Ying
Theoretical Chemistry Accounts, ISSN 1432-881X, 9/2016, Volume 135, Issue 9, pp. 1 - 14
Chlorpromazine, belonging to the first-generation antipsychotics, is known to cause some side effects, such as hepatotoxicity and agranulocytosis. The... 
Theoretical and Computational Chemistry | Chemistry | Physical Chemistry | CYP1A2 | Atomic/Molecular Structure and Spectra | Aromatic hydroxylation | Inorganic Chemistry | N -dealkylation | Chlorpromazine | Organic Chemistry | S-oxidation | N-dealkylation | AB-INITIO | REACTIVITY | CAFFEINE | CHEMISTRY, PHYSICAL | MODEL | N-DEMETHYLATION | MONOOXYGENASE | N,N-DIMETHYLANILINES | OXIDATIVE STRESS PLAYS | ENZYMES | DEALKYLATION | Metabolites | Cytochrome P-450 | Phenothiazine
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11. Full Text Kinetics and Degradation Mechanism of Adrenaline Derivative CpQ in Diluted Aqueous Solutions
by Blasko, Andrei and Tam, James and Gunasekera, Sajeevi and Eboreime, Ale
Biochemistry, ISSN 0006-2960, 07/2018, Volume 57, Issue 30, pp. 4536 - 4546
The degradation kinetics of an adrenaline (epinephrine) derivative, CpQ, was studied in solution in the pH range of 1–12 at 40–80 °C by high-performance liquid... 
CYTOCHROME-P450 | ELECTRON | AMINES | N-DEALKYLATION | BIOCHEMISTRY & MOLECULAR BIOLOGY | COMPLEXES | N,N-DIMETHYLANILINE | Hydrogen Peroxide - chemistry | Hydrolysis | Temperature | Metals - chemistry | Oxidation-Reduction | Stereoisomerism | Dealkylation | Water - chemistry | Epinephrine - analogs & derivatives | Kinetics | Buffers | Hydrogen-Ion Concentration
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12. Full Text Facile Hydrogenolysis of C(sp3)–C(sp3) σ Bonds
by Fillion, Eric and Beaton, Eric and Nguyen, Yen and Wilsily, Ashraf and Bondarenko, Ganna and Jacq, Jérôme
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2016, Volume 358, Issue 21, pp. 3422 - 3434
The modification of benzylic quaternary, tertiary, and secondary carbon centers through palladium‐catalyzed hydrogenolysis of C(sp3)–C(sp3) σ bonds is... 
diarylmethane | reductive dealkylation | quaternary centers | hydrogenolysis | Meldrum's acid
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13. Full Text Catalytic and stoichiometric oxidation of N,N-dimethylanilines mediated by nonheme oxoiron(IV) complex with tetrapyridyl ligand
by Lakk-Bogáth, Dóra and Kripli, Balázs and Meena, Bashdar I and Speier, Gábor and Kaizer, József
Polyhedron, ISSN 0277-5387, 09/2019, Volume 169, pp. 169 - 175
Catalytic activity and selectivity of [Fe (N4Py )(CH CN] , where the possible reactive high-valent intermediate (Fe O) is known and spectroscopically well... 
Nonheme oxoiron complex | Kinetics | C[sbnd]H activation | Oxidative N-dealkylation | Bioinspired oxidation | CYTOCHROME P450-CATALYZED HYDROXYLATION | HYDROGEN-ATOM | CRYSTALLOGRAPHY | HORSERADISH-PEROXIDASE | CHEMISTRY, INORGANIC & NUCLEAR | OXYGEN | C-H activation | ELECTRON-TRANSFER | MODEL SYSTEMS | AMINES | N-DEALKYLATION | DEMETHYLATION | MECHANISTIC PROBE
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14. Full Text Upgrading of lignin-derived compounds: Reactions of eugenol catalyzed by HY zeolite and by Pt/γ-Al 2O 3
by Nimmanwudipong, Tarit and Runnebaum, Ron C and Ebeler, Susan E and Block, David E and Gates, Bruce C
Catalysis Letters, ISSN 1011-372X, 02/2012, Volume 142, Issue 2, pp. 151 - 160
Dealkylation | Isomerization | Zeolite Y | Eugenol | Hydrogenation | Lignin upgrading
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15. Full Text Diisobuty laluminium hydride (DIBAL-H) promoted secondary rim regioselective demethylations of permethylated β-cyclodextrin: A mechanistic proposal
by Xiao, Sulong and Yang, Ming and Sinaÿ, Pierre and Blériot, Yves and Sollogoub, Matthieu and Zhang, Yongmin
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2010, Issue 8, pp. 1510 - 1516
Cyclodextrins | Regioselectivity | Reaction mechanisms | Dealkylation | Protecting groups
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16. Full Text Cytochrome P450 CYP199A4 from Rhodopseudomonas palustris Catalyzes Heteroatom Dealkylations, Sulfoxidation, and Amide and Cyclic Hemiacetal Formation
by Coleman, Tom and Wong, Siew Hoon and Podgorski, Matthew N and Bruning, John B and De Voss, James J and Bell, Stephen G
ACS Catalysis, ISSN 2155-5435, 07/2018, Volume 8, Issue 7, pp. 5915 - 5927
The cytochrome P450 enzymes execute a range of selective oxidative biotransformations across many biological systems. The bacterial enzyme CYP199A4 catalyzes... 
