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Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 20, pp. 6332 - 6335
A protocol for the regioselective cleavage of unsymmetrical alkyl ethers to generate alkyl alcohol and alkyl bromide products is described. A mixture of... 
CHEMISTRY, ORGANIC | DEALKYLATION | BROMIDE | CHLORIDE
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 01/2019, Volume 6, Issue 19, pp. 3401 - 3407
A metal-free, acid-free and chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines has been developed. tert-Butyl nitrite (TBN)... 
Nitration | Dealkylation | Nitrosation
Journal Article
Synlett, ISSN 0936-5214, 06/2017, Volume 28, Issue 9, pp. 1116 - 1120
Abstract A dealkylative addition of trialkylamines to dialkyl acetylenedicarboxylates with eosin Y as a metal-free catalyst and molecular oxygen as the... 
letter | organocatalysis | dealkylation | photoredox reaction | dialkyl acetylenedicarboxylates | trialkylamines | addition | ORGANIC-SYNTHESIS | COMPLEX | OXIDATIVE N-DEALKYLATION | TERTIARY-AMINES | CHEMISTRY, ORGANIC | RHODIUM PORPHYRINS | BOND-CLEAVAGE | PHOTOREDOX CATALYSIS | FUNCTIONALIZATION | ACYLATIVE DEALKYLATION | ALIPHATIC-AMINES
Journal Article
SCIENTIFIC REPORTS, ISSN 2045-2322, 09/2018, Volume 8, Issue 1, p. 13994
The pyrolysis of bisphenol A (BPA), an essential process ingredient used in industry and many everyday life products, helps produce low-industrial-demand... 
DEALKYLATION-TRANSALKYLATION | MULTIDISCIPLINARY SCIENCES | TERT-BUTYLATION | TOLUENE | HYDROGEN-PRODUCTION | BISPHENOL-A | POLYCARBONATE | PYROLYSIS | CATALYST | ETHYLBENZENE DEALKYLATION | ZEOLITE
Journal Article
Applied Catalysis A: General, ISSN 0926-860X, 05/2012, Volume 425-426, pp. 130 - 144
The Single-Event Microkinetic (SEMK) methodology has been applied towards "ethylbenzene dealkylation/xylene isomerization" under industrially relevant... 
Ethylbenzene dealkylation | Rational design | Xylene isomerization | Single-Event Microkinetic modeling | Catalyst optimization | Models | Zeolites | Analysis | Isomerization | Ethylbenzene | Catalysts | Dealkylation | Xylene | Mathematical models | Activation energy | Transalkylation
Journal Article
Journal of Catalysis, ISSN 0021-9517, 03/2014, Volume 311, pp. 6 - 16
Aromatic dealkylation in methanol-to-hydrocarbons conversion on HZSM-5 occurs via the paring mechanism and 1,2,4,5 tetramethylbenzene is the predominant... 
Propylene | Isotopic experiments | Methanol-to-olefins | Ethylene | Side-chain mechanism | Zeolite | Paring mechanism | Aromatic dealkylation | MTO REACTION | PRODUCT SELECTIVITY | CATALYSIS | CHEMISTRY, PHYSICAL | ELIMINATION | ENGINEERING, CHEMICAL | ZEOLITE H-BETA | CO-REACTION | CHEMISTRY | ETHENE | SAPO-34 | INSIGHTS | Alkylbenzene | Olefins | Methanol
Journal Article
Theoretical Chemistry Accounts, ISSN 1432-881X, 9/2016, Volume 135, Issue 9, pp. 1 - 14
Journal Article
Biochemistry, ISSN 0006-2960, 07/2018, Volume 57, Issue 30, pp. 4536 - 4546
The degradation kinetics of an adrenaline (epinephrine) derivative, CpQ, was studied in solution in the pH range of 1–12 at 40–80 °C by high-performance liquid... 
CYTOCHROME-P450 | ELECTRON | AMINES | N-DEALKYLATION | BIOCHEMISTRY & MOLECULAR BIOLOGY | COMPLEXES | N,N-DIMETHYLANILINE | Hydrogen Peroxide - chemistry | Hydrolysis | Temperature | Metals - chemistry | Oxidation-Reduction | Stereoisomerism | Dealkylation | Water - chemistry | Epinephrine - analogs & derivatives | Kinetics | Buffers | Hydrogen-Ion Concentration
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2016, Volume 358, Issue 21, pp. 3422 - 3434
The modification of benzylic quaternary, tertiary, and secondary carbon centers through palladium‐catalyzed hydrogenolysis of C(sp3)–C(sp3) σ bonds is... 
diarylmethane | reductive dealkylation | quaternary centers | hydrogenolysis | Meldrum's acid
Journal Article
Polyhedron, ISSN 0277-5387, 09/2019, Volume 169, pp. 169 - 175
Catalytic activity and selectivity of [Fe (N4Py )(CH CN] , where the possible reactive high-valent intermediate (Fe O) is known and spectroscopically well... 
Nonheme oxoiron complex | Kinetics | C[sbnd]H activation | Oxidative N-dealkylation | Bioinspired oxidation | CYTOCHROME P450-CATALYZED HYDROXYLATION | HYDROGEN-ATOM | CRYSTALLOGRAPHY | HORSERADISH-PEROXIDASE | CHEMISTRY, INORGANIC & NUCLEAR | OXYGEN | C-H activation | ELECTRON-TRANSFER | MODEL SYSTEMS | AMINES | N-DEALKYLATION | DEMETHYLATION | MECHANISTIC PROBE
Journal Article
Catalysis Letters, ISSN 1011-372X, 02/2012, Volume 142, Issue 2, pp. 151 - 160
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2018, Volume 8, Issue 7, pp. 5915 - 5927
The cytochrome P450 enzymes execute a range of selective oxidative biotransformations across many biological systems. The bacterial enzyme CYP199A4 catalyzes... 
C-H bond oxidation | heteroatom oxidation | dealkylation | enzyme mechanism | crystal structures | biocatalysis | cytochrome P450 enzymes | OXIDATION | SYSTEM | COMPOUND-I | MECHANISM | CRYSTAL-STRUCTURE | REACTIVITY | CHEMISTRY, PHYSICAL | EPOXIDATION | N-DEALKYLATION | DEMETHYLATION | C-H HYDROXYLATION
Journal Article
Organic Process Research & Development, ISSN 1083-6160, 03/2012, Volume 16, Issue 3, pp. 512 - 517
An efficient process for synthesizing and isolating a new investigative anticancer agent, 1-bromoacetyl-3,3-dinitroazetidine, is described. The reaction... 
MILD | ACID | TERTIARY-AMINES | N-DEALKYLATION | NITROLYSIS | ACYLATIVE DEALKYLATION | CHEMISTRY, ORGANIC | CHEMISTRY, APPLIED | SALTS | 1,3,3-TRINITROAZETIDINE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2017, Volume 82, Issue 13, pp. 6615 - 6620
Our study shows that among aza-heterocycles of various ring sizes, including aziridines, azetidines, pyrrolidines, and piperidines, only N-alkyl pyrrolidines... 
DENSITY | MILD | ACID-CHLORIDES | TERTIARY-AMINES | CHEMISTRY, ORGANIC | DEALKYLATION | DERIVATIVES | Chemical reactions | Usage | Chemical properties | Pyrrole
Journal Article
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