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ISSN 0040-4020, 2018
A mannitol derived 2,3-butanediacetal ethyl ketone displays high levels of diastereoselectivity in boron and titanium mediated aldol reactions with a range of... 
butane-diacetal | diastereoselectivity | aldol
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2007, Volume 46, Issue 37, pp. 7052 - 7055
Broken down and added onto: An enantiomerically pure cyclic (alkyl)(amino)carbene cleanly activates P4, affording highly reactive products that can be further... 
carbenes | cycloaddition | diastereoselectivity | diphosphenes | phosphorus | Phosphorus | Cycloaddition | Diphosphenes | Carbenes | Diastereoselectivity
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2014, Volume 55, Issue 4, pp. 806 - 810
A one-pot, highly efficient and diastereoselective construction of 1,2-dihyro-10′bH-spiro[indole-3,1′-pyrazole[3,2-a]isoquinoline] -2′-carboxylates via silver... 
Cycloaddition | Spirooxindole | Pyrazoloisoquinoline | Diastereoselectivity
Journal Article
SCIENCE, ISSN 0036-8075, 05/2013, Volume 340, Issue 6136, pp. 1065 - 1068
An important challenge in asymmetric synthesis is the development of fully stereodivergent strategies to access the full complement of stereoisomers of... 
ALCOHOLS | DIASTEREOSELECTIVITY | MULTIDISCIPLINARY SCIENCES | TRANSITION-METAL | ALLYLIC ALKYLATION | ORGANOCATALYSIS | NUCLEOPHILE | DERIVATIVES | EFFICIENT | TERTIARY | PHOTOREDOX CATALYSIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 30, pp. 10011 - 10011
The epoxide‐opening cascade cyclization of polyepoxides, which produces tetrahydrofuran (THF) in acidic aqueous media, produces tetrahydropyran (THP) in... 
natural products | terpenoids | diastereoselectivity | biomimetic synthesis | cyclization
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 9, pp. 2097 - 2097
A reductive Ireland–Claisen reaction was developed utilizing a boron‐based Lewis acid catalyst with size‐exclusion design. In the graphical art, the juggler... 
boranes | silanes | diastereoselectivity | sigmatropic rearrangement | Ireland–Claisen
Journal Article
Química Nova, ISSN 0100-4042, 2019, Volume 42, Issue 6, pp. 642 - 660
Amino sugars are chemical compounds that have a sugar backbone, in which one of the hydroxyl groups is replaced by an amino group. Derivatives of... 
amino sugars | regioselectivity | diastereoselectivity | carbohydrate
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2015, Volume 2015, Issue 16, pp. 3486 - 3494
A catalytic [3+3] annulation of cyclopropane 1,1‐diesters with in‐situ‐generated mercaptoacetaldehyde for the synthesis of polyfunctionalized... 
Lewis acids | Small ring systems | Sulfur heterocycles | Cyclization | Dia­stereoselectivity | Homogeneous catalysis | Dia-stereoselectivity | Diastereoselectivity
Journal Article
SYNTHESIS-STUTTGART, ISSN 0039-7881, 07/2019, Volume 51, Issue 13, pp. 2720 - 2728
(2S,3S,4R)- Dihydroxyhomoprolines were obtained from a six- carbon- atom lactone intermediate obtained from D- erythrose in a short synthesis, by facile... 
lactones | ACIDS | CHEMISTRY, ORGANIC | diastereoselectivity | DIVERGENT | dihydroxyproline
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 03/2018, Volume 16, Issue 13, pp. 2269 - 2276
It was established that 2-O-benzoyl-3,4,6-tri-O-benzyl protected β-SEt, β-SPh and β-SBox glucosyl donors are not superarmed when using the NIS/TfOH promoter... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 13, pp. 2269 - 2276
It was established that 2-O-benzoyl-3,4,6-tri-O-benzyl protected -SEt, -SPh and -SBox glucosyl donors are not superarmed when using the NIS/TfOH promoter... 
REACTIVITY | CHEMISTRY, ORGANIC | THIOGLYCOSIDES | ACTIVATION | DIASTEREOSELECTIVITY | Activation | Reactivity
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 12/2019, Volume 1198, p. 126924
New series of chiral isoxazoles and pyrazoles with monoterpenic skeleton, have been efficiently synthesized from naturally occurring (R)-Carvone, using... 
Isoxazoles | Cytotoxicity | Cycloaddition | DFT | Pyrazoles | Diastereoselectivity
Journal Article
Synlett, ISSN 0936-5214, 10/2018, Volume 29, Issue 16, pp. 2126 - 2130
Abstract 2-Ethylquinazolin-4-one derivatives bearing various ortho -substituted phenyl groups were revealed to possess a stable C–N axially chiral structure at... 
cluster | axial chirality | alkylation | diastereoselectivity | quinazolinones
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4189 - 4189
Planar chiral ligands based upon (η5‐cyclopentadienyl)(η4‐tetraphenylcyclobutadiene)cobalt(I) were readily synthesised as single stereoisomers. This chemistry... 
enantioselectivity | sandwich complexes | ligands | cobalt | diastereoselectivity
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 04/2019, Volume 14, Issue 8, pp. 1085 - 1085
A potential energy surface (PES) with two pathways that result in different diastereoisomers is shown in the cover feature. The Woodward–Hoffmann (WH) allowed... 
solvent effects | diastereoselectivity | electrocyclic reactions | isomerization | rearrangement
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2014
A facile promiscuous reaction catalyzed by Acylase 'Amano' was developed for the preparation of spirooxindole derivatives. At the optimized reaction condition,... 
Spirooxindole | Acylase | Diastereoselectivity | Domino reaction
Journal Article
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