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ENVIRONMENTAL RESEARCH LETTERS, ISSN 1748-9326, 10/2019, Volume 14, Issue 10, p. 104006
Using data from the Environmental Protection Agency's Chemical Speciation Network, we have characterized trends in PM2.5 transition metals in urban areas... 
BLACK CARBON | AMBIENT PARTICLES | AIRWAY INFLAMMATION | metals | urban air quality | particulate matter | ENVIRONMENTAL SCIENCES | TRACE-ELEMENTS | PARTICULATE MATTER PM | EARLY 1990S | LOS-ANGELES | PM exposure | CHEMICAL SPECIATION | TEMPORAL TRENDS | METEOROLOGY & ATMOSPHERIC SCIENCES | LONG-TERM TRENDS
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 2011, Volume 369, Issue 1, pp. 120 - 125
Diazabutadiene rings when folded on coordination to a metal are acting as LX ligands with donation from the filled π orbital to the metal via the N atoms. ►... 
Early transition metals | Electronic structure | DFT | Diazabutadiene | X-ray structure | APPROXIMATION | REACTIVITY | CENTERS | ENEDIAMIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | REGULAR 2-COMPONENT HAMILTONIANS | DIIMINE | ETA-2-IMINOACYL | DERIVATIVES | GEOMETRY
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 06/2016, Volume 49, Issue 6, pp. 1158 - 1167
Single-molecule magnets (SMMs) are highly sought after for their potential application in high-density information storage, spintronics, and quantum computing.... 
SANDWICH COMPLEXES | MAGNETOSTRUCTURAL CORRELATIONS | SYMMETRY | TEMPERATURE | LIGANDS | LANTHANIDE COMPLEXES | EARLY TRANSITION-METALS | ION MAGNETS | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | CYCLOOCTATETRAENYL COMPLEXES
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 04/2017, Volume 336, pp. 78 - 95
Journal Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 07/2005, Volume 690, Issue 14, pp. 3321 - 3332
The reactivity of M(eta(6)-arene)(2) derivatives of early transition metals (M = Ti, Cr, Me, arene = MeC6H5; M = V, Nb, arene = 1,3,5-Me3C6H3) has been... 
reactivity | CARBOXYLATES | MOLECULAR-STRUCTURE | arene | ORGANOMETALLIC CRYSTAL SYNTHESIS | early transition elements | oxidation | CHEMISTRY, ORGANIC | COORDINATION | structure | HYDROGEN-BONDS | CHEMISTRY, INORGANIC & NUCLEAR | VANADIUM | ARENE COMPLEXES | INTERMEDIATE
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 11/2019, Volume 55, Issue 88, pp. 13263 - 13266
Using H-2 as a reducing agent, we demonstrate controlled reduction of tri- and tetramethyl tantalum bis(N-heterocyclic carbene)borate complexes to yield... 
ACTIVATION | NIOBIUM | LIGANDS | COMPLEXES | DINITROGEN | REACTIVITY | EARLY TRANSITION-METALS | ARENE HYDROGENATION | MONOXIDE CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | BINUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2019, Volume 55, Issue 88, pp. 13263 - 13266
Using H2 as a reducing agent, we demonstrate controlled reduction of tri- and tetramethyl tantalum bis(N-heterocyclic carbene)borate complexes to yield... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2004, Volume 689, Issue 24, pp. 4552 - 4563
Journal Article
Synthesis, ISSN 0039-7881, 11/2014, Volume 46, Issue 21, pp. 2884 - 2896
Abstract The recent development and progress of early-transition-metal-catalyzed C–H alkylation adjacent to nitrogen of unprotected amines with alkenes are... 
short review | amines | metallaziridine | alkenes | early transition metals | C-H alkylation | TANTALUM COMPLEXES | CHEMISTRY, ORGANIC | UNACTIVATED OLEFINS | HYDROAMINATION | ADJACENT | INTERMOLECULAR HYDROAMINOALKYLATION | ZIRCONOCENE COMPLEXES | H BOND ACTIVATION | FUNCTIONALIZATION | SECONDARY-AMINES | AMIDATE COMPLEXES
Journal Article
Chemical Reviews, ISSN 0009-2665, 10/2018, Volume 118, Issue 19, pp. 9930 - 9987
High-oxidation-state 3d metal species have found a wide range of applications in modern synthetic chemistry and materials science. They are also implicated as... 
CYTOCHROME-P450 COMPOUND I | OXYGEN-EVOLVING COMPLEX | BIS(IMINO)PYRIDINE IRON IMIDES | CROSS-COUPLING REACTIONS | HYDROGEN-ATOM ABSTRACTION | OLEFIN METATHESIS CATALYSTS | EXHIBITING SPIN-CROSSOVER | PINCER DICARBENE COMPLEXES | EARLY TRANSITION-METALS | H BOND AMINATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organometallics, ISSN 0276-7333, 11/2018, Volume 37, Issue 21, pp. 3708 - 3717
Novel chiral rare-earth half sandwich complexes containing the chiral amidinate ligand, (S,S)-N,N′-bis­(1-phenylethyl)­benzamidinate ((S)-PEBA) or the t Bu... 
TEMPERATURE | SINGLE-ION MAGNET | LANTHANIDE COMPLEXES | CHEMISTRY, ORGANIC | EARLY TRANSITION-METALS | RELAXATION | BASIS-SETS | LIGAND | METALLOCENES | CYCLOOCTATETRAENYL COMPLEXES | YTTRIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 11/2015, Volume 119, Issue 46, pp. 26046 - 26055
The interaction of tetrahedrally coordinated Ti3+ ions generated in the framework of TiAlPO-5 microporous materials with 12,13C2H4 leads to the formation of... 
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 08/2017, Volume 36, Issue 15, pp. 2973 - 2981
The N-H and C-H bond activation reactions at ambient conditions of seven different secondary allyl amines (Aa-g) with bis(eta(5):eta(1)-pentafulvene)titanium... 
TITANAAZIRIDINES | SUBSTITUTED PYRROLES | CRYSTAL-STRUCTURE | ALKYLATION | 1-AZA-1,3-DIENE COMPLEXES | ZIRCONOCENE | CHEMISTRY, ORGANIC | EARLY TRANSITION-METALS | HYDROAMINOALKYLATION | DICARBONYLS | MONOAZADIENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 12/2016, Volume 35, Issue 24, pp. 4044 - 4049
Monodeprotonation of the 2,6-bis­(di-tert-butylphosphinomethyl) pyridine (tBuPNtBuP) at the α-lutidinyl-CH2 position with 1 equiv of KCH2C6H5 and concomitant... 
PALLADIUM(II) COMPLEXES | N-HETEROCYCLIC CARBENE | HYDROGENATION | BIS(CARBENE)PYRIDINE COMPLEXES | CHEMISTRY, ORGANIC | EARLY TRANSITION-METALS | BOND ACTIVATION | POLYMERIZATION | ORGANOMETALLIC CATALYSIS | STABILIZED CARBANIONS | COOPERATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 10, pp. 3346 - 3355
Uncommon examples of coordination compounds of high valent transition metals with α-diimines were obtained and characterized by IR and NMR spectroscopy, X-ray... 
Journal Article