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ChemCatChem, ISSN 1867-3880, 04/2014, Volume 6, Issue 4, pp. 992 - 995
Herein we report a one‐pot protocol for the deracemisation of chiral benzylic amines employing a novel monoamine oxidase–ω‐transaminase cascade, allowing... 
dealkylation | enzyme catalysis | chiral amines | biotransformations | deracemisation
Journal Article
ChemCatChem, ISSN 1867-3880, 12/2013, Volume 5, Issue 12, pp. 3505 - 3508
Biocatalytic imine reduction: A whole‐cell recombinant E. coli system, producing an (S)‐selective imine reductase (IRED) from Streptomyces sp. GF3546, is... 
amines | Streptomyces | imine reductase | asymmetric synthesis | biocatalysis | HYDROGENATION | RESOLUTION | CHEMISTRY, PHYSICAL | DERACEMISATION | AMINE OXIDASE | Schiff bases | Synthesis | Organic compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 35, pp. 4445 - 4448
The existing asymmetric synthesis of enantiopure alpha-substituted cyclic ethers predominantly relies on the enantioselective C-C bond formation involving a... 
BRONSTED ACID | ALCOHOLS | TRANSFORMATION | OXIDATION | CATALYSIS | ASYMMETRIC TRANSFER HYDROGENATION | NATURAL-PRODUCTS | DERACEMISATION | OXOCARBENIUM IONS | CHEMISTRY, MULTIDISCIPLINARY | PRINS CYCLIZATION
Journal Article
Nature Communications, ISSN 2041-1723, 06/2016, Volume 7, Issue 1, p. 11917
Journal Article
ChemCatChem, ISSN 1867-3880, 12/2015, Volume 7, Issue 23, pp. 3838 - 3841
Multienzyme cascade approaches for the synthesis of optically pure molecules from simple achiral compounds are desired. Herein, a cofactor self‐sufficient... 
amine dehydrogenase | chiral amines | biotransformations | asymmetric catalysis | cascade reaction | OXIDATION | KETONES | CONVERSION | TRANSAMINASES | CHEMISTRY, PHYSICAL | DERACEMISATION | CATALYZED N-ALKYLATION | Enzymes | Synthesis | Catalysis | Enantiomers | Organic compounds
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 12, pp. 2562 - 2568
The synthesis of optically pure secondary epoxy alcohols from racemic allylic alcohols using a single whole-cell biocatalyst of recombinant Escherichia coli... 
SECONDARY ALCOHOLS | ENANTIOSELECTIVE EPOXIDATION | ALLYLIC ALCOHOLS | CHIRAL OXIRANES | DERACEMIZATION | ASYMMETRIC EPOXIDATION | CHEMISTRY, ORGANIC | DERACEMISATION | DYNAMIC KINETIC RESOLUTION | STYRENE MONOOXYGENASE | DEHYDROGENASE
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 03/2017, Volume 15, Issue 12, pp. 2562 - 2568
The synthesis of optically pure secondary epoxy alcohols from racemic allylic alcohols using a single whole-cell biocatalyst of recombinant Escherichia coli... 
Journal Article
by Ju, SY and Qian, MX and Li, J and Yang, LR and Wu, JP
GREEN CHEMISTRY, ISSN 1463-9262, 10/2019, Volume 21, Issue 20, pp. 5579 - 5585
Optically pure 1,2,3,4-tetrahydroisoquinoline carboxylic acids are important chiral building blocks in the pharmaceutical and fine chemical industries.... 
OXIDATION | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | OXIDASE | ASYMMETRIC REDUCTION | STEP DERACEMIZATION | DEALKYLATION | (R)-IMINE REDUCTASE | DERACEMISATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | IMINE REDUCTASES | STRATEGIES
Journal Article
Crystal Growth & Design, ISSN 1528-7483, 09/2017, Volume 17, Issue 9, pp. 4965 - 4976
It has been recently observed that coupling Viedma ripening with a seeded in situ metastable racemic crystal to conglomerate transformation leads to... 
