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chemistry, multidisciplinary (8) 8
chemistry, organic (7) 7
fluorine (7) 7
difluoromethyl (5) 5
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Chinese Chemical Letters, ISSN 1001-8417, 08/2019, Volume 30, Issue 8, pp. 1515 - 1518
A facile and highly efficient approach for selective O-difluoromethylation of 1,3-diones with S-(difluoromethyl)sulfonium salt was developed, and a wide... 
S-(Difluoromethy)sulfonium salt | 1,3-Diones | Difluoromethyl enol ethers | O-Difluoromethylation | Difluorocarbene | ALCOHOLS | ETHERS | FLUORINE | DIFLUOROCARBENE REAGENT | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 24, pp. 6053 - 6063
Difluorodiazoethane (CF2HCHN2) is a small reactive diazoalkane. Its synthesis has been pursued since the 1970s, although only in the past three years have... 
carbenes | cycloaddition | difluoromethyls | diazo compounds | heterocycles | SITU GENERATED CF2HCHN2 | CATALYZED SYNTHESIS | FLUORINATED PYRAZOLES | CHEMISTRY, MULTIDISCIPLINARY | FLOW | MEDICINAL CHEMISTRY | DIAZO | TAMING HAZARDOUS CHEMISTRY | TRIFLUOROMETHYL DIAZOMETHANE | CARBOXYLIC-ACIDS | Chemical tests and reagents | Diazo compounds | Esterification | Reagents
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2018, Volume 140, Issue 6, pp. 2036 - 2040
Regioselective α,α-difunctionalization adjacent to a ketone is a significant synthetic challenge. Here, we present a solution to this problem through the... 
DOUBLE ALDOL REACTION | ORGANIC-SYNTHESIS | ASYMMETRIC-SYNTHESIS | DIFLUOROMETHYL KETONES | ALPHA-ARYLATION | BUILDING-BLOCKS | SILYL ENOL ETHERS | RADICAL CYCLIZATION | CARBONYL-COMPOUNDS | ALLYLATION REACTION | CHEMISTRY, MULTIDISCIPLINARY | Electrophiles | Analysis | Enolates | Electric properties
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2017, Volume 23, Issue 21, pp. 4950 - 4961
This Minireview describes recent advances toward the synthesis of trifluoromethyl‐ and difluoromethyl‐substituted cyclopropanes. Synthetic methodologies using... 
difluoromethyl | trifluoromethyl | substituted cyclopropanes | synthetic methods | fluorine | DITHIONITE INITIATED ADDITION | ANALOGS | BUILDING-BLOCKS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | CHEMISTRY | GENERATION | STEREOSELECTIVE-SYNTHESIS | 1-BROMO-1-CHLORO-2,2,2-TRIFLUOROETHANE | Cycloaddition | Synthesis | Organic compounds | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 15, pp. 4790 - 4793
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 8, pp. 1885 - 1889
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 2007, Volume 128, Issue 7, pp. 755 - 761
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 2001, Volume 112, Issue 2, pp. 355 - 360
Di- and monofluoromethyl ketones were prepared from the readily available trifluoromethyl ketones in high yields. Magnesium metal mediated reductive... 
Monofluoromethyl | Synthesis | Difluoromethyl | Trifluoromethyl ketones | Silyl ethers | Magnesium | Defluorination
Journal Article