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diarylation (40) 40
chemistry, organic (31) 31
chemistry, multidisciplinary (20) 20
palladium (17) 17
derivatives (15) 15
alkenes (12) 12
aromatic compounds (11) 11
cross-coupling reactions (11) 11
arylation (10) 10
bromides (10) 10
olefins (8) 8
efficient (7) 7
functionalization (7) 7
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chemistry, applied (6) 6
halides (6) 6
nickel (6) 6
2-methoxypropanoic acid (5) 5
aryl (5) 5
aryl iodides (5) 5
dicarbofunctionalization (5) 5
iodides (5) 5
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triphenylphosphine (5) 5
alpha-arylation (4) 4
amination (4) 4
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one-pot synthesis (4) 4
p2o5-msoh (4) 4
pentoxide-methanesulfonic acid (4) 4
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suzuki-miyaura (4) 4
acids (3) 3
activation (3) 3
alkene (3) 3
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alkynes (3) 3
alpha,alpha-diarylation (3) 3
amines (3) 3
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bond (3) 3
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copper (3) 3
cross coupling (3) 3
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decarbonylative alpha,alpha-diarylation (3) 3
design (3) 3
direct arylation (3) 3
esters (3) 3
heck reaction (3) 3
hydroarylation (3) 3
inhibitors (3) 3
ionic liquids (3) 3
ligand (3) 3
monoarylation (3) 3
olefination (3) 3
organic-synthesis (3) 3
ring-closure (3) 3
silanols (3) 3
styrenes (3) 3
unactivated olefins (3) 3
2,2′-dimethoxy-1,1′-binaphthyl (2) 2
acylation (2) 2
alcohols (2) 2
aldehydes (2) 2
alkyl-halides (2) 2
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arenes (2) 2
article (2) 2
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arylboronate esters (2) 2
arylierung (2) 2
asymmetric catalysis (2) 2
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c-c coupling (2) 2
c-h activation (2) 2
c-h bonds (2) 2
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chemistry (2) 2
chemistry, physical (2) 2
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Tetrahedron, ISSN 0040-4020, 08/2014, Volume 70, Issue 32, pp. 4754 - 4759
A readily accessible catalytic system, PdCl (Ph P) /Ph P, was developed for the selective arylation of primary anilines with aryl bromides. The strong... 
Diarylation | Amination | Monoarylation | Palladium | Triphenylphosphine
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1530 - 1533
A method of synthesizing 3-arylquinoxalin-2­(1H)-ones using diaryliodonium tetrafluoroborates under mild conditions is described. This protocol has a wide... 
DESIGN | HETEROARENES | ONE-POT SYNTHESIS | ARENES | CHEMISTRY, ORGANIC | ARYL | INHIBITORS | DIARYLATION | EFFICIENT | DERIVATIVES | (HETERO)ARENES
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2014, Volume 70, Issue 32, pp. 4754 - 4759
A readily accessible catalytic system, PdCl2(Ph3P)2/Ph3P, was developed for the selective arylation of primary anilines with aryl bromides. The strong... 
Diarylation | Palladium | Amination | Triphenylphosphine | Monoarylation
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 03/2018, Volume 54, Issue 20, pp. 2558 - 2561
A reductive dicarbofunctionalization reaction of alkenes has been developed and applied to the preparation of substituted carbo- and heterocycles. The reaction... 
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 07/2017, Volume 4, Issue 7, pp. 1224 - 1228
An efficient Pd-catalyzed three components reaction involving the 1,2-diarylation of vinylarenes has been disclosed. This reaction introduces two different... 
CHEMISTRY, ORGANIC | PALLADIUM | ALKENES | DIARYLATION | 1,3-DIENES | TRIARYLMETHANES
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 8, pp. 2154 - 2157
We disclose a Pd-catalyzed reaction protocol that regioselectively difunctionalizes unactivated olefins with aryl iodides and tethered enolates. The current... 
ALCOHOLS | HALIDES | COUPLING REACTIONS | TANDEM ARYLATION | CHEMISTRY, ORGANIC | CARBOPALLADATION | ARYL | DIARYLATION | DERIVATIVES | TERMINAL ALKENES
Journal Article
Chemical science, ISSN 2041-6520, 01/2018, Volume 9, Issue 3, pp. 600 - 607
Efficient difunctionalization of alkenes allows the rapid construction of molecular complexity from simple building blocks in organic synthesis. We present... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 20, pp. 2558 - 2561
A reductive dicarbofunctionalization reaction of alkenes has been developed and applied to the preparation of substituted carbo- and heterocycles. The reaction... 
CROSS-COUPLING REACTIONS | ARYLATION | CARBONYL-COMPOUNDS | OLEFINS | ARYL IODIDES | DIARYLATION | ELECTROPHILES | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | RING-CLOSURE | UNACTIVATED ALKYL-HALIDES | Alkenes | Reagents
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 3, pp. 600 - 607
Efficient difunctionalization of alkenes allows the rapid construction of molecular complexity from simple building blocks in organic synthesis. We present... 