MATERIALS SCIENCE, MULTIDISCIPLINARY | RESOLUTION | CRYSTALLOGRAPHY | MODEL | DERACEMISATION | EMERGENCE | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | DISSOLUTION | KINETICS | ATTRITION-ENHANCED DERACEMIZATION | CHIRAL-SYMMETRY-BREAKING | NUCLEATION
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 35, pp. 4445 - 4448
The existing asymmetric synthesis of enantiopure α-substituted cyclic ethers predominantly relies on the enantioselective C–C bond formation involving a... 
Substitutes | Indoles | Ethers | Substrates
Journal Article
by Seo, YM and Mathew, S and Bea, HS and Khang, YH and Lee, SH and Kim, BG and Yun, H
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2012, Volume 10, Issue 12, pp. 2482 - 2485
A deracemization method was developed to generate optically pure L-homoalanine from racemic homoalanine using D-amino acid oxidase and omega-transaminase. A... 
ASYMMETRIC-SYNTHESIS | KINETIC RESOLUTION | ESTERS | VITREOSCILLA HEMOGLOBIN | FUSION PROTEIN | HYDROLYSIS | CHEMISTRY, ORGANIC | DERACEMISATION | DERIVATIVES
Journal Article
NATO Science for Peace and Security Series A: Chemistry and Biology, ISSN 1874-6489, 2017, Volume 1, pp. 331 - 339
Journal Article
Current Opinion in Chemical Biology, ISSN 1367-5931, 04/2013, Volume 17, Issue 2, pp. 236 - 249
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 23, pp. 3031 - 3035
An efficient organocatalytic oxidation of racemic secondary alcohols, mediated by sodium hypochlorite (NaOCl) and 2‐azaadamantane N‐oxyl (AZADO), has been... 
Oxidation | Oxidoreductases | Organocatalysis | Alcohols | SYSTEM | TRANSFORMATION | CATALYSIS | ASYMMETRIC-SYNTHESIS | ONE-POT | CHEMISTRY, ORGANIC | DERACEMISATION | SECONDARY ALCOHOLS | STEREOINVERSION | LIGANDS | KINETIC RESOLUTION | Sodium hypochlorite | Oxidation-reduction reaction | Enantiomers
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 11/2019, Volume 9, Issue 11, pp. 10152 - 10158
Enantiomerically pure amino acid derivatives could be foundational compounds for peptide drugs. Deracemization of racemates to L-amino acid derivatives can be... 
deracemization | artificial protein | ancestral sequence reconstruction | EVOLUTION | l-amino acid oxidase | SPECIFICITY | RECONSTRUCTION | CHEMISTRY, PHYSICAL | BIOCATALYST | DERACEMISATION | EXPRESSION | d-amino acid derivatives
Journal Article
Crystal Growth & Design, ISSN 1528-7483, 11/2018, Volume 18, Issue 11, pp. 7122 - 7131
Recently, temperature cycles have been shown to lead to total deracemization of conglomerate forming compounds, in the presence of a racemizing agent. Even... 
CRYSTALLIZATION | MATERIALS SCIENCE, MULTIDISCIPLINARY | CRYSTALLOGRAPHY | AGGLOMERATION | DERACEMISATION | CHEMISTRY, MULTIDISCIPLINARY | CONGLOMERATE FORMING SYSTEM | INTERFACIAL SURFACE-TENSION | AMINO-ACID | PRECIPITATION | HIGH-PRESSURE HOMOGENIZATION | ATTRITION-ENHANCED DERACEMIZATION | SYMMETRY-BREAKING
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 18, pp. 5116 - 5120
The first redox deracemization of a series of cyclic benzylic ethers, including 6H‐benzo[c]chromenes, isochromans, and 1H‐isochromenes, is described. An... 
deracemization | benzylic ethers | acetals | synthetic methods | redox chemistry | TRANSFORMATION | OXIDATION | CATALYSIS | ASYMMETRIC TRANSFER HYDROGENATION | DERACEMISATION | OXOCARBENIUM IONS | CHEMISTRY, MULTIDISCIPLINARY | PRINS CYCLIZATION | ALCOHOLS | BRONSTED ACIDS | DERIVATIVES | Hydrogenation | Salicylates | Strategy | Biological effects | Oxidation | Asymmetry | Ethers
Journal Article