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electron-deficient olefins (714) 714
chemistry, organic (499) 499
chemistry, multidisciplinary (274) 274
catalysis (211) 211
conjugate addition (146) 146
olefins (115) 115
michael addition (112) 112
derivatives (109) 109
index medicus (94) 94
alkenes (74) 74
asymmetric-synthesis (72) 72
organic-synthesis (69) 69
stereoisomerism (68) 68
alpha,beta-unsaturated ketones (67) 67
cycloaddition (67) 67
chemistry (63) 63
arylboronic acids (62) 62
chemical properties (62) 62
indoles (62) 62
ligands (62) 62
2,3-butadienoates (61) 61
organic chemistry (60) 60
functionalized cyclopentenes (58) 58
chemistry, physical (57) 57
epoxidation (57) 57
molecular structure (57) 57
chemistry, inorganic & nuclear (56) 56
electron-deficient alkenes (56) 56
enantioselective synthesis (56) 56
oxidation (55) 55
ketones (54) 54
synthesis (54) 54
allenes (53) 53
carbonyl-compounds (52) 52
cyclization (52) 52
asymmetric catalysis (51) 51
complexes (51) 51
imines (51) 51
organocatalysis (50) 50
catalysts (48) 48
rhodium (48) 48
hydrogen-peroxide (45) 45
3+2 cycloaddition (44) 44
aldehydes (43) 43
chemistry, applied (43) 43
nitrogen-heterocycles (43) 43
phosphines - chemistry (42) 42
4+2 annulation (41) 41
chemical reactions (41) 41
diels-alder reactions (41) 41
indole (41) 41
organoboronic acids (41) 41
research (40) 40
morita-baylis-hillman (39) 39
analysis (38) 38
esters (38) 38
enones (37) 37
friedel-crafts alkylation (37) 37
alkylation (36) 36
asymmetric 1,4-addition (35) 35
one-pot synthesis (34) 34
efficient (33) 33
asymmetric epoxidation (32) 32
baylis-hillman reaction (32) 32
diastereoselective synthesis (31) 31
efficient synthesis (31) 31
acid (30) 30
phosphine (30) 30
stereoselective-synthesis (30) 30
alkenes - chemistry (29) 29
chiral phosphines (29) 29
enantiomers (29) 29
palladium (29) 29
water (29) 29
boronic acids (28) 28
alpha,beta-unsaturated carbonyl-compounds (27) 27
asymmetry (27) 27
pyrrole (27) 27
allenoates (26) 26
ring formation (26) 26
alcohols (25) 25
cross-coupling reactions (25) 25
diels-alder reaction (25) 25
letter (25) 25
1,4-addition (24) 24
chemical sciences (24) 24
amino-acid (23) 23
aqueous-media (23) 23
article (23) 23
chemical synthesis (23) 23
michael reaction (23) 23
phosphines (23) 23
annulation (22) 22
asymmetric synthesis (22) 22
cycloaddition reactions (22) 22
activation (21) 21
alkaloids (21) 21
alkynes (21) 21
arylation (21) 21
c-h bonds (21) 21
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Organic Letters, ISSN 1523-7060, 07/2011, Volume 13, Issue 13, pp. 3410 - 3413
The design and development of a novel class of chiral sulfur-olefin hybrid ligands with high synthetic feasibility are described. These new sulfoxide-olefin... 
RHODIUM | STEERING LIGANDS | ARYLATION | COMPLEXES | CHEMISTRY, ORGANIC | DIENE LIGANDS | N-TOSYLARYLIMINES | 1,4-ADDITION | ADDITIONS | ARYLBORONIC ACIDS | ELECTRON-DEFICIENT OLEFINS | Alkenes - chemistry | Sulfoxides - chemistry | Stereoisomerism | Ligands | Molecular Structure | Catalysis | Sulfur - chemistry
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2016, Volume 358, Issue 10, pp. 1595 - 1601
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2080 - 2090
The transition-metal-catalyzed asymmetric cyclopropanation of olefins with diazoacetates has become one of the most important methods for the synthesis of... 
STEREOSELECTIVE CYCLOPROPANATION | REVERSE-TRANSCRIPTASE INHIBITORS | ALKYLIDENECYCLOPROPANES | SUCCINIMIDYL DIAZOACETATE | CYCLOPROPYLPHOSPHONATES | DIAZOKETONES | ASYMMETRIC INTRAMOLECULAR CYCLOPROPANATION | CONTAINING NATURAL-PRODUCTS | BELACTOSIN-A | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DEFICIENT OLEFINS
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2014, Volume 50, Issue 27, pp. 3619 - 3622
We present alpha-chloro amides as a new class of alpha-acetyl radical precursors, which undergo a tin-free, photoredox-catalysed intermolecular... 