C-H bond oxidation | heteroatom oxidation | dealkylation | enzyme mechanism | crystal structures | biocatalysis | cytochrome P450 enzymes | OXIDATION | SYSTEM | COMPOUND-I | MECHANISM | CRYSTAL-STRUCTURE | REACTIVITY | CHEMISTRY, PHYSICAL | EPOXIDATION | N-DEALKYLATION | DEMETHYLATION | C-H HYDROXYLATION
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17. Full Text Development of a Safe and Efficient Two-Step Synthesis for Preparing 1-Bromoacetyl-3,3-dinitroazetidine, a Novel Clinical Anticancer Candidate
by Straessler, Nicholas A and Lesley, Michael W and Cannizzo, Louis F
Organic Process Research & Development, ISSN 1083-6160, 03/2012, Volume 16, Issue 3, pp. 512 - 517
An efficient process for synthesizing and isolating a new investigative anticancer agent, 1-bromoacetyl-3,3-dinitroazetidine, is described. The reaction... 
MILD | ACID | TERTIARY-AMINES | N-DEALKYLATION | NITROLYSIS | ACYLATIVE DEALKYLATION | CHEMISTRY, ORGANIC | CHEMISTRY, APPLIED | SALTS | 1,3,3-TRINITROAZETIDINE
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18. Full Text Shape selectivity vapor-phase conversion of lignin-derived 4-ethylphenol to phenol and ethylene over acidic aluminosilicates: Impact of acid properties and pore constraint
by Liao, Yuhe and d’Halluin, Martin and Makshina, Ekaterina and Verboekend, Danny and Sels, Bert F
Applied Catalysis B: Environmental, ISSN 0926-3373, 10/2018, Volume 234, pp. 117 - 129
Selective dealkylation of alkylphenols, the opposite reaction of the more commonly studied phenol alkylation, may represent an important reaction in the... 
Aluminosilicate | Shape selectivity | Bio-Phenol | Ethylphenol | Dealkylation | ZSM-5 | BIRCH WOOD | HYDROGENOLYSIS | ALKYLAROMATIC COMPOUNDS | THERMOLYTIC REACTIONS | NICKEL-CATALYST | CHEMISTRY, PHYSICAL | ENGINEERING, CHEMICAL | ALKYL-AROMATICS | LIGNOCELLULOSE FRACTIONATION | ENGINEERING, ENVIRONMENTAL | CATALYTIC REDUCTIVE FRACTIONATION | ETHYLBENZENE DEALKYLATION | ZEOLITE
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19. Full Text Synthesis of 2-arylhydrazinylidene-3-oxo-4,4,4-trifluorobutanoic acids as new selective carboxylesterase inhibitors and radical scavengers
by Khudina, Olga G and Makhaeva, Galina F and Elkina, Natalia A and Boltneva, Natalia P and Serebryakova, Olga G and Shchegolkov, Evgeny V and Rudakova, Elena V and Lushchekina, Sofya V and Burgart, Yanina V and Bachurin, Sergey O and Richardson, Rudy J and Saloutin, Victor I
Bioorganic & Medicinal Chemistry Letters, ISSN 0960-894X, 10/2019, p. 126716
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20. Full Text Selective Ring-Opening of N‑Alkyl Pyrrolidines with Chloroformates to 4‑Chlorobutyl Carbamates
by Yu, Chunghyeon and Shoaib, Mahbubul Alam and Iqbal, Naeem and Kim, Jun Soo and Ha, Hyun-Joon and Cho, Eun Jin
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2017, Volume 82, Issue 13, pp. 6615 - 6620
Our study shows that among aza-heterocycles of various ring sizes, including aziridines, azetidines, pyrrolidines, and piperidines, only N-alkyl pyrrolidines... 
DENSITY | MILD | ACID-CHLORIDES | TERTIARY-AMINES | CHEMISTRY, ORGANIC | DEALKYLATION | DERIVATIVES | Chemical reactions | Usage | Chemical properties | Pyrrole
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