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Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 38, pp. 5319 - 5329
A mannitol derived 2,3-butanediacetal ethyl ketone displays high levels of diastereoselectivity in boron and titanium mediated aldol reactions with a range of... 
Aldol | Butane-diacetal | Diastereoselectivity
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4189 - 4189
Planar chiral ligands based upon (η5‐cyclopentadienyl)(η4‐tetraphenylcyclobutadiene)cobalt(I) were readily synthesised as single stereoisomers. This chemistry... 
enantioselectivity | sandwich complexes | ligands | cobalt | diastereoselectivity
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 06/2016, Volume 2016, Issue 16, pp. 2793 - 2801
Relying on our previous achievements toward the a total synthesis of bielschowskysin, we herein report additional efforts to close the bridged tetradecane... 
Propargylation | Natural products | Terpenoids | Total synthesis | Diastereoselectivity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2002, Volume 41, Issue 16, pp. 3054 - 3056
In situ generation of nucleophilic alkynilides by using substoichiometric amounts of Zn(OTf)2 (OTf = trifluoromethanesulfonate) followed by removal of the... 
glycosylnitrones | diastereoselectivity | acetylides | hydroxylamines | zinc | Glycosylnitrones | Acetylides | Diastereoselectivity | Zinc | Hydroxylamines
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 11/2013, Volume 2013, Issue 32, pp. 7221 - 7262
Glycals (1,2‐unsaturated, cyclic carbohydrate derivatives) readily undergo (catalyzed) substitution reactions at C‐1 accompanied by allylic rearrangement. This... 
Carbohydrates | Glycosylation | Allylic compounds | Glycals | Diastereoselectivity | Rearrangement | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology | Substitution reactions
Journal Article
Chemistry, an Asian journal, ISSN 1861-4728, 02/2016, Volume 11, Issue 3, pp. 418 - 418
Spirocyclic pyrrolidinoindolines are privileged scaffolds present in a growing number of alkaloids with potential biological importance. A concise and... 
gold | cyclizationt | diastereoselectivity | 1,5-hydride shif | spirocyclic pyrrolidinoindoline
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 03/2017, Volume 2017, Issue 9, pp. 1262 - 1271
We report the use of bifunctional starting materials (ketoacids) in a diastereoselective Passerini three-center-two-component reaction. Study of the reaction... 
Multicomponent reactions | Cyclization | Ketoacids | Diastereoselectivity | Lactones | Rearrangement | Enantiomers | Isomerization | Full Paper | Full Papers
Journal Article
Synlett, ISSN 0936-5214, 12/2017, Volume 28, Issue 20, pp. 2946 - 2950
Abstract The title compounds were found to undergo a [2+2] photocycloaddition with olefins at λ = 419 nm in CH 2 Cl 2 as the solvent. The resulting... 
letter | cyclobutanes | cycloaddition | photochemistry | stereoselective synthesis | umpolung | nitro compounds | visible light | diastereoselectivity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2007, Volume 46, Issue 37, pp. 7052 - 7055
Broken down and added onto: An enantiomerically pure cyclic (alkyl)(amino)carbene cleanly activates P4, affording highly reactive products that can be further... 
carbenes | cycloaddition | diastereoselectivity | diphosphenes | phosphorus | Phosphorus | Cycloaddition | Diphosphenes | Carbenes | Diastereoselectivity
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 2017, Volume 2017, Issue 3, pp. 662 - 670
A new tandem strategy based on a Mannich/Pictet–Spengler sequence has been developed and applied to the synthesis of a new small library (14 examples) of... 
Multicomponent reactions | Enantioselectivity | Nitrogen heterocycles | Diastereoselectivity | Spiro compounds | Library synthesis | Libraries | Synthesis | Piperidine | Fluorination
Journal Article
Synthesis (Stuttgart), ISSN 0039-7881, 09/2014, Volume 47, Issue 1, pp. 95 - 107
Abstract The diastereoselective synthesis of 2,6-disubstituted 3-alkanoyl-4-hydroxycyclohex-3-ene-1,1-dicarbonitriles has been developed through domino double... 
paper | Michael addition | diastereoselectivity | cyclohexanone | domino reaction | curcumin
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6533 - 6537
The total synthesis of the tunicate metabolite mandelalide A and the correction of its originally assigned stereochemistry are reported. Key features of the... 
configuration determination | diastereoselectivity | structure elucidation | total synthesis | marine macrolides | Molecular Structure | Cyclization | Macrolides - chemistry | Magnetic Resonance Spectroscopy | Macrolides - chemical synthesis | Stereoisomerism | Index Medicus
Journal Article