HYPOPHOSPHOROUS ACID | ORGANIC-SYNTHESIS | ARYL DIAZONIUM SALTS | BOND-FORMING REACTIONS | ARYLATION | CARBONYL-COMPOUNDS | ELECTRON-DEFICIENT ALKENES | MICHAEL ACCEPTORS | C-H FUNCTIONALIZATION | ATOM-TRANSFER ADDITION | CHEMISTRY, MULTIDISCIPLINARY | Amides | Precursors | Olefins | Radicals | Alkylation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2016, Volume 138, Issue 7, pp. 2146 - 2149
Pd-catalyzed alpha-olefinic C-H activation of simple alpha,beta-unsaturated olefins has been developed. 4-imino-beta-lactam derivatives were readily... 
OXIDATIVE OLEFINATION | C(SP)-H BONDS | CROSS-COUPLING REACTION | PALLADIUM(II)-CATALYZED DIRECT ARYLATION | CYCLIC ENAMINONES | ELECTRON-DEFICIENT ALKENES | CARBON-HYDROGEN BONDS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | BETA-LACTAMS | ARYLBORONIC ACIDS
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 05/2016, Volume 11, Issue 10, pp. 1518 - 1522
New chiral phosphorus–olefin hybrid ligands derived from the rigid “privileged” l ‐proline have been conveniently prepared and applied in the rhodium‐catalyzed... 
ligands | asymmetric arylation | L-proline | electron-deficient olefins | rhodium | Density functionals | Proline | Olefins
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2014, Volume 356, Issue 13, pp. 2749 - 2755
Journal Article
Chemical science, ISSN 2041-6520, 01/2014, Volume 5, Issue 1, pp. 101 - 106
A new strategy to access linear amines from terminal olefin precursors is reported. This two-step, one-pot hydroamination methodology employs sequential... 
Journal Article
Chemical Science, ISSN 2041-6520, 01/2014, Volume 5, Issue 1, pp. 101 - 106
A new strategy to access linear amines from terminal olefin precursors is reported. This two-step, one-pot hydroamination methodology employs sequential... 
OXIDATION | ALKENES | ASSISTED INTRAMOLECULAR AMINATION | CATALYZED TRANSFER HYDROGENATION | INTERMOLECULAR HYDROAMINATION | VINYLARENES | H BONDS | ALKYNES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DEFICIENT OLEFINS | Amines | Precursors | Olefins | Strategy | Transformations | Terminals | Arrays | Aliphatic compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 90, pp. 12193 - 12196
A highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by chiral Ru(II)-Pheox complexes was developed to give chiral... 
TERT-BUTYL | ALKENES | DIASTEREOSELECTIVE CYCLOPROPANATION | LIGANDS | ALKYLIDENECYCLOPROPANES | CYCLOPROPYLPHOSPHONATES | ENANTIOSELECTIVE CYCLOPROPANATION | ASYMMETRIC INTRAMOLECULAR CYCLOPROPANATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DEFICIENT OLEFINS
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2017, Volume 53, Issue 90, pp. 12193 - 12196
A highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by chiral Ru(ii)–Pheox complexes was developed to give chiral... 
Alkenes | Sulfones | Organic compounds
Journal Article
ACS Catalysis, ISSN 2155-5435, 08/2016, Volume 6, Issue 8, pp. 5493 - 5499
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2018, Volume 2018, Issue 30, pp. 4058 - 4063
Phenylboronic acid was shown to mediate the multicomponent free‐radical carbocyanation of olefins and the addition of alkyl iodides to vinylsulfones. The... 
C–C coupling | Boron | Synthetic methods | Multicomponent reactions | Radical reactions | C-C coupling | ELECTRON-DEFICIENT HETEROCYCLES | SULFUR-DIOXIDE | CHEMISTRY, ORGANIC | ALKYNYLATION | C-H BONDS | ARYLBORONIC ACIDS | SULFONYL RADICALS | RADICAL CARBO-ALKENYLATION | ALPHA-SCISSION | ARYL RADICALS | ACETYLENIC TRIFLONES | Olefins
Journal Article