FUNCTIONALIZATION | ARYL GRIGNARD-REAGENTS | ALKENYL CARBONYL-COMPOUNDS | SQUARE-PLANAR NICKEL | COUPLING REACTION | BOND FORMATION | OLEFINS | DICARBOFUNCTIONALIZATION | DIARYLATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Iodides | Alkenes | Regioselectivity | Halides | Aromatic compounds | Isomerization | Reagents | Bromides | Nickel | Chemical synthesis | Substrates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 36, pp. 11461 - 11464
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 10/2001, Volume 3, Issue 21, pp. 3313 - 3316
[GRAPHICS] In contrast to the Pd(0)-catalyzed mechanism by Uemura, Mizoroki-Heck type reaction of boronic acids is found to proceed under a Pd(ll)mediated... 
HALIDES | PALLADIUM | IODIDES | SILANOLS | CHEMISTRY, ORGANIC | ARYL | DIARYLATION | BOND
Journal Article
RSC Advances, ISSN 2046-2069, 07/2012, Volume 2, Issue 14, pp. 5968 - 5971
A novel protocol for the copper-catalysed direct C(sp(3))-H bond functionalisation of 2-alkyl azaarenes to C=O double bonds has been developed, which expands... 
FUNCTIONALIZATION | C-H BOND | DIRECT ARYLATION | OLEFINATION | STRATEGY | N-SULFONYL ALDIMINES | SITE-SELECTIVE SP | DIARYLATION | PYRIDINES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 42, pp. 5381 - 5384
A method for the Cu-catalyzed cross-coupling of both aryl and alkylboranes with aryl bromides is described. The method employs an inexpensive Cu-catalyst and... 
ARYLBORONATE ESTERS | HALIDES | IODIDES | ALKENES | REAGENTS | ACIDS | TRANSMETALATION | LIGAND | DIARYLATION | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | Bromides | Cross coupling | Coupling | Iodides | Copper | Aromatic compounds
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2019, Volume 60, Issue 38, p. 151018
[Display omitted] •Transition-metal-free and ligand-free reaction.•Facile approach to synthesize diarylamines utilizing aryne precursors and... 
Diarylation | Transition-metal-free | Isocyanate | Aryne | HETEROARYL | FACILE N-ARYLATION | HETEROCYCLIC CARBENE | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | DIPHENYLAMINE | BROMIDES | PALLADIUM-CATALYZED AMINATION | AMINES | DERIVATIVES | ARYL CHLORIDES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 10, pp. 3198 - 3202
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 36, pp. 6217 - 6224
A density functional theory study on nickel‐catalyzed diarylation of styrene (R1) with arylboron (R2) and aryl bromide (R3) is presented in this article, to... 
Diarylation | Nickel | Density functional calculations | Reaction mechanisms | Homogeneous catalysis | Density functionals | Olefins
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2020, Volume 59, Issue 6, pp. 2375 - 2379
The redox‐neutral dicarbofunctionalization of tri‐ and tetrasubstituted olefins to form a variety of (hetero)cyclic compounds under photoinduced palladium... 
palladium catalysis | dicarbofunctionalization | quaternary centers | radicals | heterocycles | ACTIVATION | UNACTIVATED OLEFINS | DIARYLATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | ALKENES | BONDS | HECK REACTION | DERIVATIVES | CYCLIZATION | Alkenes | Styrenes | Aromatic compounds | Quaternary | Bromides | Amides | Palladium | Catalysis | Cascade chemical reactions | Cyclic compounds | Carbon
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2020, Volume 59, Issue 3, pp. 1201 - 1205
A nickel‐catalyzed conjunctive cross‐coupling of alkenyl carboxylic acids, aryl iodides, and aryl/alkenyl boronic esters is reported. The reaction delivers the... 
nickel | carboxylic acid | trifunctionalization | diarylation | ANNULATION | UNACTIVATED OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | CARBOMETALATION | FUNCTIONALIZATION | DIFUNCTIONALIZATION | CROSS-COUPLINGS | BIDENTATE | BONDS | BORYLATION | Coupling (molecular) | Cross coupling | Iodides | Aromatic compounds | Esters | Nickel | Carboxylic acids | Carboxylates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 20, pp. 6722 - 6726
Reported is an asymmetric reductive dicarbofunctionalization of unactivated alkenes. Under the catalysis of a Ni/BOX system, various aryl bromides,... 
nickel | asymmetric catalysis | annulations | alkenes | synthetic methods | STYRENES | DIARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | CONSTRUCTION | BONDS | OLEFINS | DICARBOFUNCTIONALIZATION | CYCLIZATION | Olefins | Nickel | Catalysis | Alkenes | Aromatic compounds | Quaternary | Benzene | Organometallic compounds | Bromides | Cyclic compounds | Zinc
Journal Article